在盐湖地区暴露<strong>48</strong>个月纯锌的腐蚀行为

doi:10.11901/1005.3093.2018.492

材料研究学报

2019, Vol. 33

Issue (8): 603-613 DOI: 10.11901/1005.3093.2018.492

研究论文

本期目录 | 过刊浏览

在盐湖地区暴露48个月纯锌的腐蚀行为

张丹,王振尧(

)

中国科学院金属研究所沈阳 110016

Corrosion Behavior of Zinc Exposed to Salt Lake Area for 48 Months

Dan ZHANG,Zhenyao WANG(

)

Institute of Metals Research, Chinese Academy of Sciences, Shenyang 110016, China

引用本文:

张丹,王振尧. 在盐湖地区暴露48个月纯锌的腐蚀行为[J]. 材料研究学报, 2019, 33(8): 603-613.
Dan ZHANG, Zhenyao WANG. Corrosion Behavior of Zinc Exposed to Salt Lake Area for 48 Months[J]. Chinese Journal of Materials Research, 2019, 33(8): 603-613.

全文: PDF(28039 KB) HTML

摘要:

采用X射线衍射(XRD)、扫描电子显微镜(SEM)、金相显微镜和电化学阻抗等手段研究了锌在青海盐湖大气环境(富盐干旱型大气环境)中的腐蚀行为。结果表明，在青海盐湖大气环境中锌的腐蚀规律遵循经验公式m=Atⁿ。锌的向地面比向天面腐蚀严重，向天面暴晒48个月出现锈层脱落现象。两个表面的腐蚀产物均由Zn₅(OH)₈Cl₂·H₂O，Zn₅(CO)₃(OH)₆和Zn₄SO₄(OH)₆·3H₂O组成，锈层均富含SiO₂。电化学结果表明，随着暴晒时间的延长向地面的极化电阻R_p逐渐增大，而向天面的R_p逐渐增加，而暴晒48个月时减小。锈层有抑制基体腐蚀的作用，对两个表面锈层的保护性随暴晒时间的延长而增大，而向天面暴晒48个月时保护性减弱。

关键词 ：材料失效与保护, 锌, 青海盐湖, 大气腐蚀, 锈层分析, EIS

Abstract：

Corrosion behavior of zinc was field exposed to salt-rich arid atmosphere at Qinghai salt lake of Qinghai province at the Northwest China for 48 months was investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), metalloscopy and EIS techniques.Results reveal that the corrosion kinetics of zinc in the atmosphere at a selected site followed the empirical equation m=Atⁿ. The corrosion of zinc on the skyward surface is heavier than that on the fieldward one, while spallation of the rust layer on the skyward surface did occur after exposure for 48 months. The corrosion products on the two surfaces were mainly composed of Zn₅(OH)₈Cl₂·H₂O, Zn₅(CO)₃(OH)₆, Zn₄SO₄(OH)₆·3H₂O, the rust layer contained also certain amount of SiO₂. The results of EIS analysis showed that the rust layer could suppress the corrosion of zinc substrate, the corrosion resistance of rust layers on the two surfaces increased with time, then the protectiveness of the rust layer on the skyward surface was weakened for 48 months exposure.

Key words： materials failure and proterction zinc Qinghai salt lake atmospheric corrosion the skyward surfaces EIS

收稿日期: 2018-08-13

ZTFLH:

TG172.3

基金资助:国家自然科学基金(No. 51671197);国家自然科学基金(No. 51601199);广州市产学研协同创基金项目:新联盟专项(No. 201604046014)

作者简介: 张丹，女，1990年生，硕士

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	张丹
	王振尧
44.8K

链接本文:

https://www.cjmr.org/CN/10.11901/1005.3093.2018.492 或 https://www.cjmr.org/CN/Y2019/V33/I8/603

图1 纯Zn的腐蚀失重曲线

图2 暴晒不同时间后纯Zn的宏观形貌图

图3 暴晒不同时间后纯Zn的表面形貌

图4 暴晒不同时间后 Zn 的 XRD 谱

图5 暴晒不同时间后纯锌的截面形貌图

表1 图5中腐蚀产物层不同位置处元素的EDS分析结果

图6 暴晒不同时间后去除腐蚀产物后Zn的形貌

图7 腐蚀不同时间后锌的Nyquist图

图8 腐蚀不同时间后锌的Bode图

图9 锌的腐蚀等效拟合电路

表2 拟合所得锌的电化学阻抗谱参数

图10 电化学阻抗谱参数Rp随暴晒时间的变化

图11 在青海盐湖大气暴晒期间Zn的腐蚀过程示意图[31]

[1]	Cole I S, Paterson, D A, Ganther W D. Holistic model for atmospheric corrosion. Part I. Theoretical framework for production,transportation and deposition of marine salts [J]. Corr. Eng. Sci,Technol, 2003, 38: 129
[2]	Lindstrom R, Svensson J E, Johansson L G, The atmospheric corrosion of zinc in the presence of NaCl-the influence of carbon dioxide and temperature [J]. J. Electrochem. Soc, 2000, 147: 1751
[3]	Svensson J E, Johansson L G. A laboratory study of the initial stages of the atmospheric corrosion of zinc in the presence of NaCl; influence of SO2 and NO2 [J]. Corros. Sci, 1993, 34: 721
[4]	Aske Y A, Lyon S B, Thompson G E, et al. The effect of fly-ash particulates on the atmospheric corrosion of zinc and mild-steel [J]. Corros. Sci, 1993, 34: 1055
[5]	Wang Z Y, Yu G C， Han W. Atmospheric corrosion performance of zinc at several selected sits in china [J]. Corrosion Science and Protection Technology, 2003, 4: 1911
[5]	王振尧, 于国才, 韩薇. 我国典型大气环境中的锌腐蚀 [J]. 腐蚀科学与防护技术, 2003, 4: 1911
[6]	Perssona D, Thierryb D, Karlsson O. Corrosion and corrosion products of hot dipped galvanized steel during long term atmospheric exposure at different sites world-wide [J]. Corros. Sci,2017, 126: 152
[7]	Shu D X, Yang X R, Liu Y. Study of Zn corrosion in tropic marine atmosphere [J]. Equipment Environment Engineering,2003, 4: 45
[7]	舒德学, 杨晓然, 罗勇. 纯锌在热带海洋环境下的大气腐蚀行为及规律 [J]. 装备环境工程, 2003, 4: 45
[8]	Lindstrom R, Svensson J E, Johansson L G.The influence of salt deposits on the atmospheric corrosion of zinc, the important role of the sodiumion [J]. J. Electrochem. Soc, 2002, 149: 57
[9]	Chen Z Y, Persson D, Leygraf C. Initial NaCl-particle induced atmospheric corrosion of zinc-effect of CO2 and SO2 [J]. Corros. Sci, 2008, 50: 111
[10]	Lindstrom R, Svensson J E, Johansson L G. The atmospheric corrosion of zinc in the presence of NaCl-the influence of carbon dioxide and temperature, J. Electrochem [J]. Soc,2000, 147: 1751
[11]	Liu A Q, Xiao K, Li X G, et al. Comparison of corrosion behavior of pure Zn and Zn-Al alloy coating in serious Xisha marine atmosphere environment [J]. Thermal Spray Technology, 2005, 4: 46
[11]	刘安强, 肖葵, 李晓刚等. Zn和ZnAl合金涂层在西沙严酷海洋大气环境下的腐蚀行为的比较 [J]. 热喷涂技术, 2005, 4: 46
[12]	Liu Y W, Wang Z Y,Cao G W, et al. Study on corrosion behavior of zinc exposed in coastal-industrial atmospheric environment [J]. Materials Chemistry and Physics, 2017, 198: 243
[13]	Azmat N S, Ralston K D, Muddle B C, et al. Corrosion of Zn under acidified marine droplets [J]. Corro. Sci, 2011, 53: 1604
[14]	Vera R, Rosales B M, Tapia C. Effect of the exposure angle in the corrosion rate of plain carbon steel in a marine atmosphere [J]. Corros. Sci, 2003, 45: 321
[15]	Wang Z Y, Li Q X, Wang C, et al. Corrosion behavior of Al alloy LC4 in geermu salt lake atmosphere [J]. The Chinese Journal of Nonferrous Metals, 2007, 17: 24
[15]	王振尧, 李巧霞, 汪川等. LC4铝合金在格尔木盐湖大气环境中的腐蚀行为 [J]. 中国有色金属学报, 2007, 17: 24
[16]	Wang B B, Wang Z Y, Cao G W, et al. Localized corrosion of Aluminum alloy 2024 exposed to salt lake atmospheric environment in western china [J]. Acta Metallurgica Sinica, 2014, 50: 49
[16]	王彬彬, 王振尧, 曹公望等. 2024铝合金在中国西部盐湖大气环境中的局部腐蚀行为 [J]. 金属学报, 2014, 50: 49
[17]	Natesan M, Venkatachari G, Palaniswamy N. Kinetics of atmospheric corrosion of mild steel, zinc, glavanized iron and aluminum at 10 exposure stations in India [J]. Corro. Sci, 2006, 11: 3584
[18]	Syed S. Influence of the environment on atmospheric corrosion of aluminium [J].Corrosion Engineering Science and Technology, 2010, 4: 282
[19]	Liu S, Sun H Y, Fan J J, et al. Research progress on corrosion behavior of galvanized steel [J]. Materials Protection, 2012, 12: 42
[19]	刘栓, 孙虎元, 范汇吉等. 镀锌钢腐蚀行为的研究进展 [J]. 材料保护, 2012, 12: 42
[20]	Zhang X G. Corrosion of zinc and zinc alloys [J]. Corrosion and Protection, 2006, 1: 41
[20]	章小鸽. 锌和锌合金的腐蚀 [J]. 腐蚀与防护, 2006, 1: 41
[21]	Azmat N S, Ralston K D, Muddle B C.Corrosion of Zn under acidified marine droplets [J]. Corro.Sci, 2011, 53: 1604
[22]	Bernard M C, Hugot L A, Philips N .Underpaint corrosion of zinc-coat ed steel sheet studied by in situ Raman spectroscopy [J]. Corro. Sci, 1993, 5: 13
[23]	Liu Y W, Wang Z Y, Cao G W, et al. Corrosion behavior of Zn simulated acid rain atmospheric environment [J]. The Chinese Journal of Nonferous Metals, 2011, 25: 375
[23]	刘雨薇, 王振尧, 曹公望等. Zn在模拟酸雨大气环境中的腐蚀行为 [J]. 中国有色金属学报, 2011, 25: 375
[24]	Chunga S C, Cheng J R, Chioub S D, et al.EIS behavior of anodized zinc in chloride environments [J]. Corro. Sci, 2000, 42: 1249
[25]	Chung S C, Sung S L, Hsien C C, et al. SHIH.Application of EIS to the initial stages of atmospheric zinc corrosion [J]. Journal of Applied Electrochemistry, 2000, 30: 607
[26]	Katayama H K, Kurodav S J. Long-term atmospheric corrosion properties of thermally sprayed Zn, Aland Zn-Al coatings exposed in a coastal area [J]. Corro. Sci, 2013, 76: 35
[27]	Liu S, Sun H Y, Sun L J, et al.Effects of pH and Cl-concentration on corrosion behavior of the galvanized steel in simulated rust layer solution [J]. Corro. Sci, 2012, 65: 520
[28]	Stern M, Geary A L. Electrochemical polarization: I. A theoretical analysis of the shape of polarzation curve [J]. J. Electrochem. Soc, 2004, 16: 156
[29]	Roberge P, Klassen R, Haberecht P. Atmospheric corrosivity modeling-a review [J]. Mater. Des, 2002, 23: 321
[30]	Hosking N, Strom M, Shipway P, et alCorrosion resistance of zinc-magnesium coated steel [J]. Corro. Sci, 2007, 49: 3669
[31]	Cui Z Y, Li X G, Xiao K, et al. Corrosion behavior of field-exposed zinc in a tropical marine atmosphere [J]. Corro. Sci, 2014, 70: 731
[32]	Cole I S, Ganther W D, Sinclair J Det al, A study of the wetting of metal surfaces in order to understand the processes controlling atmospheric corrosion [J]. J. Electrochem. Soc, 2004, 151: 627

[1]	谢锋, 郭建峰, 王海涛, 常娜. ZnO/CdS/Ag复合光催化剂的制备及其催化和抗菌性能[J]. 材料研究学报, 2023, 37(1): 10-20.
[2]	高巍, 刘江南, 魏敬鹏, 要玉宏, 杨巍. TC4钛合金表面氧化亚铜掺杂微弧氧化层的结构和性能[J]. 材料研究学报, 2022, 36(6): 409-415.
[3]	杨留洋, 谭卓伟, 李同跃, 张大磊, 邢少华, 鞠虹. 利用WBE及EIS测试技术对管道缺陷区动态冲刷腐蚀行为的研究[J]. 材料研究学报, 2022, 36(5): 381-391.
[4]	陈铮, 杨芳, 王成, 杜瑶, 卢壹梁, 朱圣龙, 王福会. 惰性无机填料比例和颗粒尺寸对纳米Al/Al₂O₃ 改性有机硅涂料抗高温氧化行为的影响[J]. 材料研究学报, 2022, 36(4): 271-277.
[5]	李玉峰, 张念飞, 刘丽爽, 赵甜甜, 高文博, 高晓辉. 含磷石墨烯的制备及复合涂层的耐蚀性能[J]. 材料研究学报, 2022, 36(12): 933-944.
[6]	陈艺文, 王成, 娄霞, 李定骏, 周科, 陈明辉, 王群昌, 朱圣龙, 王福会. 无机复合涂层对CB2铁素体耐热钢在650℃水蒸气中的防护[J]. 材料研究学报, 2021, 35(9): 675-681.
[7]	唐荣茂, 刘光明, 刘永强, 师超, 张帮彦, 田继红, 甘鸿禹. 用电化学噪声技术研究Q235钢在含氯盐模拟混凝土孔隙液中的腐蚀行为[J]. 材料研究学报, 2021, 35(7): 526-534.
[8]	彭浩平, 席世亨, 崔德荣, 刘亚, 邓嵩, 苏旭平, 阮睿文. Mn对熔融Zn-Mn合金与X80钢润湿行为的影响[J]. 材料研究学报, 2021, 35(10): 785-794.
[9]	张大磊, 魏恩泽, 荆赫, 杨留洋, 豆肖辉, 李同跃. 超级铁素体不锈钢表面超疏水结构的制备及其耐腐蚀性能[J]. 材料研究学报, 2021, 35(1): 7-16.
[10]	王冠一, 车欣, 张浩宇, 陈立佳. Al-5.4Zn-2.6Mg-1.4Cu合金板材的低周疲劳行为[J]. 材料研究学报, 2020, 34(9): 697-704.
[11]	黄安然, 张伟, 王学林, 尚成嘉, 范佳杰. 铁素体不锈钢在高温尿素环境中的腐蚀行为研究[J]. 材料研究学报, 2020, 34(9): 712-720.
[12]	公维炜, 杨丙坤, 陈云, 郝文魁, 王晓芳, 陈浩. 扫描电化学显微镜原位观察碳钢涂层缺陷处的交流腐蚀行为[J]. 材料研究学报, 2020, 34(7): 545-553.
[13]	郭铁明, 徐秀杰, 张延文, 宋志涛, 董志林, 金玉花. Q345q桥梁钢和Q345qNH耐候钢在模拟工业大气+除冰盐混合介质中的腐蚀行为[J]. 材料研究学报, 2020, 34(6): 434-442.
[14]	朱金阳, 谭成通, 暴飞虎, 许立宁. 一种新型含Al低Cr合金钢在模拟油田采出液环境下的CO₂腐蚀行为[J]. 材料研究学报, 2020, 34(6): 443-451.
[15]	梁新磊, 刘茜, 王刚, 王震宇, 韩恩厚, 王帅, 易祖耀, 李娜. 氧化石墨烯改性环氧隔热涂层的耐蚀和隔热性能研究[J]. 材料研究学报, 2020, 34(5): 345-352.

Viewed

Full text

Abstract

Cited

Shared

Discussed