<strong>TC4</strong>钛合金表面氧化亚铜掺杂微弧氧化层的结构和性能

doi:10.11901/1005.3093.2021.411

材料研究学报

2022, Vol. 36

Issue (6): 409-415 DOI: 10.11901/1005.3093.2021.411

研究论文

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TC4钛合金表面氧化亚铜掺杂微弧氧化层的结构和性能

高巍, 刘江南, 魏敬鹏, 要玉宏, 杨巍(

)

西安工业大学材料与化工学院西安 710021

Structure and Properties of Cu₂O Doped Micro Arc Oxidation Coating on TC4 Titanium Alloy

GAO Wei, LIU Jiangnan, WEI Jingpeng, YAO Yuhong, YANG Wei(

)

School of Materials Science and Chemical Engineering, Xi'an Technological University, Xi'an 710021, China

引用本文:

高巍, 刘江南, 魏敬鹏, 要玉宏, 杨巍. TC4钛合金表面氧化亚铜掺杂微弧氧化层的结构和性能[J]. 材料研究学报, 2022, 36(6): 409-415.
Wei GAO, Jiangnan LIU, Jingpeng WEI, Yuhong YAO, Wei YANG. Structure and Properties of Cu₂O Doped Micro Arc Oxidation Coating on TC4 Titanium Alloy[J]. Chinese Journal of Materials Research, 2022, 36(6): 409-415.

全文: PDF(2472 KB) HTML

摘要:

在电解液中添加不同浓度的氧化亚铜微粒,然后在TC4钛合金表面制备掺杂铜氧化物的微弧氧化层。在模拟海水中进行微弧氧化层的摩擦磨损和抗菌实验,并使用扫描电镜(SEM)、X射线衍射仪(XRD)、X光电子能谱仪(XPS)和显微硬度仪等手段对比研究了掺杂氧化亚铜的微弧氧化层的微观结构和性能。结果表明：掺杂氧化亚铜的微弧氧化层表面呈多孔形貌特征,但是微孔的数量较少和孔径尺寸较小,氧化亚铜微粒在膜层中以氧化铜和氧化亚铜两种形式存在；与未掺杂氧化亚铜的微弧氧化层相比,添加不同浓度氧化亚铜的微弧氧化层在模拟海水中的抗磨损性能和抗菌性能显著提高,但是微弧氧化层中的铜元素使其耐蚀性有所降低。

关键词 ：材料失效与保护, 钛合金, 微弧氧化, 氧化亚铜, 微观结构, 性能

Abstract：

The microarc oxidation coating doped with coprous oxide was prepared on the surface of TC4 Ti-alloy by adding different amount of cuprous oxide particles into the electrolyte. The microstructure and properties of the cuprous oxide doped microarc oxidation coating were investigated by means of scanning electron microscope (SEM), X-ray diffractometer (XRD), X-ray photoelectron spectroscope (XPS) and microhardness tester. The results show that the surface of the microarc oxidation coating doped with cuprous oxide is porous, but the number and size of micropores are small. However the doped Cu oxides are present in the coating in two forms, namely copper oxide and cuprous oxide. Compared with the microarc oxidation coating without doping of cuprous oxide, the wear resistance and antibacterial performance of microarc oxidation coating doped with different amount of cuprous oxide are significantly improved in artifitial seawater, but their corrosion resistance degraded.

Key words： materials failure and protection titanium alloy micro arc oxidation Cu₂O microstructure performance

收稿日期: 2021-07-16

ZTFLH:

TG174

基金资助:国家自然科学基金(52071252)

作者简介: 高巍,男,1977年生,博士生

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https://www.cjmr.org/CN/10.11901/1005.3093.2021.411 或 https://www.cjmr.org/CN/Y2022/V36/I6/409

图1 用不同氧化亚铜浓度制备的TC4表面微弧氧化层的SEM形貌

表1 不同氧化亚铜浓度制备的TC4表面微弧氧化层的EDS结果

图2 TC4表面不同含量氧化亚铜微粒制备微弧氧化层的XRD谱

图3 6 g/L氧化亚铜微粒的微弧氧化层的XPS谱

图4 添加不同浓度氧化亚铜微粒TC4表面微弧氧化层的摩擦曲线

图5 添加不同浓度氧化亚铜微粒TC4表面微弧氧化层磨损后的SEM照片和EDS结果

图6 添加不同浓度氧化亚铜微粒微弧氧化层的浸泡失重曲线

图7 添加不同浓度氧化亚铜TC4表面微弧氧化层的金黄色葡萄球菌附着形貌

表2 金黄色葡萄球菌在氧化亚铜掺杂微弧氧化层表面培养3 d后的OD值

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