快重离子辐照对氧化锌材料内部结构特性的影响

doi:10.11901/1005.3093.2019.335

材料研究学报

2020, Vol. 34

Issue (1): 16-20 DOI: 10.11901/1005.3093.2019.335

研究论文

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快重离子辐照对氧化锌材料内部结构特性的影响

宋银^1,²(

),吕康源^1,²,张胜霞^1,²

1. 中国科学院近代物理研究所兰州 730000
2. 中国科学院大学核科学与技术学院北京 100049

Microstructure of Zinc Oxide Irradiated with Swift Heavy Ions Beam

SONG Yin^1,²(

),LV Kangyuan^1,²,ZHANG Shenxia^1,²

1. Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000, China
2. School of Nuclear Science and Technology, University of Chinese Academy of Sciences, Beijin 100049, China

引用本文:

宋银,吕康源,张胜霞. 快重离子辐照对氧化锌材料内部结构特性的影响[J]. 材料研究学报, 2020, 34(1): 16-20.
Yin SONG, Kangyuan LV, Shenxia ZHANG. Microstructure of Zinc Oxide Irradiated with Swift Heavy Ions Beam[J]. Chinese Journal of Materials Research, 2020, 34(1): 16-20.

全文: PDF(2034 KB) HTML

摘要:

使用拉曼光谱和透射电镜等分析手段研究了高能快重离子辐照对ZnO单晶内部结构特性的影响。结果表明，经过快重离子辐照后，在ZnO单晶的拉曼光谱中出现了两个新的振动吸收峰。采用不同轴向的拉曼入射光表征方法，证实了位于576 cm^-1的振动吸收峰与氧空缺位(V₀)密切相关。经离子辐照后透射电镜图像显示出现了许多间隙原子、空位和位错等缺陷，而电子衍射图表明试样没有出现明显的非晶化。这个结果表明，较高的能量和辐照剂量对氧化锌的整体结构和性能几乎没有影响，也充分证明ZnO单晶具有良好的抗辐照性能。

关键词 ：无机非金属材料, ZnO的结构与性能, 快重离子, 拉曼光谱, 透射电镜

Abstract：

The effect of irradiation with swift heavy ion beam of 350 MeV ⁵⁶Fe²¹⁺ on the internal structure characteristics of single crystal ZnO was investigated by means of Raman spectroscopy and transmission electron microscopy (TEM). It follows that two new vibration absorption peaks appeared in Raman spectra for the ZnO after irradiation. The results of characterization with different coaxial Raman incident lights proves that the vibration absorption peak at 576 cm^-1 is closely related to the oxygen vacancy (V₀). TEM images show that there exist many defects such as interstitial, vacancy and dislocation in the irradiated ZnO single crystal, but the electron diffraction patterns of which did not reveal any obvious amorphous wherein. It illustrates that the higher energy and irradiation dose will hardly impact the structure and properties of the entire ZnO. This has fully proved that ZnO single crystal with good resistance to swift heavy ion beam irradiation.

Key words： unorganic non-metallic materials structure and properties of ZnO fast heavy ions raman spectrum TEM

收稿日期: 2019-07-09

ZTFLH:

O433.5+1

基金资助:国家自然科学基金(11575263);国家自然科学基金(11705246);中科院“西部之光”人才培养项目和甘肃省自然科学基金(1501RJZA009)

作者简介: 宋银，男，1975年生，副研究员

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https://www.cjmr.org/CN/10.11901/1005.3093.2019.335 或 https://www.cjmr.org/CN/Y2020/V34/I1/16

图1 拉曼入射光沿晶体z轴方向56Fe21+离子辐照和非辐照氧化锌单晶的拉曼光谱

图2 剂量为1×1014 ions/cm256Fe21+离子辐照后沿离子入射方向[0001]不同深度处拉曼入射光和散射光垂直于ZnO单晶z轴[0001]方向的拉曼光谱

图3 1×1014 ions/cm256Fe21+离子辐照后样品中沿离子的入射方向在不同深度处的图像和电子衍射光斑

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