制备方法对磷酸盐微晶玻璃结构和性能的影响

doi:10.11901/1005.3093.2023.087

材料研究学报

2023, Vol. 37

Issue (10): 739-746 DOI: 10.11901/1005.3093.2023.087

研究论文

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制备方法对磷酸盐微晶玻璃结构和性能的影响

周毅¹(

), 涂强², 米忠华³

^1.太原科技大学材料科学与工程学院太原 030024
^2.上海核工程研究设计院有限公司上海 200233
^3.中船重工电机科技股份有限公司太原分公司太原 030027

Effect of Preparing Methods on Structure and Properties of Phosphate Glass-ceramics

ZHOU Yi¹(

), TU Qiang², MI Zhonghua³

^1.School of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, China
^2.Shanghai Nuclear Engineering Research and Design Institute Co. Ltd., Shanghai 200233, China
^3.Taiyuan Branch of CSIC Electrical Machinery Scienceand Technology Co. Ltd., Taiyuan 030027, China

引用本文:

周毅, 涂强, 米忠华. 制备方法对磷酸盐微晶玻璃结构和性能的影响[J]. 材料研究学报, 2023, 37(10): 739-746.
Yi ZHOU, Qiang TU, Zhonghua MI. Effect of Preparing Methods on Structure and Properties of Phosphate Glass-ceramics[J]. Chinese Journal of Materials Research, 2023, 37(10): 739-746.

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摘要:

分别用熔融法和烧结法制备P₂O₅-Nb₂O₅-BaO-Na₂O-CeO₂体系磷酸盐微晶玻璃，用XRD谱和SEM观察表征其结构并测定其体积密度、显微硬度、介电性能、极化性能和储能特性，研究了制备工艺对其结构和性能的影响。结果表明，用熔融法可制备出结构更致密的微晶玻璃，使其体积密度和显微硬度提高和降低其介电损耗。当CeO₂添加量提高到1%(摩尔分数)时，用两种工艺都可实现微晶玻璃的结构致密化，并促进其结晶。结晶程度的提高可改善微晶玻璃的介电常数和极化性能。用熔融法制备的CeO₂添加量为1%(摩尔分数)的微晶玻璃样品其能量释放密度为13.5 mJ/cm³、储能效率为50.1%。

关键词 ：无机非金属材料, 微晶玻璃, 制备方法, 力学性能, 介电性能, 电滞回线, 储能特性

Abstract：

Gass-ceramics can be well used for making energy storage capacitors because of their unique structure of crystalline particles uniformly distributed in the glass matrix. Compared with conventional silicon glass-based glass-ceramics, phosphate glass-ceramics have significant advantage of less energy consumption. In this study, glass-ceramics of P₂O₅-Nb₂O₅-BaO-Na₂O-CeO₂ were prepared by melting and sintering respectively. The structure of the prepared phosphate glass-ceramics was characterized through XRD and SEM. The effect of preparation method on the structure and properties of the phosphate glass-ceramics were systematically studied in terms of the bulk density, microhardness, dielectric properties, polarization performance and energy storage etc. The results showed that the more compact glass-ceramics could be obtained by the melting method, which could improve the bulk density and micro-hardness of the glass-ceramics, the corresponding dielectric loss was reduced. In addition, when the addition of CeO₂ was increased to 1% (mole fraction), the phosphate glass-ceramics obtained by the two methods were also achieved good densification. The addition of CeO₂ played a role in promoting crystallization, which enhanced the dielectric constant and polarization performance. The released energy density of 13.5 mJ/cm³ and energy storage efficiency of 50.1% were obtained for the glass-ceramic with addition of 1% CeO₂ (mole fraction) prepared by melting method.

Key words： inorganic non-metallic materials glass-ceramics preparing method mechanical properties dielectric properties P-E hysteresis loops energy storage characteristics

收稿日期: 2023-01-05

ZTFLH:

TQ110.1

基金资助:国家自然科学基金(51902221);校企技术转让项目(C2022007)

通讯作者: 周毅，副教授，zhouyi@tyust.edu.cn，研究方向为无机非金属材料

Corresponding author: ZHOU Yi, Tel: 18335130685, E-mail: zhouyi@tyust.edu.cn

作者简介: 周毅，男，1984年生，博士

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图1 磷酸盐微晶玻璃的XRD谱

图2 磷酸盐微晶玻璃的SEM照片

图3 用熔融法和烧结法制备的磷酸盐微晶玻璃的体积密度、显微维氏硬度和努氏硬度

图4 用熔融法和烧结法制备的磷酸盐微晶玻璃的介电常数与介电损耗的频率曲线

图5 用熔融法和烧结法制备的磷酸盐微晶玻璃的极化曲线、能量释放密度与能量效率

表1 用于储能电容器的微晶玻璃的电学性能

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