g-C3N4/Ag/BiOBr复合材料的制备及其光催化还原硝酸盐氮

doi:10.11901/1005.3093.2022.627

材料研究学报

2023, Vol. 37

Issue (10): 781-790 DOI: 10.11901/1005.3093.2022.627

研究论文

本期目录 | 过刊浏览

g-C₃N₄/Ag/BiOBr复合材料的制备及其光催化还原硝酸盐氮

刘志华¹^,³^,⁴(

), 岳远超², 丘一帆², 卜湘¹^,³^,⁴, 阳涛¹^,³^,⁴

^1.长沙理工大学水利与环境工程学院长沙 410114
^2.长沙理工大学化学化工学院长沙 410114
^3.洞庭湖水环境治理与生态修复湖南省重点实验室长沙 410114
^4.湖南省环境保护河湖疏浚污染控制工程技术中心长沙 410114

Preparation of g-C₃N₄/Ag/BiOBr Composite and Photocatalytic Reduction of Nitrate

LIU Zhihua¹^,³^,⁴(

), YUE Yuanchao², QIU Yifan², BU Xiang¹^,³^,⁴, YANG Tao¹^,³^,⁴

^1.School of Hydraulic and Environmental Engineering, Changsha University of Science & Technology, Changsha 410114, China
^2.School of Chemistry and Chemical Engineering, Changsha University of Science & Technology, Changsha 410114, China
^3.Key Laboratory of Dongting Lake Aquatic Eco-Environmental Control and Restoration of Hunan Province, Changsha 410114, China
^4.Engineering and Technical Center of Hunan Provincial Environmental Protection for River-Lake Dredging Pollution Control, Changsha 410114, China

引用本文:

刘志华, 岳远超, 丘一帆, 卜湘, 阳涛. g-C₃N₄/Ag/BiOBr复合材料的制备及其光催化还原硝酸盐氮[J]. 材料研究学报, 2023, 37(10): 781-790.
Zhihua LIU, Yuanchao YUE, Yifan QIU, Xiang BU, Tao YANG. Preparation of g-C₃N₄/Ag/BiOBr Composite and Photocatalytic Reduction of Nitrate[J]. Chinese Journal of Materials Research, 2023, 37(10): 781-790.

全文: PDF(8457 KB) HTML

摘要:

用高温煅烧、反应合成以及光还原等方法制备新型g-C₃N₄/Ag/BiOBr复合光催化材料，使用SEM、XRD、EPMA、FT-IR、XPS和UV-vis等手段对其表征，研究了这种复合材料在金卤灯照射下对硝酸盐氮(50 mg/L)的还原效果和氮气选择性。结果表明，使用1 g/L g-C₃N₄/Ag/BiOBr复合光催化材料，光反应180 min后硝酸盐的去除率为95.2%。用g-C₃N₄/Ag/BiOBr光催化硝酸盐氮的主要产物中N₂的占比最高(为88.0%)，氮气的选择性为92.4%。g-C₃N₄/Ag/BiOBr催化剂中的Ag能促进对电子的捕捉，BiOBr的光生电子经银单质转移到g-C₃N₄的价带上形成Z型复合光催化结构。这种复合光催化剂可将硝酸盐氮氧化，空穴清除剂甲酸在复合材料中空穴的作用下转化成强氧化性物质(COO $-$ )并进一步将其还原成硝酸盐氮。

关键词 ：无机非金属材料, g-C₃N₄/Ag/BiOBr, 硝酸盐氮, 复合材料, 光催化, 氮气选择性

Abstract：

Nitrate as one of the water pollutants is one of the major environmental problems. Photocatalytic reduction of nitrate nitrogen has attracted a lot of attention because of its high efficiency and environmental friendliness. The g-C₃N₄/Ag/BiOBr composite photocatalyst was prepared by high temperature calcination, reaction synthesis and photoreduction. The photocatalysts were characterized by SEM, XRD, EPMA、FT-IR, XPS and UV-vis, and the reduction effect of the composite on nitrate nitrogen (50 mg/L) under the irradiation of metal halide lamp was studied. The results showed that when 1g/L g-C₃N₄/Ag/BiOBr catalyst was used, the nitrate concentration was 2.4 mg/L, and the removal rate was 95.2% after 180 min photoreaction. Compared with g-C₃N₄, BiOBr and g-C₃N₄/BiOBr photocatalysts, the removal rates increased by 38.8%, 34.6% and 13.1%, respectively. Nitrogen was the main product in the photocatalytic conversion of nitrate nitrogen. The proportion of N₂ in the main products of nitrate nitrogen photocatalyzed by g-C₃N₄/Ag/BiOBr was the highest (88.0%), and the selectivity of nitrogen was 92.4%. Ag can be used as an electron trapping agent to effectively reduce the recombination of electron-hole pairs in photocatalytic materials. Under the action of silver, the photogenerated electrons of BiOBr are transferred to the valence band of g-C₃N₄ by silver elemental material, forming a Z-type composite photocatalytic structure. Nitrate nitrogen can be directly oxidized by the composite photocatalyst, and the hole scavenger formic acid can be converted into a strong oxidizing substance (COO.-) under the action of the composite hole, which can further reduce nitrate nitrogen.

Key words： inorganic non-metallic materials g-C₃N₄/Ag/BiOBr nitrate nitrogen composite photocatalysis nitrogen selectivity

收稿日期: 2022-11-25

ZTFLH:

O643

基金资助:湖南省教育厅优秀青年项目(19B040);长沙理工大学青年教师成长计划(2019QJCZ038);长沙理工大学研究生实践创新项目(SJCX202189)

通讯作者: 刘志华，liuzhihua@csust.edu.cn，研究方向为光催化材料

Corresponding author: LIU Zhihua, Tel: 13574872739, E-mail: liuzhihua@csust.edu.cn

作者简介: 刘志华，男，1979年生，博士

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	刘志华
	岳远超
	丘一帆
	卜湘
	阳涛
44.8K

链接本文:

https://www.cjmr.org/CN/10.11901/1005.3093.2022.627 或 https://www.cjmr.org/CN/Y2023/V37/I10/781

图1 不同光催化剂的XRD谱

图2 BiOBr、C3N4和C3N4-Ag-BiOBr 的XPS谱

图3 不同催化剂的FT-IR谱

图4 不同催化剂的SEM像

图5 g-C3N4/Ag/BiOBr的元素面分布

图6 不同催化剂的紫外可见光漫反射谱

图7 不同光催化剂对硝酸盐氮还原的影响

图8 不同光催化剂对硝酸盐氮还原及产物的影响

Photocatalyst	Hole scavenger	Light source	R_N/%	S $N 2$ /%	Ref.
g-C₃N₄/Ag/BiOBr	Formic acid	Halide lamp	95.2	92.4	This work
Ag/TiO₂	Formic acid	Xe lamp	95	90	[48]
Au/TiO₂	Oxalic acid	High-pressure Hg lamp	44	49.9	[49]
0.5TiO₂/Ti₃C₂/g-C₃N₄	Formic acid	High-pressure Hg lamp	93.3	96.62	[29]
Fe-LiNbO₃	Formic acid	High-pressure Hg lamp	90	88	[50]
ZnSe/BiVO₄	Formic acid	High-pressure Hg lamp	89.84	91.03	[14]
NH₂-MIL-101(Fe)/BiVO₄	Formic acid	High-pressure Hg lamp	94.8	93.5	[51]
Ag/SiO₂@cTiO₂	Formic acid	High-pressure Hg lamp	95.8	93.6	[22]

表1 光催化还原硝酸盐氮的比较

图9 g-C3N4/Ag/BiOBr光催化材料的光还原机制

1	Suriyaraj S P, Selvakumar R. Advances in nanomaterial based approaches for enhanced fluoride and nitrate removal from contaminated water [J]. RSC Adv., 2016, 6: 10565 doi: 10.1039/C5RA24789F
2	Wei L, Adamson M A S, Vela J. Ni₂P-modified Ta₃N₅ and TaON for photocatalytic nitrate reduction [J]. ChemNanoMat, 2020, 6: 1179 doi: 10.1002/cnma.v6.8
3	Zarei S, Farhadian N, Akbarzadeh R, et al. Fabrication of novel 2D Ag-TiO₂/γ-Al₂O₃/Chitosan nano-composite photocatalyst toward enhanced photocatalytic reduction of nitrate [J]. Int. J. Biol. Macromol., 2020, 145: 926 doi: 10.1016/j.ijbiomac.2019.09.183
4	Ge X H, Fu W Z, Wang Y J, et al. Removal of nitrate nitrogen from water by phosphotungstate-supported TiO₂ photocatalytic method [J]. Environ. Sci. Pollut. Res., 2020, 27: 40475 doi: 10.1007/s11356-020-09947-y
5	Qiu Y Y, Zhang L, Mu X T, et al. Overlooked pathways of denitrification in a sulfur-based denitrification system with organic supplementation [J]. Water Res., 2020, 169, 115084 doi: 10.1016/j.watres.2019.115084
6	Ma H, Gao X L, Chen Y H, et al. Fe(II) enhances simultaneous phosphorus removal and denitrification in heterotrophic denitrification by chemical precipitation and stimulating denitrifiers activity [J]. Environ. Pollut., 2021, 287: 117668 doi: 10.1016/j.envpol.2021.117668
7	Zeng D F, Liang K, Guo F, et al. Denitrification performance and microbial community under salinity and MIT stresses for reverse osmosis concentrate treatment [J]. Sep. Purif. Technol., 2020, 242: 116799 doi: 10.1016/j.seppur.2020.116799
8	Wang Z X, Richards D, Singh N. Recent discoveries in the reaction mechanism of heterogeneous electrocatalytic nitrate reduction [J]. Catal. Sci. Technol., 2021, 11: 705 doi: 10.1039/D0CY02025G
9	Vandekerckhove T G L, Kobayashi K, Janda J, et al. Sulfur-based denitrification treating regeneration water from ion exchange at high performance and low cost [J]. Bioresour Technol., 2018, 257: 266 doi: 10.1016/j.biortech.2018.02.047
10	Lim J, Liu C Y, Park J, et al. Structure sensitivity of Pd facets for enhanced electrochemical nitrate reduction to ammonia [J]. ACS Catal., 2021, 11: 7568 doi: 10.1021/acscatal.1c01413
11	Rai R K, Tyagi D, Singh S K. Room-temperature catalytic reduction of aqueous nitrate to Ammonia with Ni nanoparticles immobilized on an Fe₃O₄@n-SiO₂@h-SiO₂-NH₂ support [J]. Eur. J. Inorg. Chem., 2017, 2017: 2450 doi: 10.1002/ejic.v2017.18
12	Tugaoen H O, Garcia-Segura S, Hristovski K, et al. Challenges in photocatalytic reduction of nitrate as a water treatment technology [J]. Sci. Total Environ., 2017, 599-600: 1524 doi: 10.1016/j.scitotenv.2017.04.238
13	Yang W P, Wang J L, Chen R M, et al. Reaction mechanism and selectivity regulation of photocatalytic nitrate reduction for wastewater purification: progress and challenges [J]. J. Mater. Chem., 2022, 10A: 17357
14	Shi H L, Li C H, Wang L, et al. Photocatalytic reduction of nitrate pollutants by novel Z-scheme ZnSe/BiVO₄ heterostructures with high N₂ selectivity [J]. Separat. Purificat. Technol., 2022, 300: 121854 doi: 10.1016/j.seppur.2022.121854
15	Zazo J A, García-Muñoz P, Pliego G, et al. Selective reduction of nitrate to N₂ using ilmenite as a low cost photo-catalyst [J]. Appl. Catal., 2020, 273B: 118930
16	Anderson J A. Photocatalytic nitrate reduction over Au/TiO₂ [J]. Catal. Today, 2011, 175: 316 doi: 10.1016/j.cattod.2011.04.009
17	Zhang F X, Jin R C, Chen J X, et al. High photocatalytic activity and selectivity for nitrogen in nitrate reduction on Ag/TiO₂ catalyst with fine silver clusters [J]. J. Catal., 2005, 232: 424 doi: 10.1016/j.jcat.2005.04.014
18	Lucchetti R, Onotri L, Clarizia L, et al. Removal of nitrate and simultaneous hydrogen generation through photocatalytic reforming of glycerol over "in situ" prepared zero-valent nano copper/P25 [J]. Appl. Catal., 2017, 202B: 539
19	Ren H T, Jia S Y, Zou J J, et al. A facile preparation of Ag₂O/P25 photocatalyst for selective reduction of nitrate [J]. Appl. Catal., 2015, 176-177B: 53
20	Adamu H, McCue A J, Taylor R S F, et al. Simultaneous photocatalytic removal of nitrate and oxalic acid over Cu₂O/TiO₂ and Cu₂O/TiO₂-AC composites [J]. Appl. Catal., 2017, 217B: 181
21	Wang L S, Fu W Z, Zhuge Y P, et al. Synthesis of polyoxometalates (POM)/TiO₂/Cu and removal of nitrate nitrogen in water by photocatalysis [J]. Chemosphere, 2021, 278: 130298 doi: 10.1016/j.chemosphere.2021.130298
22	Hou Z A, Chu J F, Liu C, et al. High efficient photocatalytic reduction of nitrate to N₂ by Core-shell Ag/SiO₂@cTiO₂ with synergistic effect of light scattering and surface plasmon resonance [J]. Chem. Eng. J., 2021, 415: 128863 doi: 10.1016/j.cej.2021.128863
23	Imam S S, Adnan R, Kaus N H M. The photocatalytic potential of BiOBr for wastewater treatment: A mini-review [J]. J. Environ. Chem. Eng., 2021, 9(4): 105404 doi: 10.1016/j.jece.2021.105404
24	Fu J W, Yu J G, Jiang C J, et al. g-C₃N₄-based heterostructured photocatalysts [J]. Adv. Energy Mater, 2018, 8: 1701503 doi: 10.1002/aenm.v8.3
25	Chen P, Liu H J, Cui W, et al. Bi-based photocatalysts for light-driven environmental and energy applications: Structural tuning, reaction mechanisms, and challenges [J]. EcoMat, 2020, 2(3): e12047 doi: 10.1002/eom2.v2.3
26	Meng L Y, Qu Y, Jing L Q. Recent advances in BiOBr-based photocatalysts for environmental remediation [J]. Chin. Chem. Lett., 2021, 32(11): 3265 doi: 10.1016/j.cclet.2021.03.083
27	Vu M H, Sakar M, Nguyen C C, et al. Chemically bonded Ni cocatalyst onto the S doped g-C₃N₄ nanosheets and their synergistic enhancement in H₂ production under sunlight irradiation [J]. ACS Sustainable Chem. Eng., 2018, 6: 4194 doi: 10.1021/acssuschemeng.7b04598
28	Song T, Yu X, Tian N, et al. Preparation, structure and application of g-C₃N₄/BiOX composite photocatalyst [J]. Int. J. Hydrogen Energy, 2021, 46(2): 1857 doi: 10.1016/j.ijhydene.2020.10.136
29	Zheng R, Li C H, Huang K L, et al. TiO₂/Ti₃C₂ intercalated with g-C₃N₄ nanosheets as 3D/2D ternary heterojunctions photocatalyst for the enhanced photocatalytic reduction of nitrate with high N₂ selectivity in aqueous solution [J]. Inorg. Chem. Front., 2021, 8(10): 2518 doi: 10.1039/D1QI00001B
30	Jaffari Z H, Lam S M, Sin J C, et al. Magnetically recoverable Pd-loaded BiFeO₃ microcomposite with enhanced visible light photocatalytic performance for pollutant, bacterial and fungal elimination [J]. Separat. Purificat. Technol., 2020, 236: 116195 doi: 10.1016/j.seppur.2019.116195
31	Yang L W, Liu L J, Xia X F, et al. Preparation of pg-C₃N₄/BiOBr/Ag composite and photocatalytic degradation of sulfamethoxazole [J]. Environmental Science, 2021, 42(6): 2896
31	杨利伟, 刘丽君, 夏训峰等. pg-C₃N₄/BiOBr/Ag复合材料的制备及其光催化降解磺胺甲噁唑 [J]. 环境科学, 2021, 42(6): 2896
32	Varapragasam S J P, Andriolo J M, Skinner J L, et al. Photocatalytic reduction of aqueous nitrate with hybrid Ag/g-C₃N₄ under ultraviolet and visible light [J]. ACS Omega, 2021, 6: 34850 doi: 10.1021/acsomega.1c05523 pmid: 34963968
33	Di J, Xia J X, Yin S, et al. A g-C₃N₄/BiOBr visible-light-driven composite: Synthesis via a reactable ionic liquid and improved photocatalytic activity [J]. RSC Adv., 2013, 3(42): 19624 doi: 10.1039/c3ra42269k
34	Li Z Y, Zhao Y J, Guan Q, et al. Novel direct dual Z-scheme AgBr(Ag)/MIL-101(Cr)/CuFe₂O₄ for efficient conversion of nitrate to nitrogen [J]. Appl. Surf. Sci., 2020, 508: 145225 doi: 10.1016/j.apsusc.2019.145225
35	He F, He Z J, Xie J L, et al. IR and Raman spectra properties of Bi₂O₃-ZnO-B₂O₃-BaO quaternary glass system [J]. Am. J. Analyt. Chem., 2014, 5(16): 1142
36	Zhou C Y, Lai C, Huang D L, et al. Highly porous carbon nitride by supramolecular preassembly of monomers for photocatalytic removal of sulfamethazine under visible light driven [J]. Appl. Catal., 2018, 220B: 202
37	Liu Z S, Bi Y H, Zhao Y L, et al. Synthesis and photocatalytic property of BiOBr/palygorskite composites [J]. Mater. Res. Bull., 2014, 49: 167 doi: 10.1016/j.materresbull.2013.08.068
38	Fu Y H, Liang W, Guo J Q, et al. MoS₂ quantum dots decorated g-C₃N₄/Ag heterostructures for enhanced visible light photocatalytic activity [J]. Appl. Surf. Sci., 2018, 430: 234 doi: 10.1016/j.apsusc.2017.08.042
39	Xin G, Meng Y L. Pyrolysis synthesized g-C₃N₄ for photocatalytic degradation of methylene blue [J]. J. Chem., 2013, 2013: 187912
40	Kharlamov A, Marina B, Kharlamova G, et al. Features of the synthesis of carbon nitride oxide (g-C₃N₄)O at urea pyrolysis [J]. Diam. Relat. Mater., 2016, 66: 16 doi: 10.1016/j.diamond.2016.03.012
41	Dai H Z, Gao X C, Liu E Z, et al. Synthesis and characterization of graphitic carbon nitride sub-microspheres using microwave method under mild condition [J]. Diam. Relat. Mater. 2013, 38: 109 doi: 10.1016/j.diamond.2013.06.012
42	Fu Y S, Huang L T, Zhang J L, et al. Ag/g-C₃N₄ catalyst with superior catalytic performance for the degradation of dyes: a borohydride-generated superoxide radical approach [J]. Nanoscale, 2015, 7: 13723 doi: 10.1039/C5NR03260A
43	Gupta G, Kaur A, Sinha A S K, et al. Photocatalytic degradation of levofloxacin in aqueous phase using Ag/AgBr/BiOBr microplates under visible light [J]. Mater. Res. Bull., 2017, 88: 148 doi: 10.1016/j.materresbull.2016.12.016
44	Lu L F, Kong L, Jiang Z, et al. Visible-light-driven photodegradation of rhodamine B on Ag-modified BiOBr [J]. Catal. Lett., 2012, 142(6): 771 doi: 10.1007/s10562-012-0824-2
45	Yan T J, Yan X Y, Guo R R, et al. Ag/AgBr/BiOBr hollow hierarchical microspheres with enhanced activity and stability for RhB degradation under visible light irradiation [J]. Catal. Commun., 2013, 42: 30 doi: 10.1016/j.catcom.2013.07.022
46	Zheng R, Li C H, Huang K L, et al. In situ synthesis of N-doped TiO₂ on Ti₃C₂ MXene with enhanced photocatalytic activity in the selective reduction of nitrate to N₂ [J]. Inorg. Chem. Front., 2022, 9(6): 1195 doi: 10.1039/D1QI01614H
47	Zhang D F, Wang B Q, Gong X B, et al. Selective reduction of nitrate to nitrogen gas by novel Cu₂O-Cu⁰@Fe⁰ composite combined with HCOOH under UV radiation [J]. Chem. Eng. J., 2019, 359: 1195 doi: 10.1016/j.cej.2018.11.058
48	Sun D C, Yang W Y, Zhou L, et al. The selective deposition of silver nanoparticles onto {1 0 1} facets of TiO₂ nanocrystals with co-exposed {0 0 1}/{1 0 1} facets, and their enhanced photocatalytic reduction of aqueous nitrate under simulated solar illumination [J]. Appl. Catal., 2016, 182B: 85
49	Kominami H, Furusho A, Murakami S Y, et al. Effective photocatalytic reduction of nitrate to ammonia in an aqueous suspension of metal-loaded titanium (IV) oxide particles in the presence of oxalic acid [J]. Catal. Lett., 2001, 76: 31 doi: 10.1023/A:1016771908609
50	Li X, Wang S, An H Z, et al. Enhanced photocatalytic reduction of nitrate enabled by Fe-doped LiNbO₃ materials in water: Performance and mechanism [J]. Appl. Surf. Sci., 2021, 539: 148257 doi: 10.1016/j.apsusc.2020.148257
51	Shi H L, Li C H, Wang L, et al. Selective reduction of nitrate into N₂ by novel Z-scheme NH₂-MIL-101(Fe)/BiVO₄ heterojunction with enhanced photocatalytic activity [J]. J. Hazardous Mater., 2022, 424: 127711 doi: 10.1016/j.jhazmat.2021.127711
52	Ge L, Han C C, Liu J, et al. Enhanced visible light photocatalytic activity of novel polymeric g-C₃N₄ loaded with Ag nanoparticles [J]. Appl. Catal, 2011, 409-411A: 215

[1]	宋莉芳, 闫佳豪, 张佃康, 薛程, 夏慧芸, 牛艳辉. 碱金属掺杂MIL125的CO₂ 吸附性能[J]. 材料研究学报, 2023, 37(9): 649-654.
[2]	邵鸿媚, 崔勇, 徐文迪, 张伟, 申晓毅, 翟玉春. 空心球形AlOOH的无模板水热制备和吸附性能[J]. 材料研究学报, 2023, 37(9): 675-684.
[3]	潘新元, 蒋津, 任云飞, 刘莉, 李景辉, 张明亚. 热挤压钛/钢复合管的微观组织和性能[J]. 材料研究学报, 2023, 37(9): 713-720.
[4]	刘瑞峰, 仙运昌, 赵瑞, 周印梅, 王文先. 钛合金/不锈钢复合板的放电等离子烧结技术制备及其性能[J]. 材料研究学报, 2023, 37(8): 581-589.
[5]	任富彦, 欧阳二明. g-C₃N₄ 改性Bi₂O₃ 对盐酸四环素的光催化降解[J]. 材料研究学报, 2023, 37(8): 633-640.
[6]	刘明珠, 樊娆, 张萧宇, 马泽元, 梁城洋, 曹颖, 耿仕通, 李玲. SnO₂ 作散射层的光阳极膜厚对量子点染料敏化太阳能电池光电性能的影响[J]. 材料研究学报, 2023, 37(7): 554-560.
[7]	季雨辰, 刘树和, 张天宇, 查成. MXene在锂硫电池中应用的研究进展[J]. 材料研究学报, 2023, 37(7): 481-494.
[8]	王伟, 解泽磊, 屈怡珅, 常文娟, 彭怡晴, 金杰, 王快社. Graphene/SiO₂ 纳米复合材料作为水基润滑添加剂的摩擦学性能[J]. 材料研究学报, 2023, 37(7): 543-553.
[9]	李延伟, 罗康, 姚金环. Ni(OH)₂ 负极材料的十二烷基硫酸钠辅助制备及其储锂性能[J]. 材料研究学报, 2023, 37(6): 453-462.
[10]	张藤心, 王函, 郝亚斌, 张建岗, 孙新阳, 曾尤. 基于界面氢键结构的石墨烯/聚合物复合材料的阻尼性能[J]. 材料研究学报, 2023, 37(6): 401-407.
[11]	邵萌萌, 陈招科, 熊翔, 曾毅, 王铎, 王徐辉. C/C-ZrC-SiC复合材料的Si²⁺ 离子辐照行为[J]. 材料研究学报, 2023, 37(6): 472-480.
[12]	余谟鑫, 张书海, 朱博文, 张晨, 王晓婷, 鲍佳敏, 邬翔. N掺杂生物炭的制备及其对Co²⁺ 的吸附性能[J]. 材料研究学报, 2023, 37(4): 291-300.
[13]	张锦中, 刘晓云, 杨健茂, 周剑锋, 查刘生. 温度响应性双面纳米纤维的制备和性能[J]. 材料研究学报, 2023, 37(4): 248-256.
[14]	王刚, 杜雷雷, 缪自强, 钱凯成, 杜向博文, 邓泽婷, 李仁宏. 聚多巴胺改性碳纤维增强尼龙6复合材料的界面性能[J]. 材料研究学报, 2023, 37(3): 203-210.
[15]	林师峰, 徐东安, 庄艳歆, 张海峰, 朱正旺. TiZr基非晶/TC21双层复合材料的制备和力学性能[J]. 材料研究学报, 2023, 37(3): 193-202.

Viewed

Full text

Abstract

Cited

Shared

Discussed