<strong>Ni(OH)<sub>2</sub></strong> 负极材料的十二烷基硫酸钠辅助制备及其储锂性能

doi:10.11901/1005.3093.2022.267

材料研究学报

2023, Vol. 37

Issue (6): 453-462 DOI: 10.11901/1005.3093.2022.267

研究论文

本期目录 | 过刊浏览

Ni(OH)₂ 负极材料的十二烷基硫酸钠辅助制备及其储锂性能

李延伟¹^,², 罗康¹, 姚金环¹(

)

^1.桂林理工大学化学与生物工程学院广西电磁化学功能物质重点实验室桂林 541004
^2.桂林理工大学材料科学与工程学院有色金属材料及其加工新技术省部共建教育部重点实验室桂林 541004

Lithium Ions Storage Properties of Ni(OH)₂ Anode Materials Prepared with Sodium Dodecyl Sulfate as Accessory Ingredient

LI Yanwei¹^,², LUO Kang¹, YAO Jinhuan¹(

)

^1.Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, China
^2.Key Laboratory of New Processing Technology for Nonferrous Metal & Materials, Ministry of Education, College of Material Science and Engineering, Guilin University of Technology, Guilin 541004, China

引用本文:

李延伟, 罗康, 姚金环. Ni(OH)₂ 负极材料的十二烷基硫酸钠辅助制备及其储锂性能[J]. 材料研究学报, 2023, 37(6): 453-462.
Yanwei LI, Kang LUO, Jinhuan YAO. Lithium Ions Storage Properties of Ni(OH)₂ Anode Materials Prepared with Sodium Dodecyl Sulfate as Accessory Ingredient[J]. Chinese Journal of Materials Research, 2023, 37(6): 453-462.

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摘要:

以十二烷基硫酸钠(SDS)为辅助剂用均相沉淀法制备出具有微/纳分级结构的α-Ni(OH)₂材料并使用XRD、SEM、FT-IR、TGA和XPS等手段进行表征，研究了SDS对其结构和储锂性能的影响。结果表明，在制备过程中使用SDS可细化α-Ni(OH)₂的晶粒并有助于形成更加开放的微/纳米分级形貌；在n(SDS)/n(Ni²⁺)为2∶10的条件下制备的α-Ni(OH)₂储锂性能最佳，在2 A·g^-1电流密度下循环40次后其比容量保持在800 mAh·g^-1，在3 A·g^-1大电流密度下其可逆比容量仍达到710 mAh·g^-1，还表现出显著的赝电容效应(在0.9 mV·s^-1下其赝电容贡献率高达84.2%)。

关键词 ：无机非金属材料, 氢氧化镍, 均相沉淀法, 负极材料, 十二烷基硫酸钠, 锂离子电池

Abstract：

α-Ni(OH)₂ materials with micro/nano hierarchical structure were prepared by a facile homogeneous precipitation method with sodium dodecyl sulfate (SDS) as accessory ingredient. It was found that the introduction of SDS can refine the grain size of α-Ni(OH)₂ and facilitate the formation of micro/nano hierarchical morphology with a more open structure as evidenced by XRD, SEM, FT-IR, TGA, and XPS analysis. Results of electrochemical test demonstrate that the α-Ni(OH)₂ sample synthesized with the n(SDS)/n(Ni²⁺) of 2∶10 exhibits the best lithium ions storage performance. After 40 cycles at the current density of 2 A·g^-1 the α-Ni(OH)₂ sample maintained a specific capacity of 800 mAh·g^-1; even at the high current density of 3 A·g^-1 it still delivered a reversible specific capacity of 710 mAh·g^-1. Moreover, it shows a significant pseudo-capacitive effect during discharge/charge processes (the pseudo-capacitive contribution to the total stored charge is as high as 84.2% at 0.9 mV·s^-1).

Key words： inorganic non-metallic materials nickel hydroxide homogeneous precipitation method anode materials sodium dodecyl sulfate lithium-ion batteries

收稿日期: 2022-05-11

ZTFLH:

TQ152

基金资助:国家自然科学基金(22065010)

通讯作者: 姚金环，教授，yaojinhuan@126.com，研究方向为湿法冶金与电池电化学

Corresponding author: YAO Jinhuan, Tel: (0773)2538354, E-mail: yaojinhuan@126.com

作者简介: 李延伟，男，1979年生，教授

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https://www.cjmr.org/CN/10.11901/1005.3093.2022.267 或 https://www.cjmr.org/CN/Y2023/V37/I6/453

图1 SDS用量不同的Ni(OH)2样品的XRD谱和TGA图、NS-0和NS-20样品的FT-IR对比、NS-0和NS-20的Ni 2p XPS谱以及NS-20的S 2p XPS谱

表1 不同SDS添加量样品的晶格参数和平均晶粒尺寸

图2 NS-0、NS-10、NS-20和NS-30样品的SEM照片

图3 NS-0、NS-10、NS-20和NS-30样品在0.1 mV·s-1扫描速度下的CV曲线以及四个样品循环性能的对比、NS-0和NS-20样品在不同循环次数下的充放电曲线

表2 NS-20与用于LIBs的其他氢氧化镍基负极材料的循环性能的比较

图4 四个样品的倍率性能对比、NS-0、NS-20和NS-30样品在不同电流密度下的充放电曲线

图5 NS-0和NS-20样品在不同扫描速度下的CV曲线、NS-20样品在0.5 mV·s-1扫描速度下的CV曲线、NS-10、NS-20和NS-30样品在不同扫描速度下的赝电容贡献百分比

图6 NS-0、NS-10、NS-20和NS-30样品20次循环后的Nyquist图、Bode图和等效电路

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