含钼镍基焊缝金属在硝酸溶液中的腐蚀行为

doi:10.11901/1005.3093.2018.714

材料研究学报

2019, Vol. 33

Issue (6): 401-408 DOI: 10.11901/1005.3093.2018.714

研究论文

本期目录 | 过刊浏览

含钼镍基焊缝金属在硝酸溶液中的腐蚀行为

张旭^1,^2,³,陆善平^1,²(

)

1. 中国科学院金属研究所沈阳材料科学国家研究中心沈阳 110016
2. 中国科学院核用材料与安全评价重点实验室沈阳 110016
3. 中国科学技术大学材料科学与工程学院沈阳 110016

Corrosion Behavior of Ni-based Weld Metals with Different Mo Content in a Nitric Acid Aqueous Solution

Xu ZHANG^1,^2,³,Shanping LU^1,²(

)

1. Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
2. CAS Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
3. School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China

引用本文:

张旭,陆善平. 含钼镍基焊缝金属在硝酸溶液中的腐蚀行为[J]. 材料研究学报, 2019, 33(6): 401-408.
Xu ZHANG, Shanping LU. Corrosion Behavior of Ni-based Weld Metals with Different Mo Content in a Nitric Acid Aqueous Solution[J]. Chinese Journal of Materials Research, 2019, 33(6): 401-408.

全文: PDF(14434 KB) HTML

摘要:

研究了三种不同Mo含量的镍基焊缝熔敷金属在强氧化性介质(65%硝酸溶液)中的腐蚀行为。结果表明，熔敷金属在硝酸溶液中浸泡后发生了晶间腐蚀、点蚀以及枝晶间腐蚀等局部腐蚀。由于Mo元素促进了大尺寸Laves相在熔敷金属枝晶间的析出，在Laves相与基体之间产生了较大的电化学差异，导致Laves相在氧化性介质中腐蚀溶解，增大了熔敷金属的点蚀敏感性。在620℃焊后的去应力退火过程中，在焊缝中发生元素再分配，Mo元素降低了枝晶间Ni、Cr元素的贫化。由于枝晶间Ni、Cr元素的贫化是引起熔敷金属枝晶间腐蚀的重要因素，Mo元素降低了焊缝熔敷金属在硝酸溶液中枝晶间腐蚀敏感性。

关键词 ：材料失效与保护, 耐蚀性, ASTM-262A, 镍基焊缝, 钼

Abstract：

Welding overlayers of three welding wires containing various concentrations of Mo have been fabricated as the experimental materials via multiple semiautomatic gas tungsten arc welding (GTAW) with cold-wire feed. Then post-weld heat treatment is carried out at 620℃ for 29 h to reduce the welding residual stress. The corrosion resistance of the as-weld and heat-treated Ni-based weld metals is assessed in 65% nitric acid aqueous solution at 117℃ for 48 h. The results show that weld metals were suffered from several types of localized corrosion in the test medium, such as intergranular corrosion (IGC), pitting corrosion and interdendritic corrosion (IDC). Mo can promote the precipitation of Laves phase in the interdendritic region. Due to the electrochemical difference between the Laves phases and the matrix, pitting susceptibility of the Ni-based weld metals increase with the increase of Mo content. Further, the IDC takes place in the heat-treated weld metals. The electrochemical difference between the dendrite and the interdendritic region is the key factor for IDC. Mo can influence the diffusion of Ni and Cr during the post heat treatment and decrease the depletion degree of Cr and Ni in the interdendritic zone, then the degree of IDC drops for the heat-treated weld metals with addition of Mo.

Key words： materials failure and protection corrosion resistance ASTM-262A Ni-based weld metals Mo

收稿日期: 2018-12-17

ZTFLH:

TG422.3

基金资助:中国科学院重点部署项目(ZDRW-CN-2017-1);江苏省重点研发计划(BE2018113);国家自然科学基金(51474203)

作者简介: 张旭，男，1992年生，博士生

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https://www.cjmr.org/CN/10.11901/1005.3093.2018.714 或 https://www.cjmr.org/CN/Y2019/V33/I6/401

图1 焊接接头的示意图和取样位置

表1 不同Mo含量焊缝熔敷金属的化学成分

图2 焊态熔敷金属的金相组织

图3 焊态下不同Mo含量焊缝熔敷金属中的析出相

图4 热处理后不同成分焊缝熔敷金属的组织形貌

图5 焊缝金属的失重速率与Mo含量的关系

图6 不同Mo含量焊态熔敷金属的腐蚀形貌

图7 4Mo焊缝熔敷金属点蚀坑截面的形貌

图8 热处理态不同Mo含量焊缝熔敷金属的腐蚀形貌

图9 热处理态熔敷金属枝晶间元素的分布

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