原位生长在聚喹唑啉基共轭微孔聚合物表面的<strong>MoS<sub>2</sub></strong> 及其析氢性能

doi:10.11901/1005.3093.2021.263

材料研究学报

2022, Vol. 36

Issue (12): 900-906 DOI: 10.11901/1005.3093.2021.263

研究论文

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原位生长在聚喹唑啉基共轭微孔聚合物表面的MoS₂ 及其析氢性能

姜海超¹(

), 安昊东¹, 杨静¹, 苏玉金¹, 李泽¹, 张滨²

^1.河北科技大学化学与制药工程学院石家庄 050018
^2.河北化工医药职业技术学院实验实训中心石家庄 050026

In-situ Growth of MoS₂ on the Surface of Polyquinazoline Conjugated Microporous Polymers and Its Electrocatalysis Hydrogen Performance

JIANG Haichao¹(

), AN Haodong¹, YANG Jing¹, SU Yujin¹, LI Ze¹, ZHANG Bin²

^1.Hebei University of Science & Technology, College of Chemical and Pharmaceutical, Shijiazhuang 050018, China
^2.Hebei Chemical & Pharmaceutical College, Shijiazhuang 050026, China

引用本文:

姜海超, 安昊东, 杨静, 苏玉金, 李泽, 张滨. 原位生长在聚喹唑啉基共轭微孔聚合物表面的MoS₂ 及其析氢性能[J]. 材料研究学报, 2022, 36(12): 900-906.
Haichao JIANG, Haodong AN, Jing YANG, Yujin SU, Ze LI, Bin ZHANG. In-situ Growth of MoS₂ on the Surface of Polyquinazoline Conjugated Microporous Polymers and Its Electrocatalysis Hydrogen Performance[J]. Chinese Journal of Materials Research, 2022, 36(12): 900-906.

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摘要:

合成一种三环喹唑啉的共轭微孔聚合物(TQ-CMPs)并用水热法使二硫化钼原位生长在其骨架表面，制备出一种新型复合电催化析氢催化剂并研究了它的电催化析氢活性。结果表明，TQ-CMPs与MoS₂的质量比为2∶1的催化剂具有优异的电催化析氢活性，其过电势为71 mV，Tafel斜率为52 mV·dec^-1。比表面积较大的TQ-CMPs，使MoS₂的分散度提高、避免了MoS₂的堆积和聚集并使更多的MoS₂边缘暴露，从而提高了催化剂的效率。TQ-CMPs丰富的孔道结构和延伸的π共轭骨架，有利于质量运输和电荷转移。

关键词 ：复合材料, 共轭微孔聚合物, 二硫化钼, 电化学析氢, 电催化

Abstract：

Tripolyquinazoline-based conjugated microporous polymers (TQ-CMPs) were synthesized, and molybdenum sulfide (MoS₂) nanoparticles grown in-situ on the surface of TQ-CMPs via hydrothermal method as a new type of composite electrocatalyst for hydrogen evolution reaction. Its electrocatalytic hydrogen evolution activity was studied. As a result, when the mass ratio of the TQ-CMPs and MoS₂ is 2∶1 the electrocatalyst has excellent electrocatalytic activity for an overpotential of 71 mV and a Tafel slope of 52 mV·dec^-1 for hydrogen evolution reaction. TQ-CMPs have large specific surface areas, which improve the dispersion of MoS₂. The accumulation of MoS₂ was avoided effectively, and more MoS₂ edges was exposed, which improved the electrocatalytic activity. In addition, the abundant porous structure and extended π-conjugated framework of TQ-CMPs facilitated mass transport and charge transfer.

Key words： composits conjugated microporous polymers molybdenum sulfide hydrogen evolution reaction electrocatalysis

收稿日期: 2021-04-25

ZTFLH:

TB322

基金资助:河北省重点研发计划(19273808D);石家庄市科学技术研究与发展计划(201240253A)

作者简介: 姜海超，男，1982年生，博士

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https://www.cjmr.org/CN/10.11901/1005.3093.2021.263 或 https://www.cjmr.org/CN/Y2022/V36/I12/900

图1 TQ-CMPs 的FI-IR谱

图2 在77K测定的N2吸附和脱附等温线(a)和孔隙宽度分布(b)

图3 MoS2、TQ-CMPs@MoS2和TQ-CMP的XRD谱

图4 TQ-CMPs(a)和TQ-CMPs@MoS2 2∶1(b)的SEM图；TQ-CMPs(c)和TQ-CMPs@MoS2 2∶1(d)的TEM图；TQ-CMPs @MoS2 2∶1(e, f)的HRTEM图

图5 催化剂的电化学性能(a)0.5 mol·L?1 H2SO4中的LSVs，(b)由LSVs计算得到的Tafel斜率，(c)催化剂的Nyquist图，TQ-CMPs@MoS2 2∶1的稳定性(d)和循环伏安曲线(e)，催化剂的双层电容(f)

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