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材料研究学报  2011, Vol. 25 Issue (5): 517-521    
  研究论文 本期目录 | 过刊浏览 |
SO42-对Mn掺杂硫磷酸盐玻璃结构和发光性能的影响
杨一凡1, 曾惠丹1,  任晶1,  陈丹平2,  陈国荣1
1.华东理工大学材料科学与工程学院超细材料制备与应用教育部重点实验室~~上海~200237
2.中国科学院上海光学精密机械研究所~~上海~201800
Effect of SO2−4 on the Structure and Luminescence Properties of Manganese-doped Sulfophosphate Glasses
YANG Yifan1,  ZENG Huidan1,  REN Jing1,  CHEN Danping2,  CHEN Guorong1,
1.Key Laboratory for Ultrafine Materials of Ministry of Education, School of Materials Science and Engineering, East China University of Science and Technology, Shanghai 200237
2. Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800
引用本文:

杨一凡 曾惠丹 任晶 陈丹平 陈国荣. SO42-对Mn掺杂硫磷酸盐玻璃结构和发光性能的影响[J]. 材料研究学报, 2011, 25(5): 517-521.
, , , , , . Effect of SO2−4 on the Structure and Luminescence Properties of Manganese-doped Sulfophosphate Glasses[J]. Chin J Mater Res, 2011, 25(5): 517-521.

全文: PDF(947 KB)  
摘要: 采用高温熔融法制备了Mn掺杂P2O5--ZnO--ZnSO4--Na2O硫磷酸盐玻璃, 研究了不同SO42-含量下玻璃结构的变化以及Mn离子的发光性能。结果表明: 在409 nm光激发下, Mn离子掺杂硫磷酸盐玻璃可产生500 nm到750 nm的宽带发射, SO42-的引入改变了Mn2+周围的配位场, 使Mn2+发光强度和发光峰半高宽增加。
关键词 无机非金属材料发光硫磷酸盐玻璃Mn    
Abstract:Manganese-doped sulfophosphate glasses (P2O5–ZnO–ZnSO4–Na2O) were synthesized by traditional melting–quenching method. The structure and luminescence properties of the glasses with varying SO2−4 content were studied. The results revealed that a broad emission band of Mn2+ from 500 to 750 nm excited by a 409 nm laser was observed. With the introduction of SO2−4 , the ligand field around Mn2+ was affected, resulting in the increasing of the luminescence intensity and full width at half maximum (FWHM) of Mn2+ emission.
Key wordsinorganic non-metallic materials    luminescence properties    sulfophosphate glass    Mn
收稿日期: 2011-07-01     
ZTFLH: 

TQ171

 
基金资助:

中央高校基本科研业务费专项资金WD1014035和上海市重点学科建设项目B502资助。

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