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材料研究学报  2008, Vol. 22 Issue (3): 327-332    
  论文 本期目录 | 过刊浏览 |
NZ2合金在不同介质中腐蚀后氧化膜的晶体结构
章海霞;李中奎;张建军;郑欣;FRUCHART Daniel; HLIL El Kébir;孙军;周廉
西安交通大学材料科学与工程学院
西安交通大学材料科学与工程学院
引用本文:

章海霞; 李中奎; 张建军; 郑欣; FRUCHART Daniel; HLIL El; Kébir; 孙军 ; 周廉 . NZ2合金在不同介质中腐蚀后氧化膜的晶体结构[J]. 材料研究学报, 2008, 22(3): 327-332.

全文: PDF(903 KB)  
摘要: 通过分析NZ2合金在360℃、18.6 MPa含锂水和400℃、10.3 MPa蒸汽中腐蚀后氧化膜的晶体结构,研究了腐蚀过程中氧化膜晶体结构的转变及其对锆合金耐腐蚀性能的影响. 结果表明:NZ2合金腐蚀后氧化膜的结构以单斜氧化锆为主, 还有一定量畸变了的四方氧化锆.四方氧化锆主要由氧化膜内的压应力稳定. 随着腐蚀时间的延长,氧化膜与金属间的界面向前推进, 当氧化锆中的压应力不足以稳定四方相时,四方氧化锆转变为单斜氧化锆. 从氧化膜与金属间的界面到氧化膜的外表面,四方相的含量不断降低, 界面处的四方相含量最高. NZ2合金在360℃含锂水中腐蚀时,氧化膜内四方相向单斜相的转变速度比在400℃蒸汽中腐蚀时四方相向单斜相的转变速度低得多.四方相向单斜相的转变是决定锆合金抗腐蚀性能的主要因素, 四方相转变得越快,其含量越低, 腐蚀速率越高.
关键词 材料失效与保护氧化膜晶体结构    
Key words
收稿日期: 2007-05-08     
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