基于<strong>MOFs</strong>的复合材料制备及其对亚甲基蓝染料的吸附性能

doi:10.11901/1005.3093.2021.002

材料研究学报

2021, Vol. 35

Issue (11): 866-872 DOI: 10.11901/1005.3093.2021.002

研究论文

本期目录 | 过刊浏览

基于MOFs的复合材料制备及其对亚甲基蓝染料的吸附性能

张向阳¹, 章奇羊³, 汤涛¹, 郑涛¹, 柳浩¹, 刘国金¹, 朱海霖¹, 朱海峰²(

)

^1.浙江理工大学浙江省纤维材料和加工技术研究重点实验室杭州 310018
^2.浙江理工大学服装学院杭州 310018
^3.绍兴市生态环境宣教与机排中心绍兴 312000

Fabrication of Composite Material Based on MOFs and its Adsorption Properties for Methylene Blue Dyes

ZHANG Xiangyang¹, ZHANG Qiyang³, ZHENG Tao¹, TANG Tao¹, LIU Hao¹, LIU Guojin¹, ZHU Hailin¹, ZHU Haifeng²(

)

^1.Zhejiang Provincial Key Laboratory of Fiber Materials and Manufacturing Technology, Zhejiang Sci-Tech University, Hangzhou 310018, China
^2.School of Fashion Design & Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, China
^3.Shaoxing Eco-Environmental Education and Aircraft Platoon Center, Shaoxing 312000, China

引用本文:

张向阳, 章奇羊, 汤涛, 郑涛, 柳浩, 刘国金, 朱海霖, 朱海峰. 基于MOFs的复合材料制备及其对亚甲基蓝染料的吸附性能[J]. 材料研究学报, 2021, 35(11): 866-872.
Xiangyang ZHANG, Qiyang ZHANG, Tao ZHENG, Tao TANG, Hao LIU, Guojin LIU, Hailin ZHU, Haifeng ZHU. Fabrication of Composite Material Based on MOFs and its Adsorption Properties for Methylene Blue Dyes[J]. Chinese Journal of Materials Research, 2021, 35(11): 866-872.

全文: PDF(5593 KB) HTML

摘要:

用甲基丙烯酸酐对锆基MOFs UiO-66-NH₂进行改性，然后用紫外光固化将改性后的MOFs UiO-66-NH₂负载于聚丙烯(PP)非织造布制备出MOFs与非织造布(PSP)复合材料。分析了改性前后UiO-66-NH₂的晶型和形貌变化并测试了MOFs(UiO-66-NH₂-MET)与PP非织造布的结合牢度，测试了吸附条件对PSP复合材料吸附性能的影响。结果表明：通过在UiO-66-NH₂结构中修饰甲基丙烯酸酐基团制备出UiO-66-NH₂-MET，改性后MOFs的晶型结构没有变化，保留了原有的框架结构；UiO-66-NH₂-MET与PP非织造布间有良好的结合牢度。PSP复合材料经历多次水洗后未发生质量损失，保留了良好的吸附效果；PSP复合材料吸附亚甲基蓝(MB)的最佳条件为：染料的初始浓度为50 mg/L，吸附时间为300 min，pH值为9。

关键词 ：有机高分子材料, PSP复合材料, 吸附, 染料, 非织造布

Abstract：

Zr-based metal-organic frameworks (MOFs) UIO-66-NH₂ was modified with methacrylate anhydride, and then the modified MOFs were deposited onto polypropylene (PP) nonwoven fabric while real-time curing assisted by UV irradiation to prepare composite of MOFS/nonwoven fabric (PSP). The changes of crystal form and morphology of UIO-66-NH₂ before and after modification were analyzed, and the binding fastness of MOFs (UIO-66-NH2-MET) to PP nonwovens was examined, and the effect of adsorption conditions on the adsorption properties of PSP composite was investigated. The results show that UIO-66-NH2-MET could be prepared through modifying the UIO-66-NH2 structure with methacrylate anhydride group. After modification, the crystal structure of MOFs remained unchanged and the original frame structure was retained. UIO-66-NH2-MET has good fastness on PP nonwovens. No mass loss occurred after repeated washing, and the PSP composite retained good adsorption effect. The optimum conditions for PSP composites to adsorb methylene blue (MB) are as follows: The initial concentration of the dye was 50 mg/L, the adsorption time was 300 min, and the pH value was 9.

Key words： organic polymer materials PSP composite adsorption dyes nonwovens

收稿日期: 2021-01-11

ZTFLH:

TS179

基金资助:浙江省自然科学基金(LQ19E030022)

作者简介: 张向阳，男，1996年生，硕士生

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	张向阳
	章奇羊
	汤涛
	郑涛
	柳浩
	刘国金
	朱海霖
	朱海峰
44.8K

链接本文:

https://www.cjmr.org/CN/10.11901/1005.3093.2021.002 或 https://www.cjmr.org/CN/Y2021/V35/I11/866

图1 MB的标准吸附曲线

图2 UiO-66-NH2改性前后的红外图和改性后的核磁图

图3 改性前后UiO-66-NH2的TEM照片、TG曲线和XRD图

图4 PSP布元素的分布

图5 PP非织造布和PSP复合材料的FESEM照片

图6 PSP复合材料的吸附量和质量分数与吸附时间的关系

图7 PSP复合材料对不同初始浓度染料的吸附量与吸附时间的关系

图8 PSP复合材料对染料的吸附量与pH值的关系

图9 PSP复合材料的吸附量与温度的关系

图10 PSP复合材料对MB的拟一阶动力学和拟二阶动力学线性拟合方程

表1 拟一阶和拟二阶动力学常数

1	Fernandez C, Soledad Larrechi M, Pilar Callao M. An analytical overview of processes for removingorganic dyes from wastewater effluents [J]. Trac-Trends Anal. Chem., 2010, 29(10): 1202
2	Yasemin B, Haluk A. A. Kinetics and thermodynamics study of methylene blue adsorption on wheat shells [J]. Desalination. 2005, 194(1-3): 259
3	Naef A. A Qasem, Rached Ben-Mansour. Energy and productivity efficient vacuum pressure swing adsorption process to separate CO₂ from CO₂/N₂ mixture using Mg-MOF-74: A CFD simulation [J]. Appl.Energy., 2018, (209): 190
4	Wen T Y, Ming B L, Ya x Y, et al. Metal-organic framework (MOF) showing both ultrahigh As(V) and As(III) removal from aqueous solution [J]. J. Solid State Chem., 2019 (269): 264
5	Shen K, Chen X, Chen J, et al. Development of MOF-derived carbon-based nanomaterials for efficient catalysis [J]. Acs Catalysis., 2016, 6(9): 5887
6	Bhatt A. S., Sakaria P. L., Vasudevan M.,et al. Adsorption of an anionic dye from aqueous medium by organoclays:equilibrium modeling, kinetic and thermodynamic exploration [J]. RSC Adv., 2012(2): 8663
7	Ayati A., Shahrak M. N., Tanhaei B., Sillanpaa M.. Emerging adsorptive removal of azo dye by metal-organic frameworks [J]. Chemosphere, 2016 (160): 30
8	Jawada Ali H., Ahmed Saud Abdulhameedc, Reghioua Abdallah,et al. Zwitterion composite chitosan-epichlorohydrin/zeolite for adsorption of methylene blue and reactive red 120 dyes [J]. Int. J. Biol. Macromol., 2020 (163): 756
9	Chen Q, He Q Q, Lv M M, et al. Selective adsorption of cationic dyes by UiO-66-NH₂ [J]. Appl. Surf. Sci., 2015 (327): 77
10	Yang Q X, Zhao Q Q, Ren S S, et al. Assembly of Zr-MOF crystals onto magnetic beads as a highly adsorbent for recycling nitrophenol [J]. Chem. Eng. J., 2017(323): 74
11	Kitao T, Zhang Y, Kitagawa S, et al. Hybridization of MOFs and polymers [J]. Chem. Soc. Rev., 2017, 46(11): 3108-3133
12	Yu Z, Lu L J, Lu L X, et al. Preparation and characterization of anti-oxidation packaging films based on poly (acrylic acid) grafting polypropylene surface [J]. Highpolymer Mater Sci ＆ Eng, 2020, 36(07): 134
12	于振, 卢莉璟, 卢立新等. 聚丙烯酸表面接枝改性聚丙烯抗氧化膜的制备与性能 [J]. 高分子材料科学与工程, 2020, 36(07): 134
13	Zhang Y Y, Dr. Xiao Feng, Li H W,et al. Photoinduced postsynthetic polymerization of a metal-organic framework toward a flexible stand‐alone membrane [J]. Angew, Chemie, 54(2015): 4259
14	Wang Y X, Xie H, Huang L, et al. Synthesis of methacrylic anhydride by transanhydrization [J]. J. Nanjing U. Sci Techno: Nat Sci Ed., 2019, 41(06): 761
14	王亚鑫, 谢晖, 黄莉等. 酐交换法制备甲基丙烯酸酐的研究 [J]. 南京工业大学学报(自然科学版), 2019, 41(6): 761
15	Huang Y T. Synthesis and gas adsorption of UiO-66 type metal-organic frameworks [D]. J. South China Univ Techno: Nat Sci Ed., 2012
15	黄钰婷. UiO-66类型MOFs材料的合成及其气体吸附性能研究 [D]. 华南理工大学, 2012

[1]	宋莉芳, 闫佳豪, 张佃康, 薛程, 夏慧芸, 牛艳辉. 碱金属掺杂MIL125的CO₂ 吸附性能[J]. 材料研究学报, 2023, 37(9): 649-654.
[2]	邵鸿媚, 崔勇, 徐文迪, 张伟, 申晓毅, 翟玉春. 空心球形AlOOH的无模板水热制备和吸附性能[J]. 材料研究学报, 2023, 37(9): 675-684.
[3]	余谟鑫, 张书海, 朱博文, 张晨, 王晓婷, 鲍佳敏, 邬翔. N掺杂生物炭的制备及其对Co²⁺ 的吸附性能[J]. 材料研究学报, 2023, 37(4): 291-300.
[4]	叶姣凤, 王飞, 左洋, 张钧翔, 罗晓晓, 冯利邦. 兼具高强度、高韧性和自修复性能的环氧树脂改性热可逆聚氨酯[J]. 材料研究学报, 2023, 37(4): 257-263.
[5]	李瀚楼, 焦晓光, 朱欢欢, 赵晓欢, 矫庆泽, 冯彩虹, 赵芸. 支链含氟聚酯的合成和性能[J]. 材料研究学报, 2023, 37(4): 315-320.
[6]	马逸舟, 赵秋莹, 杨路, 裘进浩. 热塑型聚酰亚胺/聚偏氟乙烯全有机复合薄膜的制备及其介电储能[J]. 材料研究学报, 2023, 37(2): 89-94.
[7]	杨琴, 王振, 房春娟, 王若迪, 高大航. 力学性能可控的CMC/AA/CB[8]/BET凝胶的制备及其吸附性[J]. 材料研究学报, 2022, 36(8): 628-634.
[8]	殷洁, 胡云涛, 刘慧, 杨逸霏, 王艺峰. 基于电沉积技术构建聚苯胺/海藻酸膜及电化学性能研究[J]. 材料研究学报, 2022, 36(4): 314-320.
[9]	申延龙, 李北罡. 磁性氨基酸功能化海藻酸铝凝胶聚合物的制备及对偶氮染料的超强吸附[J]. 材料研究学报, 2022, 36(3): 220-230.
[10]	龙庆, 王传洋. 不同碳黑含量PMMA的热降解行为和动力学分析[J]. 材料研究学报, 2022, 36(11): 837-844.
[11]	蒋平, 吴丽华, 吕太勇, José Pérez-Rigueiro, 王安萍. 蜘蛛大壶状腺丝的反复拉伸力学行为和性能[J]. 材料研究学报, 2022, 36(10): 747-759.
[12]	鄢俊, 杨进, 王涛, 徐桂龙, 李朝晖. 有机硅油改性水性酚醛的制备及其性能[J]. 材料研究学报, 2021, 35(9): 651-656.
[13]	余谟鑫, 蒯乐, 王亮, 张晨, 王晓婷, 陈启厚. 吲哚基掺氮分级多孔炭的制备及其对酸性橙74的吸附性能[J]. 材料研究学报, 2021, 35(9): 667-674.
[14]	阙爱珍, 朱桃玉, 郑玉婴. 中空磁性氧化石墨烯的制备及其对亚甲基蓝吸附性能[J]. 材料研究学报, 2021, 35(7): 517-525.
[15]	张昊, 李帆, 常娜, 王海涛, 程博闻, 王攀磊. 羧酸型接枝淀粉吸附树脂的制备和对染料的去除性能[J]. 材料研究学报, 2021, 35(6): 419-432.

Viewed

Full text

Abstract

Cited

Shared

Discussed