金属有机框架材料<strong>MIL-53(Al)-F127</strong>对双酚<strong>A</strong>的吸附性能

doi:10.11901/1005.3093.2019.466

材料研究学报

2020, Vol. 34

Issue (5): 353-360 DOI: 10.11901/1005.3093.2019.466

研究论文

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金属有机框架材料MIL-53(Al)-F127对双酚A的吸附性能

孙玥, 李大伟, 魏取福(

)

江南大学生态纺织教育部重点实验室无锡 214122

Adsorption Properties of Metal-organic Framework Material MIL-53(Al)-F127 for Bisphenol A

SUN Yue, LI Dawei, WEI Qufu(

)

Key Laboratory of Eco-textiles, Ministry of Education, Jiangnan University, Wuxi 214122, China

引用本文:

孙玥, 李大伟, 魏取福. 金属有机框架材料MIL-53(Al)-F127对双酚A的吸附性能[J]. 材料研究学报, 2020, 34(5): 353-360.
Yue SUN, Dawei LI, Qufu WEI. Adsorption Properties of Metal-organic Framework Material MIL-53(Al)-F127 for Bisphenol A[J]. Chinese Journal of Materials Research, 2020, 34(5): 353-360.

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摘要:

采用一步溶剂热法制备具有介孔结构金属有机框架材料MIL-53(Al)-F127，用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、X射线衍射仪(XRD)、傅里叶红外变换光谱仪(FTIR)、全自动比表面积及孔隙度分析仪(BET)等手段表征其形貌和结构，探究其对双酚A(BPA)的吸附性能并与微孔结构的MIL-53(Al)对比，研究了吸附剂的含量、pH以及温度对其吸附性能的影响。结果表明，介孔结构金属有机框架材料MIL-53(Al)-F127对双酚A具有良好的吸附性能；在pH值为6、温度为30℃条件下MIL-53(Al)-F127在20 min左右达到最大平衡吸附量为27.2 mg/g，去除率达到92%。其吸附动力学模型拟合结果，符合准二级动力学曲线。

关键词 ：复合材料, 金属有机框架, 吸附, MIL-53(Al), MIL-53(Al)-F127, 双酚A(BPA)

Abstract：

Mesostructured metal-organic framework material MIL-53(Al)-F127 was synthesized by one-step solvothermal method, and the morphology and structure of MIL-53(Al)-F127 were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffractometer (XRD), Fourier-transform infrared spectrometer (FTIR) and N₂adsorption-desorption (BET). The adsorption performance of MIL-53(Al)-F127 and the microporous structure MIL-53(Al) on bisphenol A in aqueous solution and the influence of the adsorbent concentration, pH, temperature were comparatively investigated. Results show that MIL-53(Al)-F127 exhibited good adsorption properties for bisphenol A in aqueous solution. The optimum pH level for the removal of BPA using MIL-53(Al)-F127 were 6. The optimum temperature for the sorption behavior of BPA on the sorbent was 30℃. The equilibrium sorption amounts of BPA on MIL-53-(Al)-F127 reached approximately 27.2 mg/g, the removal efficiency was 92% after approximately 20 min. The sorption kinetics of BPA were found to follow the quasi second order dynamic model.

Key words： composite metal-organic framework adsorption MIL-53(Al) MIL-53(Al)-F127 bisphenol A(BPA)

收稿日期: 2019-10-09

ZTFLH:

TQ424.3

基金资助:江苏省自然科学基金(BK20180628);中央高校基本科研业务费专项资金(JUSRP51907A);江苏高校优势学科建设工程项目

作者简介: 孙玥，女，1996年生，硕士生

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https://www.cjmr.org/CN/10.11901/1005.3093.2019.466 或 https://www.cjmr.org/CN/Y2020/V34/I5/353

图1 吸附剂MIL-53(Al)和MIL-53(Al)-F127的 SEM和TEM照片

图2 MIL-53(Al)和MIL-53(Al)-F127的傅里叶红外变换光谱

图3 吸附剂MIL-53(Al)和MIL-53(Al)-F127的X-射线衍射谱图

图4 吸附剂MIL-53(Al)和MIL-53(Al)-F127的N2吸附-脱附曲线和孔径分布曲线

图5 吸附剂MIL-53(Al)和MIL-53(Al)-F127的吸附动力学表征和准一级以及准二级动力学模型拟合

图6 吸附剂含量对BPA去除率的影响

图7 溶液的pH值对BPA去除率的影响

图8 温度对BPA去除率的影响

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