类表面织构化镍基复合涂层的摩擦磨损性能

doi:10.11901/1005.3093.2015.114

材料研究学报

2015, Vol. 29

Issue (9): 679-685 DOI: 10.11901/1005.3093.2015.114

本期目录 | 过刊浏览

类表面织构化镍基复合涂层的摩擦磨损性能

张玉福^1,²,杨贵荣¹(

),黄超鹏¹,宋文明^1,²,李健³,吕晋军⁴,郝远¹

1. 兰州理工大学省部共建有色金属先进加工与再利用国家重点实验室兰州 730050
2. 甘肃蓝科高新石化装备股份有限公司兰州 730070
3. 武汉材料保护研究所武汉 430030
4. 西北大学化学与材料科学学院西安 710069

Wear Resistance of a Texture-like Nickel-based Composite Coating

Yufu ZHANG^1,²,Guirong YANG^1,^**(

),Chaopeng HUANG¹,Wenming SONG^1,²,Jian LI³,Jinjun LV⁴,Yuan HAO¹

1. State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou 730050, China
2. Lanzhou Petroleum Machinery Institute, Lanzhou 730070, China
3. Wuhan Research Institute of Materials Protection, Wuhan 430030, China
4. College of Chemistry and Materials Science, Northwest University, Xi’an 710069, China

引用本文:

张玉福,杨贵荣,黄超鹏,宋文明,李健,吕晋军,郝远. 类表面织构化镍基复合涂层的摩擦磨损性能[J]. 材料研究学报, 2015, 29(9): 679-685.
Yufu ZHANG, Guirong YANG, Chaopeng HUANG, Wenming SONG, Jian LI, Jinjun LV, Yuan HAO. Wear Resistance of a Texture-like Nickel-based Composite Coating[J]. Chinese Journal of Materials Research, 2015, 29(9): 679-685.

全文: PDF(5937 KB) HTML

摘要:

在低碳钢表面添加质量分数为20%的WC和6%的石墨颗粒, 采用真空熔覆方法制备出具有类织构切面形貌的镍基合金(Ni⁰)复合涂层, 研究了复合涂层的显微组织形貌及形成机理、相组成以及干摩擦条件下的摩擦磨损性能, 并与镍基合金(Ni⁰)、碳化钨增强镍基合金(Ni⁰+20%WC)、石墨改性镍基合金(Ni⁰+6%石墨)三种涂层进行了比较。结果表明, WC呈不连续的三维网状分布在镍基合金基体中, 镍基合金主要由基体相γ-Ni, 铬化物硬质相CrB、Cr₇C₃、Cr₂₃C₆和共晶相Ni₃B、Ni₃Si构成; WC和石墨的单独加入都能提高复合涂层的摩擦磨损性能, 类织构组织复合熔覆层的摩擦磨损性能优于相同组成的硬质颗粒单独弥散分布的复合熔覆层; 在WC和镍基合金基体组成的类织构形貌结构和石墨润滑相的共同影响下, 复合涂层比单一镍基合金涂层的耐磨性提高大约9.6倍。

关键词 ：材料失效与保护, 镍基复合涂层, 真空熔覆, 类织构, WC

Abstract：

A nickel-based (Ni⁰) composite coating, which was reinforced with 20%WC and 6% graphite particles and has a texture-like section morphology, was fabricated on steel substrate by vacuum cladding technology. Then its microstructure and tribological property under dry friction condition were characterized in comparison with other three coatings (Ni⁰, Ni⁰+20%WC and Ni⁰+6% graphite). The results show that the WC particles evenly distributed in the nickel-based (Ni⁰) alloy coatings and formed a special 3D reticular microstructure. The Ni-based alloy coating is mainly composed of γ-Ni solid solution, hard phases (Cr₇C₃, Cr₂₃C₆, CrB) and eutectic phases (Ni₃Si, Ni₃B). The cladd composite coating consisted of Ni⁰ with WC and graphite particles exhibits the highest wear resistance among the test coatings. The combination of texture-like structure (which was composed of WC particles and nickel base alloy) and graphite lubricant promoted the abrasion resistance of the composite coating by about 9.6 times in comparison to the pure Ni⁰coating.

Key words： materials failure and protection nickel-based alloy vacuum cladding texture WC

收稿日期: 2015-03-05

基金资助:* 国家自然科学基金51205178和甘肃省自然科学基金1208RJZA189资助项目。

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	张玉福
	杨贵荣
	黄超鹏
	宋文明
	李健
	吕晋军
	郝远
44.8K

链接本文:

https://www.cjmr.org/CN/10.11901/1005.3093.2015.114 或 https://www.cjmr.org/CN/Y2015/V29/I9/679

图1 真空熔覆Ni0+WC涂层的XRD图谱

图2 真空熔覆涂层的组织形貌

图3 四种涂层磨损率和摩擦系数以及对磨件的磨损

表1 Ni0+G的磨屑成分EDS分析结果

图4 涂层的磨损形貌SEM像

图5 Ni0+WC+G涂层摩擦表面形貌的SEM像及其中C元素分布EDS图片

1	Przyby?owicz J,Kusiński J, Structure of laser cladded tungsten carbide composite coatings, Journal of Materials Processing Technology, 109(1), 154(2001)
2	Badisch E,Kirchga?ner M, Influence of welding parameters on microstructure and wear behaviour of a typical NiCrBSi hardfacing alloy reinforced with tungsten carbide, Surface and Coatings Technology, 202(24), 6016(2008)
3	Sari N Y,Yilmaz M, Improvement of wear resistance of wire drawing rolls with Cr-Ni-B-Si+WC thermal spraying powders, Surface and Coatings Technology, 202(13), 3136(2008)
4	Murthy J K N,Venkataraman B, Abrasive wear behaviour of WC–CoCr and Cr3C2-20(NiCr) deposited by HVOF and detonation spray processes, Surface and Coatings Technology, 200(8), 2642(2006)
5	Tobar M J,Alvarez C, Amado J M, Morphology and characterization of laser clad composite NiCrBSi-WC coatings on stainless steel, Surface and coatings Technology, 200(22), 6313(2006)
6	ZHU Dingyi,GUAN Xiangfeng, DUI Weizhen, Preparation and structure properties of the nickel-graphite high temperature self-lubricating materials, The Chinese Journal of Nonferrous Metals, 14(5), 707(2004)
6	(朱定一, 关翔锋, 兑卫真, 镍-石墨高温自润滑材料的熔炼制备及其组织性能, 中国有色金属学报, 14(5), 707(2004))
7	WANG Qingnian,SUI Zhongxiang, Development of some foreign metal-matrix self-lubricating composites, Tribology, 17(1), 89(1997)
7	(王庆年, 隋忠祥, 国外某些金属基自润滑复合材料的开发与进展, 摩擦学学报, 17(1), 89(1997))
8	Liu X B,Liu H Q, Liu Y F, Effects of temperature and normal load on tribological behavior of nickel-based high temperature self-lubricating wear-resistant composite coating, Composites Part B: Engineering, 53, 347(2013)
9	ZHAO Wenjie,WANG Liping, XUE Qunji, Development and research progress of surface texturing on improving tribological performance of surface, Tribology, 31(6), 622(2011)
9	(赵文杰, 王立平, 薛群基, 织构化提高表面摩擦学性能的研究进展, 摩擦学学报, 31(6), 622(2011)
10	HU Tianchang,HU Litian, DING Qi, Tribological properties of laser textured surfaces of 45# steel under dry friction, Tribology, 30(1), 46(2010)
10	(胡天昌, 胡丽天, 丁奇, 45#钢表面激光织构化及其干摩擦特性研究, 摩擦学学报, 30(1), 46(2010))
11	HU Tianchang,HU Litian, ZHANG Yongsheng, Preparation of composite lubrication structure and its tribological properties on 45# Steel Surface, Tribology, 32(1), 14(2012)
11	(胡天昌, 胡丽天, 张永胜, 45#钢表面复合润滑结构的制备及其摩擦性能研究, 摩擦学学报, 32(1), 14(2012))
12	Liyanage T,Fisher G, Gerlich A P, Influence of alloy chemistry on microstructure and properties in NiCrBSi overlay coatings deposited by plasma transferred arc welding (PTAW), Surface and Coatings Technology, 205(3), 759(2010)
13	LU Qi,LI Jinguo, JIN Tao, ZHOU Yizhou, SUN Xiaofeng, HU Zhuangqi, Competitive growth in bi-crystal of Ni-based superalloys during directional solidification, Acta Metallurgica Sinica, 46(6), 641(2011)
13	(卢崎, 李金国, 金涛, 周亦胄, 孙晓峰, 胡壮麒, 镍基双晶高温合金定向凝固过程中的竞争生长, 金属学报, 46(6), 641(2011))
14	Song W M,Yang G R, Hao Y, Lu J J, Microstructure and wear behaviour of Ni-based surface coating on copper substrate, Wear, 262(7), 868(2007)
15	J. Rodriguez, A. Martin, R. Fernández, J.E. Fernández,An experimental study of the wear performance of NiCrBSi thermal spray coatings, Wear, 255(7), 950(2003)
16	Wang H,Xia W M, Jin Y S, A study on abrasive resistance of Ni-based coating with a WC hard phase, Wear, 195(1), 47(1996)
17	YANG Guirong,ZHAO Hu, SONG Wenming, LI Jian, MA Ying, Wear behaviour of Ni-based composite coating with directional solidification structure, Chinese Journal of Materials Research, 27(3), 279(2013)
17	(杨贵荣, 赵虎, 宋文明, 李健, 马颖, 定向凝固镍基复合涂层的摩擦磨损性能, 材料研究学报, 27(3), 279(2013))

[1]	高巍, 刘江南, 魏敬鹏, 要玉宏, 杨巍. TC4钛合金表面氧化亚铜掺杂微弧氧化层的结构和性能[J]. 材料研究学报, 2022, 36(6): 409-415.
[2]	杨留洋, 谭卓伟, 李同跃, 张大磊, 邢少华, 鞠虹. 利用WBE及EIS测试技术对管道缺陷区动态冲刷腐蚀行为的研究[J]. 材料研究学报, 2022, 36(5): 381-391.
[3]	陈铮, 杨芳, 王成, 杜瑶, 卢壹梁, 朱圣龙, 王福会. 惰性无机填料比例和颗粒尺寸对纳米Al/Al₂O₃ 改性有机硅涂料抗高温氧化行为的影响[J]. 材料研究学报, 2022, 36(4): 271-277.
[4]	李玉峰, 张念飞, 刘丽爽, 赵甜甜, 高文博, 高晓辉. 含磷石墨烯的制备及复合涂层的耐蚀性能[J]. 材料研究学报, 2022, 36(12): 933-944.
[5]	陈艺文, 王成, 娄霞, 李定骏, 周科, 陈明辉, 王群昌, 朱圣龙, 王福会. 无机复合涂层对CB2铁素体耐热钢在650℃水蒸气中的防护[J]. 材料研究学报, 2021, 35(9): 675-681.
[6]	唐荣茂, 刘光明, 刘永强, 师超, 张帮彦, 田继红, 甘鸿禹. 用电化学噪声技术研究Q235钢在含氯盐模拟混凝土孔隙液中的腐蚀行为[J]. 材料研究学报, 2021, 35(7): 526-534.
[7]	张大磊, 魏恩泽, 荆赫, 杨留洋, 豆肖辉, 李同跃. 超级铁素体不锈钢表面超疏水结构的制备及其耐腐蚀性能[J]. 材料研究学报, 2021, 35(1): 7-16.
[8]	王冠一, 车欣, 张浩宇, 陈立佳. Al-5.4Zn-2.6Mg-1.4Cu合金板材的低周疲劳行为[J]. 材料研究学报, 2020, 34(9): 697-704.
[9]	黄安然, 张伟, 王学林, 尚成嘉, 范佳杰. 铁素体不锈钢在高温尿素环境中的腐蚀行为研究[J]. 材料研究学报, 2020, 34(9): 712-720.
[10]	公维炜, 杨丙坤, 陈云, 郝文魁, 王晓芳, 陈浩. 扫描电化学显微镜原位观察碳钢涂层缺陷处的交流腐蚀行为[J]. 材料研究学报, 2020, 34(7): 545-553.
[11]	郭铁明, 徐秀杰, 张延文, 宋志涛, 董志林, 金玉花. Q345q桥梁钢和Q345qNH耐候钢在模拟工业大气+除冰盐混合介质中的腐蚀行为[J]. 材料研究学报, 2020, 34(6): 434-442.
[12]	朱金阳, 谭成通, 暴飞虎, 许立宁. 一种新型含Al低Cr合金钢在模拟油田采出液环境下的CO₂腐蚀行为[J]. 材料研究学报, 2020, 34(6): 443-451.
[13]	梁新磊, 刘茜, 王刚, 王震宇, 韩恩厚, 王帅, 易祖耀, 李娜. 氧化石墨烯改性环氧隔热涂层的耐蚀和隔热性能研究[J]. 材料研究学报, 2020, 34(5): 345-352.
[14]	王志虎,张菊梅,白力静,张国君. 水热处理对AZ31镁合金微弧氧化陶瓷层组织结构及耐蚀性的影响[J]. 材料研究学报, 2020, 34(3): 183-190.
[15]	段体岗, 黄国胜, 马力, 彭文山, 张伟, 许立坤, 林志峰, 何华, 毕铁满. Q235/Ni-Co基自修复涂层的制备和耐蚀性能[J]. 材料研究学报, 2020, 34(10): 777-783.

Viewed

Full text

Abstract

Cited

Shared

Discussed