Fe含量对FeSiBPCu合金非晶晶化行为与磁性能的影响

doi:10.11901/1005.3093.2014.747

材料研究学报

2015, Vol. 29

Issue (4): 284-290 DOI: 10.11901/1005.3093.2014.747

本期目录 | 过刊浏览

Fe含量对FeSiBPCu合金非晶晶化行为与磁性能的影响

崔立英¹(

),齐民²,牧野彰宏³

1. 大连海事大学交通运输装备与海洋工程学院大连 116026
2. 大连理工大学材料科学与工程学院大连 116024
3. 东北大学金属材料研究所日本仙台 980-8577

Effect of Fe Content on Crystallization Behaviors and Magnetic Properties of Amorphous Alloys Fe_x(SiB)_96-_xP₃Cu₁

Liying CUI^1,^**(

),Min QI²,Akihiro MAKINO³

1. Transportation Equipments and Ocean Engineering College, Dalian Maritime University, Dalian 116026, China
2. School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China
3. Institute for Materials Research, Tohoku University, Sendai 980-8577, Japan

引用本文:

崔立英,齐民,牧野彰宏. Fe含量对FeSiBPCu合金非晶晶化行为与磁性能的影响[J]. 材料研究学报, 2015, 29(4): 284-290.
Liying CUI, Min QI, Akihiro MAKINO. Effect of Fe Content on Crystallization Behaviors and Magnetic Properties of Amorphous Alloys Fe_x(SiB)_96-_xP₃Cu₁[J]. Chinese Journal of Materials Research, 2015, 29(4): 284-290.

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摘要:

用熔体快淬法制备不同Fe含量的FeSiBPCu非晶合金并进行快速退火处理, 对其晶化行为和磁性能进行了深入研究。结果表明: 随着Fe含量的增加, FeSiBPCu合金的表观晶化激活能逐渐降低; FeSiBPCu合金的整个晶化过程析出相一致, 与Fe含量无关; Fe_x(SiB)_96-_xP₃Cu₁ (x=80, 83 and 85)合金退火后得到均匀的纳米晶组织, 晶粒尺寸小于20 nm, 但是退火态Fe₇₈Si₆B₁₂P₃Cu₁和Fe₇₅Si₈B₁₃P₃Cu₁的晶粒大小很不均匀, 晶粒尺寸范围为5-50 nm; 退火态Fe₈₅Si₃B₈P₃Cu₁合金表现出优异的软磁性能：矫顽力为12 A·m^-1, 饱和磁极化强度为1.87 T, 在最大磁感应强度为1.7 T时铁损仍低于1.0, 远优于广泛使用的退火态Fe₇₈Si₉B₁₃和无取向硅钢。

关键词 ：金属材料, 铁基非晶合金, 非晶晶化, 软磁性能, 表观晶化激活能

Abstract：

Crystallization behavior and soft magnetic properties of amorphous alloys Fe_x(SiB)_96-_xP₃Cu₁ (x=75, 78, 80, 83 and 85, atomic fraction, %) were investigated. It was found that the apparent activation energy for crystallization decreased with the increasing Fe content of the Fe_x(SiB)_96-_xP₃Cu₁alloys. The phases precipitated after properly complete crystallization treatment were the same for all the alloys with varying Fe content. The annealed Fe_x(SiB)_96-_xP₃Cu₁ (x=80, 83 and 85) alloys exhibited a uniform nanostructure with grain size smaller than 20 nm, while the grain sizes of the alloys with x=75 and 78 ranged from 5 nm to 50 nm. The saturation magnetization enhanced nonlinearly as the Fe content increased from 75 to 85. The nanocrystalline alloy Fe₈₅Si₃B₈P₃Cu₁exhibited excellent soft magnetic properties with a coercivity of 12 Am^-1 and a saturation magnetization of 1.87 T. The core loss values of nanocrystalline alloys Fe₈₅Si₃B₈P₃Cu₁ and Fe₈₃Si₄B₉P₃Cu₁ were still less than 1.0 Wkg^-1 even if the saturation magnetic induction intensity was up to 1.7 T, which were superior to that of the commercial Fe₇₈Si₉B₁₃ alloy and non-orientated silicon steel.

Key words： metallic materials Fe-based amorphous alloy nanocrystallization soft magnetic property activation energy

收稿日期: 2014-12-17

基金资助:* 国家自然科学基金面上项目51371042和中央高校基本科研业务费之青年骨干教师基金3132015098资助。

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图1 FeSiBPCu合金淬火态薄带的DSC扫描曲线(β=0.67 K/s)

表1 Fex(SiB)96-xP3Cu1(x=75、78、80、83和85)合金的热物性参数

图2 淬火态Fex(SiB)96-xP3Cu1(x=75、78、80、83和85)合金的微观组织和XRD谱

图3 退火态Fex(SiB)96-xP3Cu1(x=75、78、80、83和85)合金的微观组织和XRD谱

表2 退火态Fex(SiB)96-xP3Cu1(x=75、78、80、83和85)合金中晶格常数与晶粒尺寸

图4 Fex(SiB)96-xP3Cu1 (x=75, 78, 80, 83和85)合金的软磁性能

1	Y. Yoshizawa, S. Oguma, K. Yamauchi,New Fe-based soft magnetic alloys composed of ultrafine grain structure, Journal of Applied Physics, 64(10), 6044(1988)
2	K. Suzuki, N. Kataoka, A. Inoue,High saturation magnetization and soft magnetic properties of bcc Fe-Zr-B alloys with ultrafine grain structure, Materials Transactions, JIM, 31(8), 743(1990)
3	K. Suzuki, A. Makino, A. Inoue,Soft magnetic properties of nanocrystalline bcc FeZrB and FeMBCu (M=transition metal) alloys with high saturation magnetization, Journal of Applied Physics, 70(10), 100(1991)
4	M. A. Willard, D. E. Laughlin, M. E. Mechenry,Magnetic properties of hitperm (Fe, Co)88Zr7Cu4B1 magnets, Journal of Applied Physics, 84(12), 6773(1998)
5	M. A. Willard, D. E. Laughlin, M. E. Mechenry,Structure and magnetic properties of (Fe0.5Co0.5)88Zr7B4Cu1 nanocrystalline alloys, Journal of Applied Physics, 84(12), 6773(1999)
6	F. E. Luborsky, J. J. Becker, J. L. Walter, H. Liebwemann,Formation and magnetic properties of Fe-B-Si amorphous alloys, IEEE Transactions on Magnetics, 15(4), 1146(1979)
7	M. Mitera, M. Naka, T. Masumoto, N. Kazama, K. Watanabe,Effects of metalloids on the magnetic properties of iron based amorphous alloys, Physica Status Solidi (a), 49(2), K163(1978)
8	A. Makino, A. Inoue, T. Masumoto,Soft magnetic properties of nanocrystalline Fe-M-B(M=Zr, Hf, Nb) alloys with high magnetization, Nanostructured Materials, 6(5-8), 985(1995)
9	A. Makino, M. Bingo, T. Bitoh, K. Yubuta,Improvement of soft magnetic properties by simultaneous addition of P and Cu for nanocrystalline FeNbB alloys, Journal of Applied Physics, 101, 09-N117(2007)
10	A. Makino, H. Men, T. Kubota, K. Yubuta, A. Inoue,FeSiBPCu nanocrystalline soft magnetic alloys with high Bs of 19 Tesla produced by crystallizing hetero-amorphous phase, Materials Transactions, 50, 204(2009)
11	H. Men, L. Y. Cui, T. Kubota, K. Yubuta, A. Makino, A. Inoue,Fe-Rich soft magnetic FeSiBPCu hetero-amorphous alloys with high saturation magnetization, Materials Transactions, 50(6), 1330(2009)
12	A. C.Hsiao, M. E. Mchenry, D. E. Laughlin, M. R. Tamoria, V. G. Harris,Magnetic properties and crystallization kinetics of a Mn-doped FINEMET precursor amorphous alloy, IEEE Transactions on Magnetics, 37(4), 2236(2001)
13	E. Illekov,The crystallization Kinetics of Fe80Si4B16 Metallic Glass, Thermochim. Acta, 280, 289(1996)
14	R. Singhal, A. K. Majumdar,Crystallization of glassy Fe80B20-xSix (0≤x≤12) alloys, Journal of Magnetism and Magnetic Materials, 115(2-3), 245(1992)
15	H. E. Kissinger,Reaction Kinetics in Differential Thermal Analysis, Analytical Chemistry, 29(11), 1702(1957)
16	K. Suzuki, M. Kikuchi, A. Makino, T. Masumoto,Changes in microstructure and soft magnetic properties of an Fe86Zr7B6Cu1 amorphous alloy upon crystallization, Materials Transactions, 32(10), 961(1991)
17	Y. R. Zhang, R. V. Ramanujan,Microstructural observations of the crystallization of amorphous Fe-Si-B based magnetic alloys, Thin Solid Films, 505(1-2), 97(2006)
18	J. W. Christian, The Theory of Transformation in Metals and Alloys(Oxford, Pergamon Press, 1965)
19	A. Makino, T. Bitoh, A. Inoue, T. Masumoto,Nb-Poor Fe-Nb-B nanocrystalline soft magnetic alloys with small amount of P and Cu prepared by melt-spinning in air, Scripta Materialia, 48(7), 869(2003)
20	A. Makino, H. Men, K. Yubuta, T. Kubota,Soft magnetic FeSiBPCu heteroamorphous alloys with high Fe content, Journal of Applied Physics, 105(1), 013922(2009)
21	F. E. Luborsky, H. H. Liebermann,Crystallization kinetics of Fe-B amorphous alloys, Applied Physics Letters, 33(3), 233(1978)
22	H. Men, L. Y.Cui, T. Kubota, A. Makino, A. Inoue,Fe-Rich soft magnetic FeSiBPCu hetero-amorphous alloys with high saturation magnetization, Materials Transactions, 50(6), 1330(2009)

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