热浸镀锌层钛盐转化膜的制备和耐蚀性能<sup>*</sup>

doi:10.11901/1005.3093.2014.123

材料研究学报

2014, Vol. 28

Issue (7): 521-527 DOI: 10.11901/1005.3093.2014.123

本期目录 | 过刊浏览

热浸镀锌层钛盐转化膜的制备和耐蚀性能^*

许乔瑜(

),王海霞,姜瑞

华南理工大学材料科学与工程学院广州 510640

Formation and Corrosion Resistance of Titanium Containing Conversion Film on Hot-dip Galvanized Steel

Qiaoyu XU(

),Haixia WANG,Rui JIANG

School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640

引用本文:

许乔瑜,王海霞,姜瑞. 热浸镀锌层钛盐转化膜的制备和耐蚀性能^*[J]. 材料研究学报, 2014, 28(7): 521-527.
Qiaoyu XU, Haixia WANG, Rui JIANG. Formation and Corrosion Resistance of Titanium Containing Conversion Film on Hot-dip Galvanized Steel[J]. Chinese Journal of Materials Research, 2014, 28(7): 521-527.

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摘要:

制备了热浸锌层钛盐转化膜, 采用SEM、EDS表征了转化膜的表面形貌、化学成分, 采用XPS技术分析了膜层的组成, 探讨了膜层的生长过程。通过中性盐雾试验、电化学极化分析和电化学阻抗研究了膜层的耐蚀性能。结果表明, 膜层主要由含结晶水的Ti(OH)₄/TiO₂和Zn(OH)₂/ZnO组成, 随着处理时间的增加钛盐转化膜逐渐增厚, 膜层中的Ti含量逐渐增加。与未经处理的热浸镀锌层比较, 转化膜层腐蚀电流密度减小, 极化电阻和电化学阻抗显著增大, 耐蚀性明显增强。

关键词 ：材料失效与保护, 热浸镀锌, 转化膜, 钛盐, 耐蚀性能

Abstract：

A Ti containing conversion film on hot-dip galvanized steel was prepared by chemical conversion in titanium sulfate solution. The surface morphology, chemical composition and ingredients of the film were characterized by means of SEM, EDS and XPS. Then the corrosion resistance of the galvanized steel coated with Ti containing conversion film was examined by NSS test, electrochemical polarization and electrochemical impedance spectroscopy (EIS). The results show that the Ti containing conversion film gradually thickens and the Ti content of the film increases with the increasing time in the solution; the film mainly consists of Ti(OH)₄/TiO₂ and Zn(OH)₂/ZnO. In comparison with the blank galvanized steel, the corrosion current density decreases, the polarization resistance and the electrochemical impedance increase significantly for the galvanized steel with Ti containing conversion film on top. The Ti containing conversion films enhance the corrosion resistance significantly, among them a film prepared in the solution for 10 min exhibits the highest corrosion resistance.

Key words： materials failure and protection hot-dip galvanizing conversion film titanium corrosion resistance

收稿日期: 2014-03-18

基金资助:* 广东省教育部产学研结合项目2012B091100312和中央高校基本科研业务费专项资金2012ZM0011资助。

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https://www.cjmr.org/CN/10.11901/1005.3093.2014.123 或 https://www.cjmr.org/CN/Y2014/V28/I7/521

图1 钛盐转化膜生长的微观形貌

表1 图1对应的各微区的化学成分

图2 处理10 min的钛盐转化膜的XPS全谱图

表2 处理10 min 的钛盐转化膜层表面成分的XPS 分析结果

图3 钛盐转化膜的XPS解析图

图4 25℃腐蚀-免蚀-钝化条件图

图5 HDG和不同处理时间的钛盐转化膜的NSS结果

图6 HDG和不同处理时间的钛盐转化膜在5％NaCl溶液中的极化曲线

表3 图6 极化曲线的相关电化学参数

图7 HDG和不同处理时间的钛盐转化膜在5％NaCl溶液中的电化学阻抗谱

1	XU Qiaoyu,ZENG Qiuhong, Research progress in hot-dip zinc alloy coatings, Materials Review, 22(12), 52(2009)
1	(许乔瑜, 曾秋红, 热浸镀锌合金镀层的研究进展, 材料导报, 22(12), 52(2009))
2	M. Hosseini, H. Ashassi-Sorkhabi, H. A.Y. Ghiasvand,Corrosion protection of electro-galvanized steel by green conversion coatings, Journal of Rare Earths, 25(5), 537(2007)
3	A. A. O. Magalhaes, I. C. P. Margarit, O. R. Mattos,Molybdate conversion coating on zinc surfaces, Journal of Electro analytical Chemistry, 572(2), 433(2004)
4	Y. Hamlaoui, L. Tifouti, F. Pedraza,Corrosion behavior of molybdate-phosphate-silicate coatings on galvanized steel, Corrosion Science, 51(10), 2455(2009)
5	A. Amadeh, B. Pahlevani, S. Heshmati-Manesh,Effects of rare earth metal addition on surface morphology and corrosion resistance of hot-dipped zinc coatings, Corrosion Science, 44(1), 2321(2002)
6	XU Qiaoyu,ZUO Xi, Metavanadate conversion coating on the surface of hot-dip galvanized coating, Electroplating and Finishing, 30(1), 34(2011)
6	(许乔瑜, 左茜, 热浸镀锌层表面偏钒酸盐转化膜, 电镀与涂饰, 30(1), 34(2011))
7	B. Ramezanzadeh, M. M. Attar,An evaluation of the corrosion resistance and adhesion properties of an epoxy-nanocomposite on a hot-dip galvanized steel (HDG) treated by different kinds of conversion coatings, Surface and Coatings Technology, 205(19), 4649(2011)
8	G. Rossana, M. L. Abel, M. A. Baker, B. Dunn, J. F.Watts,The adsorption of an epoxy acrylate resin on aluminum alloy conversion coatings, International Journal of Adhesion and Adhesives, 31(7), 687(2011)
9	E. Alyamac, M. D. Soucek,Acrylate-based ?uorinated copolymers for high-solids coatings, Progress in Organic Coatings, 71(3), 213(2011)
10	FANG Jingli,FANG Xin, Metal surface coordination compound protection film review (II)——Anti-discoloration coordination compound film on copper alloy, Material Protection, 40(11), 77(2007)
10	(方景礼, 方欣, 金属表面配合物保护膜述评(II)——铜及铜合金的防变色配合物膜, 材料保护, 40(11), 77(2007))
11	J. M. Sykes, J. A. Hunter, G. M. Scamans, M. A. Smit, J .D. B. Sharman,Effects of thermal and mechanical treatments on a titanium-based conversion coating for aluminium alloys, Corrosion Science, 46(7), 1713(2004)
12	KANG Juan,GUO Ruiguang, FENG Qiang, Titanium-based conversion coatings on steel, Basic Sciences Journal of Textile Universities, 19(4), 381(2006)
12	(康娟, 郭瑞光, 冯强, 钢铁表面钛盐化学转化膜研究, 纺织高校基础科学学报, 19(4), 381(2006))
13	L. Q. Zhu, F. Yang, N. Ding,Corrosion resistance of the electro-galvanized steel treated in a titanium conversion solution, Surface and Coatings Technology, 201(4), 7829(2007)
14	C. L. Perkins, S. H. Lee, X. LI, S.E. Asher, T. Coutts,Identification of nitrogen chemical states in N-doped ZnO via X-ray photoelectron spectroscopy, Journal of applied physics, 97(3), 034907(2005)
15	N. Parkansky, B. Alterkop, S. Goldsmith, R. L. Boxman, Y. Rosenberg. Effect of transverse current injection during air annealing on the formation of oxides in thin Ti films. Journal of Applied Physics, 85(1), 499(1999)
16	Y. L. Jeyachandran, S. K. Narayandassa, D. Mangalaraj, C.Y. Bao, W. Li, Y. M. Liao, C. L. Zhang, L.Y. Xiao, W. C. Chen,A study on bacterial attachment on titanium and hydroxyapatite based films, Surface and Coatings Technology, 201(6), 3462(2006)
17	M. Pourbaix, R. W. Staehle, Lectures on Electrochemical Corrosion (New York, Plenum Press, 1973) p.114
18	C. Cachet, F. Ganne, S. Joiret, G. Maurin, J. Petitjean, V. Vivier, R. Wiart,EIS investigation of zinc dissolution in aerated sulphate medium Part II: zinc coatings, Electrochimica Acta, 47(21), 3409(2002)
19	C. Cachet, F. Gannea, S. Joiret, G. Maurin, J. Petitjean, V. Vivier, R. Wiart,EIS investigation of zinc dissolution in aerated sulfate medium Part I: bulk zinc, Electrochima Acta, 47(3), 514(2001)
20	F. Suedile, F. Robert, C. Roos, M. Lebrini,Corrosion inhibition of zinc by Mansoa alliacea plant extract in sodium chloride media: Extraction, Characterization and Electrochemical Studies, Electrochimica Acta, 70(12), 4(2013)

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