镍基高温合金<strong>GH3536</strong>带箔材的再结晶与晶粒长大行为

doi:10.11901/1005.3093.2022.417

材料研究学报

2023, Vol. 37

Issue (7): 535-542 DOI: 10.11901/1005.3093.2022.417

研究论文

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镍基高温合金GH3536带箔材的再结晶与晶粒长大行为

王昊¹^,², 崔君军¹^,², 赵明久¹^,²(

)

^1.中国科学院金属研究所中国科学院核用材料与安全评价重点实验室沈阳 110016
^2.中国科学技术大学材料科学与工程学院沈阳 110016

Recrystallization and Grain Growth Behavior for Strip and Foil of Ni-based Superalloy GH3536

WANG Hao¹^,², CUI Junjun¹^,², ZHAO Mingjiu¹^,²(

)

^1.CAS Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
^2.School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China

引用本文:

王昊, 崔君军, 赵明久. 镍基高温合金GH3536带箔材的再结晶与晶粒长大行为[J]. 材料研究学报, 2023, 37(7): 535-542.
Hao WANG, Junjun CUI, Mingjiu ZHAO. Recrystallization and Grain Growth Behavior for Strip and Foil of Ni-based Superalloy GH3536[J]. Chinese Journal of Materials Research, 2023, 37(7): 535-542.

全文: PDF(11098 KB) HTML

摘要:

用光学显微镜(OM)、扫描电镜(SEM)及X射线衍射分析(XRD)等手段表征不同厚度的冷轧态GH3536微米尺度带箔材退火后的显微组织和结构特征，研究这种材料的再结晶和晶粒长大的规律。结果表明，冷轧变形后的GH3536带箔材的晶粒组织呈线条状，其主相为γ相；建立了厚度为200、100和50 μm的GH3536带箔材在1050~1150℃退火10~60 min的晶粒长大方程，得到晶粒长大的激活能分别为Q_{200 μm}=800.34 kJ/mol，Q_{100 μm}=609.50 kJ/mol，Q_{50 μm}=314.79 kJ/mol。厚度较小的GH3536带箔材其晶粒长大激活能也较小，晶粒更容易长大。影响晶粒长大的因素与变形程度和析出相颗粒有关。

关键词 ：金属材料, 镍基高温合金, 带箔材, 再结晶, 晶粒长大行为

Abstract：

The microstructure and crystallographic structure characteristics of as cold-rolled strip and foil with different thicknesses of GH3536 alloy after annealing was investigated by optical microscope (OM), scanning electron microscope (SEM), transmission electron microscope (TEM) and X-ray diffractometer (XRD) to get an insight into the recrystallization and grain growth behavior. The results show that the cold rolled strip and foil of GH3536 alloy show a microstructure composed of elongated grains along the rolling directions, and its main phase was γ. The grain growth equations of the strip and foil with thicknesses of 200,100 and 50 μm annealed at 1050~1150℃ for 10~60 min were established respectively, and the relevant activation energies were acquired as follows: Q_{200 μm}=800.34 kJ/mol, Q_{100 μm}=609.50 kJ/mol and Q_{50 μm}=314.79 kJ/mol. The activation energy of the thinner strip and foil was smaller, and the grain growth was more prone to occur. The main factors affecting the grain growth were related to deformation degree and precipitated particles.

Key words： metallic materials Ni-base superalloy strip and foil recrystallization grain growth behaviors

收稿日期: 2022-07-28

ZTFLH:

TG132.32

基金资助:国家自然科学基金委员会与中国工程物理研究院联合基金(U1730140)

通讯作者: 赵明久，研究员，mjzhao@imr.ac.cn, 研究方向为特种合金带箔材

Corresponding author: ZHAO Mingjiu, Tel: (024)23975662, E-mail:mjzhao@imr.ac.cn

作者简介: 王昊，男，1997年生，硕士生

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表1 实验用GH3536带箔材的化学成分

图1 不同厚度轧制态GH3536带箔材的表面形貌

图2 200 μm厚GH3536带箔材的微观结构和SEM-EDS化学分析

表2 200 μm厚轧制态GH3536带箔材基体和颗粒物的EDS分析结果

图3 不同厚度轧制态GH3536带箔材的XRD谱

图4 三种厚度的GH3536带箔材在不同温度退火后的金相组织

图5 不同厚度GH3536带箔材在1150℃保温20 min后的XRD谱

图6 GH3536带箔材的lnt-lnD折线图

表3 GH3536带箔材的晶粒长大方程

图7 GH3536带箔材的1000/T-lnK折线图

图8 不同厚度GH3536带箔材在1050℃退火后的背散射电子像

图9 100 μm厚GH3536的TEM形貌和析出相的电子衍射图

1	Lai G Y. An investigation of the thermal stability of a commercial Ni-Cr-Fe-Mo alloy (hastelloy alloy X) [J]. Metall. Trans., 1978, 9A: 827
2	Aghaie-Khafri M, Golarzi N. Forming behavior and workability of Hastelloy X superalloy during hot deformation [J]. Mater. Sci. Eng., 2008, 486A: 641
3	Osada T, Nagashima N, Gu Y F, et al. Factors contributing to the strength of a polycrystalline nickel-cobalt base superalloy [J]. Scripta Mater., 2011, 64(9): 892 doi: 10.1016/j.scriptamat.2011.01.027
4	Pollock T M, Tin S. Nickel-based superalloys for advanced turbine engines: chemistry, microstructure and properties [J]. J. Propul. Power., 2006, 22(2): 361
5	Williams J C, Starke E A. Progress in structural materials for aerospace systems [J]. Acta Mater., 2003, 51(19): 5775 doi: 10.1016/j.actamat.2003.08.023
6	Chen W, Zhang Y, Ding Y, et al. Size effect of tensile property for ultrathin 304 stainless steel [J]. Int. J. Plast. Eng., 2014, 21(6): 71
7	Guo B, Zhou J, Shan D B, et al. Size effects of yield strength of brass foil in tensile test [J]. Acta Metall. Sin., 2008, 44(4): 419
8	Stölken J S, Evans A G. A microbend test method for measuring the plasticity length scale [J]. Acta Mater., 1998. 46(14): 5109 doi: 10.1016/S1359-6454(98)00153-0
9	Li H Z, Dong X H, Wang Q, et al. Size effects of CuZn37 brass foil in microforming [J]. Mater. Sci. Technol., 2011, 19(4): 15
9	李河宗, 董湘怀, 王倩等. CuZn37黄铜板料微塑性成形中的尺寸效应研究 [J]. 材料科学与工艺, 2011, 19 (4):15
10	Fu H H, Benson D J, Meyers M A. Analytical and computational description of effect of grain size on yield stress of metals [J]. Acta Mater., 2001, 49(13): 2567 doi: 10.1016/S1359-6454(01)00062-3
11	Lederer M, Gröger V, Khatibi G, et al. Size dependency of mechanical properties of high purity aluminium foils [J]. Mater. Sci. Eng., 2010, 527A(3) : 590
12	Mahabunphachai S, Koç M. Investigation of size effects on material behavior of thin sheet metals using hydraulic bulge testing at micro/meso-scales [J]. Int. J. Mach. Tools Manuf., 2008, 48(9): 1014 doi: 10.1016/j.ijmachtools.2008.01.006
13	James L A. The effect of grain size upon the fatigue-crack propagation behavior of alloy 718 under hold-time cycling at elevated temperature [J]. Eng. Fract. Mech., 1986, 25(3): 305 doi: 10.1016/0013-7944(86)90127-X
14	Jiang R, Everitt S, Lewandowski M, et al. Grain size effects in a Ni-based turbine disc alloy in the time and cycle dependent crack growth regimes [J]. Int. J. Fatigue, 2014, 62: 217 doi: 10.1016/j.ijfatigue.2013.07.014
15	Zhao X Y, Liu Y, Wang Y, et al. Recrystallization behaviors of 316L stainless steel fiber with different diameters [J]. Mater. Sci. Eng. Powder Metall., 2013, 18(5): 631
15	赵秀云, 刘咏, 王岩等. 不同丝径316L不锈钢纤维的再结晶行为 [J]. 粉末冶金材料科学与工程, 2013, 18(5): 631
16	Zhang C H, Xue S B, Xiao G Z, et al. Research status of micron rare metal foil [J]. Mater. Rep., 2020, 34(13): 13139
16	张聪惠, 薛少博, 肖桂枝等. 微米级稀有金属箔材研究现状 [J]. 材料导报, 2020, 34(13): 13139
17	Humphreys F J, Hatherly M. Recrystallization and Related Annealing Phenomena [M]. Holland: Elsevier, 1995: 2
18	Beck P A, Kremer J C, Demer L. Grain growth in high purity aluminum [J]. Phys. Rev. J. Arch., 1947, 71(8): 555
19	Hu H, Rath B B. On the time exponent in isothermal grain growth [J]. Metall. Mater. Trans., 1970, 1B: 3181
20	Palai P, Prabhu N, Hodgson P D, et al. Grain growth and β-Mg₁₇Al₁₂ intermetallic phase dissolution during heat treatment and its impact on deformation behavior of AZ80 Mg-alloy [J]. J. Mater. Eng. Perform., 2014, 23(1): 77 doi: 10.1007/s11665-013-0722-9
21	Humphreys F J. Particle stimulated nucleation of recrystallization at silica particles in nickel [J]. Scripta Mater., 2000, 43(7): 591 doi: 10.1016/S1359-6462(00)00442-5
22	Nes E. The effect of a fine particle dispersion on heterogeneous recrystallization [J]. Acta Metall., 1976, 24(5): 391 doi: 10.1016/0001-6160(76)90059-6
23	McQueen H J, Evangelista E, Bowles J, et al. Hot deformation and dynamic recrystallization of Al-5Mg-0.8Mn alloy [J]. Metal. Sci., 1984, 18(8): 395 doi: 10.1179/030634584790419854
24	Humphreys F J. The nucleation of recrystallization at second phase particles in deformed aluminium [J]. Acta Metall., 1977, 25(11): 1323 doi: 10.1016/0001-6160(77)90109-2

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