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材料研究学报  2023, Vol. 37 Issue (12): 952-960    DOI: 10.11901/1005.3093.2023.103
  研究论文 本期目录 | 过刊浏览 |
自组装碳/环氧树脂复合吸波涂料的制备及性能
徐文玉, 孙佳文, 朱曜峰()
浙江理工大学材料科学与工程学院 杭州 310018
Preparation and Performance of Self-assembled Carbon/Epoxy Composite Microwave Absorbing Coating
XU Wenyu, SUN Jiawen, ZHU Yaofeng()
School of Materials Science and Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, China
引用本文:

徐文玉, 孙佳文, 朱曜峰. 自组装碳/环氧树脂复合吸波涂料的制备及性能[J]. 材料研究学报, 2023, 37(12): 952-960.
Wenyu XU, Jiawen SUN, Yaofeng ZHU. Preparation and Performance of Self-assembled Carbon/Epoxy Composite Microwave Absorbing Coating[J]. Chinese Journal of Materials Research, 2023, 37(12): 952-960.

全文: PDF(8166 KB)   HTML
摘要: 

先用静电自组装-高温碳化法制备多界面自组装碳(CS@rGO)吸波剂,然后以环氧树脂(EP)为基体用物理混合法制备自组装碳/环氧树脂(CS@rGO/EP)复合功能涂料,表征其结构并研究了吸波性能和抗腐蚀性能。结果表明:这种涂料具有良好的吸波性能,吸波剂含量为20%、涂层厚度为1.1 mm的试样其最小反射损耗值为-25.03 dB;将试样在不同的介质溶液中浸渍30 d后在5%的NaCl和NaOH介质溶液中的附着力良好,其腐蚀速率较低(6.53×10-6 mm·a-1)和保护效率较高(92.86%)。

关键词 : 复合材料,  吸波材料,  静电自组装-高温碳化,  自组装碳/环氧树脂复合涂料,  防腐性能    
Abstract:

Electromagnetic absorbing material is one of the key materials for the realization of equipment stealth protection. Moreover, electromagnetic absorbing materials with high electromagnetic absorption and corrosion resistance will play a key role in special marine environments. Herein, the CS@rGO/EP composite functional coating with excellent microwave absorbing performance and anti-corrosion properties is successfully fabricated through physical mixing method with CS@rGO as wave absorbing filler, and the epoxy resin (EP) as matrix. The structure and properties of the CS@rGO/EP composite functional coating were characterized. The results display that the CS@rGO/EP composite functional coating possess excellent microwave absorbing properties. When the CS@rGO absorber content is 20% and the coating thickness is 1.1mm, the minimum reflection loss value of the coating can reach -25.03 dB. Meanwhile, the coating can maintain well adhesion to the steel substrate after the coating/Q235 carbon steel plate has been immersed in 5%NaCl or NaOH solutions for 30 days, and electrochemical tests manifest that the corrosion rate of the coating/Q235 steel is as low as (6.53×10-6 mm·a-1), i.e. a high protection efficiency (92.86%). All in all, the good comprehensive performance of CS@rGO/EP composite functional coating shows its great application potential in special service environments.

Key words: composites    absorbing materials    electrostatic self-assembly-high temperature carbonization    self-assembled carbon/epoxy composite coatings    anti-corrosion properties
收稿日期: 2023-01-29     
ZTFLH:  TB332  
通讯作者: 朱曜峰,教授,yfzhu@zstu.edu.cn,研究方向为智能高分子材料
Corresponding author: ZHU Yaofeng, Tel: (0571)86843607, E-mail: yfzhu@zstu.edu.cn
作者简介: 徐文玉,女,1998年生,硕士生
图1  自组装碳/环氧树脂(CS@rGO/EP)复合功能涂料的制备流程
GradeShedding situation
1The shedding area of the coating surface accounts for more than 30% of the entire coating surface
2The shedding area of the coating surface accounts for less than 30% of the entire coating surface
3The shedding area of the coating surface accounts for less than 10% of the entire coating surface
4The shedding area of the coating surface accounts for less than 5% of the entire coating surface
5No shedding phenomenon on the coating surface
表1  涂层表面脱落的等级评价标准
图2  CS和CS@rGO的FESEM图、TEM照片、各试样表面的FESEM图、各试样截面的FESEM图以及试样的XRD谱和FT-IR谱
图3  CS@rGO/EP的吸波性能
图4  试样涂层附着力和耐介质性的测试效果
Sample5%NaCl5%NaOH5%HCl
SF-521Entirely shedding
SF-1021Entirely shedding
SF-1531Entirely shedding
SF-2042Entirely shedding
SF-2542Entirely shedding
表2  不同涂层的耐介质性能
图5  涂层的防腐性能
SampleEcorr / VIcorr / A·cm-2V / mm·a-1EPE / %
Steel plate-0.7957.87×10-99.17×10-5-
Pure epoxy resin coating-0.6983.16×10-93.67×10-559.85
CS@rGO/EP coating-0.3585.62×10-106.53×10-692.86
表3  试样在溶液中浸泡21 d后的Tafel曲线拟合值
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