脂肪酸/SiO<sub>2</sub>复合相变材料的制备和性能

doi:10.11901/1005.3093.2016.730

材料研究学报

2017, Vol. 31

Issue (8): 591-596 DOI: 10.11901/1005.3093.2016.730

研究论文

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脂肪酸/SiO₂复合相变材料的制备和性能

李琳¹, 李东旭^1,²(

), 张树鹏¹, 王立国¹

1 南京工业大学材料科学与工程学院南京 210009
2 江苏先进生物与化学制造协同创新中心南京 211189

Preparation and Properties of Fatty Acid/SiO₂ Composite Phase Change Materials

Lin LI¹, Dongxu LI^1,²(

), Shupeng ZHANG¹, Liguo WANG¹

1 College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009, China
2 Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing 211189, China

引用本文:

李琳, 李东旭, 张树鹏, 王立国. 脂肪酸/SiO₂复合相变材料的制备和性能[J]. 材料研究学报, 2017, 31(8): 591-596.
Lin LI, Dongxu LI, Shupeng ZHANG, Liguo WANG. Preparation and Properties of Fatty Acid/SiO₂ Composite Phase Change Materials[J]. Chinese Journal of Materials Research, 2017, 31(8): 591-596.

全文: PDF(1327 KB) HTML

摘要:

以癸酸(CA)、月桂酸(LA)、肉豆蔻酸(MA)和棕榈酸(PA)为相变材料并根据理论公式估算低共熔脂肪酸的组成配比和理论热性能,制备了4组三元低共熔脂肪酸。针对适用于夏炎热地区建筑领域的相变储能材料,选取月桂酸-肉豆蔻酸-棕榈酸(LA-MA-PA)为相变芯材,用溶胶-凝胶法制备了LA-MA-PA/SiO₂复合相变材料,并测试了这种复合相变材料的结构和性能。结果表明：LA-MA-PA具有良好的热稳定性和结构稳定性,可均匀地嵌入到SiO₂多孔网络结构中,且相变芯材与载体复合后无新物质生成。LA-MA-PA/SiO₂球体颗粒光滑饱满,分散性良好其粒径约为3 μm,经历100次热循环后脂肪酸没有明显的渗漏。这种复合相变材料的相变温度和潜热分别为29.6℃和91.1 J/g,具有良好的热稳定性。

关键词 ：无机非金属材料, 低共熔脂肪酸, 溶胶-凝胶法, 二氧化硅, 复合相变材料

Abstract：

With capric acid (CA), lauric acid (LA), palmitic acid (PA), and myristic acid (MA) as raw materials, four kinds of ternary eutectic mixtures were prepared in consideration of the theoretical thermal property of the formed mixtures with the mass ratio of the three selected raw materials. Then LA-MA-PA/SiO₂ composite phase change materials were prepared by sol-gel method and their structure and performance were characterized. The results show that LA-MA-PA was uniformly filled into the three-dimensional network of SiO₂ and there was no chemical reaction between LA-MA-PA and SiO₂. LA-MA-PA/SiO₂ presented as smooth spherical particles with 3 μm in diameter, which exhibit smooth surface and good dispersibility. While the LA-MA-PA/SiO₂ exhibited high-performance in energy storage with little leakage even after 100 thermal cycling. The phase change temperature and latent heat of the LA-MA-PA/SiO₂ were determined to be 29.6℃ and 91.1 J/g.

Key words： inorganic non-metallic materials eutectic fatty acid sol-gel method silicon dioxide composite phase change material

收稿日期: 2016-12-14

ZTFLH:

TU522

基金资助:“十二五”国家科技支撑计划课题(2014BAL03B04)

作者简介:

作者简介李琳,女,1983年生,硕士生

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链接本文:

https://www.cjmr.org/CN/10.11901/1005.3093.2016.730 或 https://www.cjmr.org/CN/Y2017/V31/I8/591

图1 CA、LA、MA和PA的DSC曲线

表1 低共熔脂肪酸的估算值和实测值对比

图2 LA-MA-PA/SiO2样品宏观图

图3 LA-MA-PA/SiO2样品热循环前后的SEM图

图4 样品的红外光谱分析

图5 LA-MA-PA及复合相变储能材料样品的DSC曲线

表2 本实验和文献中制备的复合相变材料的热物性对比

图6 LA-MA-PA及复合相变材料的TG曲线

[1]	Jeong S G, Jeon J, Lee J H, et al.Optimal preparation of PCM/diatomite composites for enhancing thermal properties[J]. Int. J. Heat Mass Transfer., 2013, 62: 711
[2]	Kim D, Jung J Y, Kim Y N, et al.Structure and thermal properties of octadecane/expanded graphite composites as shape-stabilized phase change materials[J]. Int. J. Heat Mass Transfer, 2016, 95: 735
[3]	Sobolciak P, Mrlík M, AlMaadeed M A, et al. Calorimetric and dynamic mechanical behavior of phase change materials based on paraffin wax supported by expanded graphite[J]. Thermochim. Acta, 2015, 617: 111
[4]	Tian H Q, Wang W L, Ding J, et al.Preparation of binary eutectic chloride/expanded graphite as high-temperature thermal energy storage materials[J]. Sol. Energy Mater. Sol. Cells, 2016, 149: 187
[5]	Schmit H, Rathgeber C, Hennemann P, et al.Three-step method to determine the eutectic composition of binary and ternary mixtures[J]. J. Therm. Anal. Calorim., 2014, 117: 595
[6]	Zhang Y P, Hu H P, Kong X D.Phase Change Energy Saving: Theory and Application [M]. Hefei: University of Science and Technology of China Press, 1996: 8(张寅平, 胡汉平, 孔祥东. 相变贮能-理论和应用 [M]. 合肥: 中国科学技术大学出版社, 1996: 8)
[7]	Wei T, Zheng B C, Liu J, et al.Structures and thermal properties of fatty acid/expanded perlite composites as form-stable phase change materials[J]. Energy Build., 2014, 68: 587
[8]	Guo Q, Wang T.Preparation and characterization of sodium sulfate/silica composite as a shape-stabilized phase change material by sol-gel method[J]. Chin. J. Chem. Eng., 2014, 22: 360
[9]	Zhou X F, Xiao H N, Feng J, et al.Preparation and thermal properties of paraffin/porous silica ceramic composite[J]. Compos. Sci. Technol., 2009, 69: 1246
[10]	Shang J L, Zhang H, Xiong L, et al.Preparation and texture of phase change materials of fatty acid/SiO2 composite[J]. Chin. J. Mater. Res., 2015, 29: 757(尚建丽, 张浩, 熊磊等. 脂肪酸/SiO2复合相变材料的制备及其对织构的影响因素[J]. 材料研究学报, 2015, 29: 757)
[11]	Zhang Y P, Su Y H, Ge X S.Prediction of the melting temperature and the fusion heat of (Quasi-) eutectic PCM[J]. J. China Univ. Sci. Technol., 1995, 25: 474(张寅平, 苏跃红, 葛新石. (准)共晶系相变材料融点及融解热的理论预测[J]. 中国科技技术大学学报, 1995, 25: 474)
[12]	Liu Y, Zhang Y, Li D X.Preparation of hydrophobic silica aerogels by ambitient pressure drying method[J]. J. Funct. Mater., 2015, 46: 5132(刘洋, 张毅, 李东旭. 常压干燥制备疏水性SiO2气凝胶[J]. 功能材料, 2015, 46: 5132)
[13]	Sun Z M, Zhang Y Z, Zheng S L, et al.Preparation and thermal energy storage properties of paraffin/calcined diatomite composites as form-stable phase change materials[J]. Thermochim. Acta, 2013, 558: 16
[14]	Sar? A, Karaipekli A, Alkan C.Preparation, characterization and thermal properties of lauric acid/expanded perlite as novel form-stable composite phase change material[J]. Chem. Eng. J., 2009, 155: 899
[15]	Meng D, Wang L J.Preparation and thermal properties of fatty acid/inorganic nano-particle form-stable phase change material[J]. J. Build. Mater., 2013, 16: 91(孟多, 王立久. 脂肪酸/无机纳米颗粒基定形相变材料的制备与热性能[J]. 建筑材料学报, 2013, 16: 91)
[16]	Karaipekli A, Sar? A.Capric-myristic acid/expanded perlite composite as form-stable phase change material for latent heat thermal energy storage[J]. Renew. Energy, 2008, 33: 2599
[17]	Jeong S G, Jeon J, Cha J, et al.Preparation and evaluation of thermal enhanced silica fume by incorporating organic PCM, for application to concrete[J]. Energy Build., 2013, 62: 190
[18]	Wang S P, Qin P, Fang X M, et al.A novel sebacic acid/expanded graphite composite phase change material for solar thermal medium-temperature applications[J]. Sol. Energy, 2014, 99: 283

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