石墨烯基导电纸的制备及性能研究*

doi:10.11901/1005.3093.2015.479

材料研究学报

2016, Vol. 30

Issue (11): 855-860 DOI: 10.11901/1005.3093.2015.479

论文

本期目录 | 过刊浏览

石墨烯基导电纸的制备及性能研究*

南松楠^1,²,张宏伟¹,王钦雯¹

1. 华南理工大学制浆造纸工程国家重点实验室广州 510640
2. 国家知识产权局专利局专利审查协作河南中心郑州 450002

Preparation and Properties of Graphene-based Conductive Paper

Songnan NAN^1,²,Hongwei ZHANG¹,Qingwen WANG^1,^**(

)

1. State Key Lab of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China
2. Patent Examination Cooperation Center of the Patent Office, SIPO, Zhengzhou 450002, China

引用本文:

南松楠, 张宏伟, 王钦雯. 石墨烯基导电纸的制备及性能研究*[J]. 材料研究学报, 2016, 30(11): 855-860.
Songnan NAN, Hongwei ZHANG, Qingwen WANG. Preparation and Properties of Graphene-based Conductive Paper[J]. Chinese Journal of Materials Research, 2016, 30(11): 855-860.

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摘要:

以茶多酚/铝片作为还原剂, 通过对氧化石墨烯(GO)还原制备石墨烯(RGO), 并将石墨烯与纤维素复合制备石墨烯基导电纸; 在分析石墨烯结构特征的基础上, 研究了石墨烯与纤维素配比、石墨烯基导电纸定量、弯折次数及角度对导电纸性能的影响, 并对石墨烯基导电纸的电容性进行了测试。结果表明, 茶多酚/铝片可有效还原氧化石墨烯, 石墨烯的sp²电子共轭结构得到有效重建; 当纤维素/石墨烯为1:1、定量为72 g/m²时, 石墨烯基导电纸方阻为66.33 Ω/sq, 弹性模量高达1234.00 MPa。石墨烯基导电纸具有优异的柔性及导电稳定性, 在反复弯折及90°及-90°的条件下, 其电阻比值均在1.0左右; 石墨烯基导电纸的面积比电容为5.47 mF/cm², 具有较好的电容性。

关键词 ：无机非金属材料, 茶多酚/铝片, 石墨烯, 纤维素, 石墨烯基导电纸

Abstract：

Tea polyphenols and aluminum flakes was utilized as the reductants to reduce graphene oxide and then synthesize graphene, the as-prepared graphene was then to prepare the graphene-based conductive paper recombination with cellulose. The influence of composite ratio between cellulose and graphene, the conductive paper ration, the folding times and angles to the conductive paper’s electrical property were discussed. The results show that graphene oxide can be reduced effectively by tea polyphenols and aluminum flakes, the sp²structure can be restored effectively. The optimal conditions is composite ratio between cellulose and graphene 1:1, the conductive paper ration 72 g/m², the sheet resistanceand elasticity modulus of the as-prepared conductive paper is 66.33 Ω/sqand 1234.00 MPa. The conductive paper reserved good conductivity after 500 times folding and different folding angles, the ratio between after-folded resistanceand initial resistance is near 1.0. Besides, the specific capacitance of the conductive paper is 5.47 mF/cm², which suggests a good capacitive performance.

Key words： inorganic non-metallic materials cellulose grapheme conductive paper sheet resistance

收稿日期: 2015-08-27

基金资助:* 制浆造纸工程国家重点实验室自主创新研究基金项目2014C24,ZD201401和2016C13

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https://www.cjmr.org/CN/10.11901/1005.3093.2015.479 或 https://www.cjmr.org/CN/Y2016/V30/I11/855

图1 石墨烯基导电纸制备过程

图2 石墨烯和氧化石墨烯的红外光谱图

图3 石墨烯的AFM图

图4 纤维素/石墨烯复合比例对导电纸方阻的影响

图5 纤维素/石墨烯复合比例对导电纸弹性模量的影响

图6 定量对导电纸方阻影响

图7 定量对导电纸弹性模量的影响

图8 弯折次数及角度对石墨烯基导电纸导电稳定性的影响

图9 石墨烯基导电纸通路展现

图10 石墨烯基导电纸循环伏安曲线

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