甲基丙烯酸丁酯-丙烯酸丁酯共聚物/碳酸钙复合功能树脂的制备和性能*

doi:10.11901/1005.3093.2014.729

材料研究学报

2015, Vol. 29

Issue (11): 843-852 DOI: 10.11901/1005.3093.2014.729

本期目录 | 过刊浏览

甲基丙烯酸丁酯-丙烯酸丁酯共聚物/碳酸钙复合功能树脂的制备和性能*

牛小芳¹,徐乃库¹(

),程博闻¹,谢淳²,郭成越²,肖长发¹,郭袈¹

1. 天津工业大学材料科学与工程学院改性与功能纤维天津市重点实验室天津 300387
2. 荣盛石化股份有限公司杭州 311247

Preparation and Properties of Composite Functional Resin Prepared from Poly (Butyl Methacrylate-co-butyl Acrylate)/Calcium Carbonate

Xiaofang NIU¹,Naiku XU^1,^**(

),Bowen CHENG¹,Chun XIE²,Chengyue GUO²,Changfa XIAO¹,Jia GUO¹

1. School of Material Science and Engineering, Tianjin Key Laboratory of Fiber Modification and Functional Fiber, Tianjin Polytechnic University, Tianjin 300387, China
2. Rongsheng Petrochemical Co., Ltd., Hangzhou 311247, China

引用本文:

牛小芳,徐乃库,程博闻,谢淳,郭成越,肖长发,郭袈. 甲基丙烯酸丁酯-丙烯酸丁酯共聚物/碳酸钙复合功能树脂的制备和性能*[J]. 材料研究学报, 2015, 29(11): 843-852.
Xiaofang NIU, Naiku XU, Bowen CHENG, Chun XIE, Chengyue GUO, Changfa XIAO, Jia GUO. Preparation and Properties of Composite Functional Resin Prepared from Poly (Butyl Methacrylate-co-butyl Acrylate)/Calcium Carbonate[J]. Chinese Journal of Materials Research, 2015, 29(11): 843-852.

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摘要:

先采用悬浮聚合合成含活泼叔氢原子的甲基丙烯酸丁酯-丙烯酸丁酯共聚物, 然后以其为基质、以纳米级碳酸钙为填充组分、以甲基丙烯酸羟乙酯为反应性单体、以过氧化苯甲酰为引发剂, 采用反应挤出法制备了包裹有刚性碳酸钙的新型功能树脂, 并用热重分析仪、FESEM、XRD等方法对树脂的结构和性能进行表征, 研究了酸处理前后树脂吸油性能和碱处理前后树脂的吸染料性能。结果表明, 树脂的吸油能力几乎不受酸处理的影响, 循环吸收时间达到50-60 min时, 树脂可将水中的泵油全部吸收, 完成油水分离; 与未碱处理样品相比, 碱处理30 min所得样品吸附阳离子蓝染料的能力显著提高。

关键词 ：有机高分子材料, 甲基丙烯酸丁酯, 丙烯酸丁酯, 甲基丙烯酸b羟乙酯, 纳米级碳酸钙, 反应挤出, 功能树脂

Abstract：

An active tertiary hydrogen atom containing poly (butyl methacrylate-co-butyl acrylate)was firstly synthesized via suspension polymerization, and then a novel functional resin containing rigid calcium carbonate was prepared by reactive extrusion while poly (butyl methacrylate-co-butyl acrylate), nano-calcium carbonate, hydroxyethyl methacrylate and benzoyl peroxide were used as matrix polymer, filler, reactive monomer and initiator, respectively. The corresponding structure and properties of the prepared resin were characterized by using thermogravimetric analyzer, field emission scanning electron microscope and X-ray diffractometer. The oil absorption of the resin before and after acid treatment and the capability of the resin before and after alkali treatment to absorb cationic blue dye were investigated in detail. The results show that acid treatment can not affect the oil absorption of the resin, and the resin can completely remove oil from water through absorption when circulating absorption time reached 50-60 min; additionally, the composite after alkali treatment for 30 min has good capacity to absorb cationic blue dye in comparison with the untreated ones.

Key words： organic polymer materials butyl methacrylate butyl acrylate hydroxyethyl methacrylate nano-calcium carbonate reactive extrusion functional resin

收稿日期: 2014-12-09

基金资助:*国家自然科学基金51103099, 天津市应用基础及前沿技术研究计划12JCQNJC01600, 教育部高等学校博士学科点专项科研基金20111201120002及中国博士后基金2014M550143资助项目。

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https://www.cjmr.org/CN/10.11901/1005.3093.2014.729 或 https://www.cjmr.org/CN/Y2015/V29/I11/843

图1 动态吸油装置示意图

图2 1#-4#样品的TG和DTG曲线

图3 2#-4#样品表面和断面的形貌

图4 BMA-BA共聚物、0#和5#样品TG和DTG曲线

图5 5#样品的表面及断面形貌

图6 未经酸和碱处理树脂吸油量变化曲线

图7 酸处理前后4#样品的动态吸附泵油曲线

图8 4#样品在动态吸油过程中油水混合物颜色的变化

图9 4个碱处理样品的染料吸附效率曲线

图10 未经酸和碱处理树脂的XRD谱

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