掺镁羟基磷灰石涂层在碳/碳复合材料表面的制备*

doi:10.11901/1005.3093.2015.027

材料研究学报

2015, Vol. 29

Issue (11): 853-859 DOI: 10.11901/1005.3093.2015.027

本期目录 | 过刊浏览

掺镁羟基磷灰石涂层在碳/碳复合材料表面的制备*

倪昕晔^1,^2,³,李爱军¹,白瑞成¹,熊信柏³,周栋²(

)

1. 上海大学材料科学与工程学院上海 200444
2. 南京医科大学附属常州第二人民医院常州 213003
3. 深圳大学材料学院深圳 518060

Preparation of Magnesium Doped Hydroxyapatite Coating on Carbon/Carbon Composites

Xinye NI^1,^2,³,Aijun LI¹,Ruicheng BAI¹,Xinbo XIONG³,Dong ZHOU^2,^**(

)

1. School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China
2. Second People’s Hospital of Changzhou, Nanjing Medical University, Changzhou 213003, China
3. College of Materials Science and Engineering, Shenzhen University, Shenzhen 518060, China

引用本文:

倪昕晔,李爱军,白瑞成,熊信柏,周栋. 掺镁羟基磷灰石涂层在碳/碳复合材料表面的制备*[J]. 材料研究学报, 2015, 29(11): 853-859.
Xinye NI, Aijun LI, Ruicheng BAI, Xinbo XIONG, Dong ZHOU. Preparation of Magnesium Doped Hydroxyapatite Coating on Carbon/Carbon Composites[J]. Chinese Journal of Materials Research, 2015, 29(11): 853-859.

全文: PDF(5344 KB) HTML

摘要:

用电磁感应法在碳/碳复合材料表面制备与人骨镁含量相当的羟基磷灰石涂层, 镁占涂层的重量百分含量分别为0、0.28%、0.32%、0.49%。用SEM、EDS、XRD、FT-IR等手段对涂层进行了评价, 结果表明: 镁离子能进入羟基磷灰石晶格内部, 不同镁含量涂层的物相有微小差异。在人骨镁含量的范围内, 涂层的镁含量越高体外大鼠成骨细胞(MC3T3-E1)的粘附、增殖以及分化能力越强。

关键词 ：复合材料, 碳/碳复合材料, 镁, 羟基磷灰石

Abstract：

Mg doped hydroxyapatite coatings with 0, 0.28%, 0.32%, 0.49% Mg respectively, as artificial human bones were prepared on carbon / carbon composites by means of electromagnetic induction method. Then they were characterized by SEM, EDS, X-ray diffraction and Fourier transform-infrared spectroscopy etc. The results show that Mg ions entered the hydroxyapatite lattice and these coatings have only a little difference in constituents. Within the range Mg content of human bone, Mg ions can enhance the adhesion, multiplication, and differentiation of external osteoblasts.

Key words： composites carbon/carbon composites magnesium hydroxyapatite

收稿日期: 2015-01-14

基金资助:* 中国博士后基金2014M560323, 常州市社会发展项目CJ20130019和江苏省自然科学基金BK20151181资助。

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https://www.cjmr.org/CN/10.11901/1005.3093.2015.027 或 https://www.cjmr.org/CN/Y2015/V29/I11/853

图1 不同含镁量涂层SEM照片的对比

图2 不同镁含量涂层的EDS对比

图3 不同含镁量涂层XRD衍射图谱的对比

图4 不同含镁量涂层FTIR的对比

图5 不同含镁量涂层表面的MC3T3-E1细胞粘附的对比

图6 不同含镁量涂层表面的MC3T3-E1细胞增值的对比

图7 不同含镁量涂层表面的MC3T3-E1细胞荧光电镜照片对比(2d)

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