Please wait a minute...
材料研究学报  2013, Vol. 27 Issue (1): 18-24    
  研究论文 本期目录 | 过刊浏览 |
低合金耐候钢在周期性交替条件下的腐蚀行为*
张旭1 杨善武1 张文华2 郭晖1 贺信莱1
1. 北京科技大学材料科学与工程学院 北京 100083
2. 首都航天机械公司 北京 100076
Corrosion Behavior of Low-alloy Weathering Steel in Cyclically Alternate Corrosion Environments
ZHANG Xu1 YANG Shanwu1** ZHANG Wenhua2 GUO Hui1 HE Xinlai1
1 School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083
2. Capital Aerospace Machinery Company, Beijing 100076
引用本文:

张旭 杨善武 张文华 郭晖 贺信莱. 低合金耐候钢在周期性交替条件下的腐蚀行为*[J]. 材料研究学报, 2013, 27(1): 18-24.
ZHANG Xu YANG Shanwu** Wenhua GUO Hui HE Xinlai. Corrosion Behavior of Low-alloy Weathering Steel in Cyclically Alternate Corrosion Environments[J]. Chinese Journal of Materials Research, 2013, 27(1): 18-24.

全文: PDF(9132 KB)  
摘要: 用去离子水和3.5%NaCl模拟和缓与苛刻的腐蚀环境, 进行腐蚀环境交替变换的实验研究低合金耐候钢的大气腐蚀行为。结果表明, 在和缓或苛刻的单一腐蚀条件下低合金耐候钢都不易形成致密的锈层, 但交替腐蚀1个周期后, 形成了致密的保护性锈层。在初期腐蚀环境苛刻、后期腐蚀环境和缓的试验条件下, 与相反的试验条件相比, 耐候钢能更快地形成更致密的锈层。
关键词 材料失效与保护耐候钢交替腐蚀锈层稳定化处理    
Abstract:ABSTRACT Deionized water and 3.5%NaCl were used to simulate the gentle and harsh corrosion environments respectively in this work. The atmospheric corrosion behavior of weathering steel in different corrosion orders was compared by alternative corrosion tests. The results of SEM and EIS of the rusted samples revealed that there was no compact rust layer formed in only gentle or harsh corrosion environment, while a compact rust layer formed after alternative corrosion in gentle and harsh environments. Corrosion mass gain results show that when corrosion started in the harsh environment followed by in the gentle environment, the formation of a compact rust layer needed less time than that in the opposite corrosion order.
    
ZTFLH:  TG172  
1 S.Hara, T.Kamimura, H.Miyuki, M.Yamashita, Taxonomy for protective ability of rust layer using its composition formed on weathering steel bridge, Corrosion Science, 49(3), 1131(2007)
2 ZHANG Quancheng, WU Jiansheng, ZHENG Wenlong, WANG Jianjun, CHEN Jiaguang, Formation mechanism of protective rust on weathering steel, Corrosion Science and Protection Technology, 13(3), 143(2001)
(张全成, 吴建生, 郑文龙, 王建军, 陈家光, 耐候钢表面稳定锈层形成机理的研究, 腐蚀科学与防护技术, 13(3), 143(2001))
3 Y.Y.Chen, H.J.Tzeng, L.I.Wei, L.H.Wang, J.C.Oung, H.C.Shih, Corrosion resistance and mechanical properties of low alloy steels under atmospheric conditions, Corrosion Science, 47(4), 1001(2005)
4 C.L.Li, Y.T.Ma, Y.Li, F.H.Wang, EIS monitoring study of atmospheric corrosion under variable relative humidity, Corrosion Science, 52(11), 3677(2010)
5 A.P.Yadav, A.Nishikata, T.Tsuru, Electrochemical impedance study on galvanized steel corrosion under cyclic wet-dry conditions-influence of time of wetness, Corrosion Science, 46(1), 169(2004)
6 S.Hara, M.Miura, Y.Uchiumi, T.Fujiwara, M.Yamamoto, Suppression of deicing salt corrosion of weathering steel bridges by washing, Corrosion Science, 47(10), 2419(2005)
7 GU Jialin, YAN Rui, Jun Hisamoto, Fumio Yuse, Effect of exposed mode on atmospheric corrosion for carbon steel at Qingdao area, Material Engineering, (12), 37(2009)
(顾家琳, 闫 睿, 久本淳, 濑文雄, 碳钢在青岛不同暴露方式下的大气腐蚀, 材料工程, (12), 37(2009))
8 LIU Lihong, LI Ming, LI Xiaogang, LU Yanping, QI Huibin, A new coating stabilizing surface rust of weathering steel, Acta Metallurgica Sinica, 40(11), 1195(2004)
(刘丽宏, 李 明, 李晓刚, 卢燕平, 齐慧滨, 耐候钢表面锈层稳定化处理用新型涂层研究, 金属学报, 40(11), 1195(2004))
9 XIA Maosen, GUAN Xiaojun, JIANG Shanyu, Summary of study on weathering steel and its surface stabilizing treatment, Shandong Metallurgy, 29(2), 4(2007)
(夏茂森, 关小军, 蒋善玉, 耐大气腐蚀钢及表面稳定化处理的研究综述, 山东冶金, 29(2), 4(2007))
10 X.H.Chen, J.H.Dong, E.H.Han, W.Ke, Effect of Al alloying on corrosion performance of steel, Corrosion Engineering, Science and Technology, 42(3), 224(2007)
11 T.Kamimura, S.Hara, H.Miyuki, M.Yamashita, H.Uchida, Composition and protective ability of rust layer formed on weathering steel exposed to various environments, Corrosion Science, 48(9), 2799(2006)
12 HAN Wei, WANG Jun, WANG Zhenyao, YU Guocai, LI Hongxi, Study on atmospheric corrosion of low alloy steels, Journal of Chinese Society for Corrosion and Protection, 24(3), 147(2004)
(韩 薇, 汪 俊, 王振尧, 于国才, 李洪锡, 碳钢与低合金耐大气腐蚀规律研究, 中国腐蚀与防护学报, 24(3), 147(2004))
13 J.H.Wang, F.I.Wei, Y.S.Chang, H.C.Shih, The corrosion mechanisms of carbon steel and weathering steel in SO2 polluted atmospheres, Materials Chemistry and Physics, 47(1), 1(1997)
14 K.Asami, M.Kikuchi, In-depth distribution of rusts on a plain carbon steel and weathering steels exposed to coastl-industrial atmosphere for 17 years, Corrosion Science, 45(11), 2671(2003)
15 O.Takuya, I.Yasuyuki, M.Tadashi, T.Ichiro, K.Yoshio, T.Yasuo, S.Shigeru, K.Hiroshi, I.Minoru, U.Akira, T.Kouji, M.Kazuhiro, Mossbauer studies on particle volume distribution of α-FeOOH in rust formed on weathering steel, Japanese Journal of Applied Physics, 39(6A), 3382(2000)
16 M.Yamashita, H.Miyuki, Y.Matsuda, H.Naganoa, T.Misawa, The long term growth of the protective rust layer formed on weathering steel by atmospheric corrosion during a quarter of a century, Corrosion Science, 36(2), 283(1994)
17 M.Kimura, H.Kihira, N.Ohta, M.Hashimoto, T.Senuma, Control of Fe(OOH)6 nano-network structures of rust for high atmospheric-corrosion resistance, Corrosion Science, 47(10), 2499(2005)
[1] 高巍, 刘江南, 魏敬鹏, 要玉宏, 杨巍. TC4钛合金表面氧化亚铜掺杂微弧氧化层的结构和性能[J]. 材料研究学报, 2022, 36(6): 409-415.
[2] 杨留洋, 谭卓伟, 李同跃, 张大磊, 邢少华, 鞠虹. 利用WBEEIS测试技术对管道缺陷区动态冲刷腐蚀行为的研究[J]. 材料研究学报, 2022, 36(5): 381-391.
[3] 陈铮, 杨芳, 王成, 杜瑶, 卢壹梁, 朱圣龙, 王福会. 惰性无机填料比例和颗粒尺寸对纳米Al/Al2O3 改性有机硅涂料抗高温氧化行为的影响[J]. 材料研究学报, 2022, 36(4): 271-277.
[4] 李玉峰, 张念飞, 刘丽爽, 赵甜甜, 高文博, 高晓辉. 含磷石墨烯的制备及复合涂层的耐蚀性能[J]. 材料研究学报, 2022, 36(12): 933-944.
[5] 陈艺文, 王成, 娄霞, 李定骏, 周科, 陈明辉, 王群昌, 朱圣龙, 王福会. 无机复合涂层对CB2铁素体耐热钢在650℃水蒸气中的防护[J]. 材料研究学报, 2021, 35(9): 675-681.
[6] 唐荣茂, 刘光明, 刘永强, 师超, 张帮彦, 田继红, 甘鸿禹. 用电化学噪声技术研究Q235钢在含氯盐模拟混凝土孔隙液中的腐蚀行为[J]. 材料研究学报, 2021, 35(7): 526-534.
[7] 张大磊, 魏恩泽, 荆赫, 杨留洋, 豆肖辉, 李同跃. 超级铁素体不锈钢表面超疏水结构的制备及其耐腐蚀性能[J]. 材料研究学报, 2021, 35(1): 7-16.
[8] 王冠一, 车欣, 张浩宇, 陈立佳. Al-5.4Zn-2.6Mg-1.4Cu合金板材的低周疲劳行为[J]. 材料研究学报, 2020, 34(9): 697-704.
[9] 黄安然, 张伟, 王学林, 尚成嘉, 范佳杰. 铁素体不锈钢在高温尿素环境中的腐蚀行为研究[J]. 材料研究学报, 2020, 34(9): 712-720.
[10] 公维炜, 杨丙坤, 陈云, 郝文魁, 王晓芳, 陈浩. 扫描电化学显微镜原位观察碳钢涂层缺陷处的交流腐蚀行为[J]. 材料研究学报, 2020, 34(7): 545-553.
[11] 郭铁明, 徐秀杰, 张延文, 宋志涛, 董志林, 金玉花. Q345q桥梁钢和Q345qNH耐候钢在模拟工业大气+除冰盐混合介质中的腐蚀行为[J]. 材料研究学报, 2020, 34(6): 434-442.
[12] 朱金阳, 谭成通, 暴飞虎, 许立宁. 一种新型含AlCr合金钢在模拟油田采出液环境下的CO2腐蚀行为[J]. 材料研究学报, 2020, 34(6): 443-451.
[13] 梁新磊, 刘茜, 王刚, 王震宇, 韩恩厚, 王帅, 易祖耀, 李娜. 氧化石墨烯改性环氧隔热涂层的耐蚀和隔热性能研究[J]. 材料研究学报, 2020, 34(5): 345-352.
[14] 王志虎,张菊梅,白力静,张国君. 水热处理对AZ31镁合金微弧氧化陶瓷层组织结构及耐蚀性的影响[J]. 材料研究学报, 2020, 34(3): 183-190.
[15] 段体岗, 黄国胜, 马力, 彭文山, 张伟, 许立坤, 林志峰, 何华, 毕铁满. Q235/Ni-Co基自修复涂层的制备和耐蚀性能[J]. 材料研究学报, 2020, 34(10): 777-783.