反向共沉淀法制备纳米Fe<sub>3</sub>O<sub>4</sub>及其粒径控制

材料研究学报

2011, Vol. 25

Issue (5): 489-494

研究论文

本期目录 | 过刊浏览

反向共沉淀法制备纳米Fe₃O₄及其粒径控制

程三旭¹, 李克智¹, 齐乐华², 童永煌¹, 李贺军¹

1.西北工业大学凝固技术国家重点实验室西安 710072
2.西北工业大学机电学院西安 710072

Synthesis and Size Control of the Nano-Fe₃O₄ Particles Synthesized by a Reverse Coprecipitation Method

CHENG Sanxu¹, LI Kezhi¹, QI Lehua², TONG Yonghuang¹, LI Hejun¹

1. The State Key Laboratory of Solidification Processing in Northwestern Polytechnical University, Xi’an 710072
2.College of Mechanical and Electrical Engineering, Northwestern Polytechnical University, Xi’an 710072

引用本文:

程三旭李克智齐乐华童永煌李贺军. 反向共沉淀法制备纳米Fe₃O₄及其粒径控制[J]. 材料研究学报, 2011, 25(5): 489-494.
, , . Synthesis and Size Control of the Nano-Fe₃O₄ Particles Synthesized by a Reverse Coprecipitation Method[J]. Chin J Mater Res, 2011, 25(5): 489-494.

全文: PDF(1098 KB)

摘要: 针对Fe3O4尺寸均匀性及粒径可控性难题, 采用反向共沉淀法制备了磁性纳米Fe3O4。应用透射电子显微镜(TEM)、X射线衍射仪(XRD)和振动式样品磁强计(VSM)对合成的磁性纳米Fe3O4的形貌、结构、粒径及磁性能进行了表征。结果表明: 反向共沉淀法合成的样品近似球形, 物相分析为尖晶石结构的Fe3O4; 与正向共沉淀法相比, 该方法合成的粒子粒径小, 且粒径分布均匀; 反向法合成的样品室温下无剩磁和矫顽力, 具有超顺磁性；纳米粒子随反应温度升高, 粒径尺寸增大; 随反应溶液pH值增大, 粒径尺寸减小。

关键词 ：无机非金属材料, 纳米Fe3O4, 反向共沉淀, 超顺磁性, 粒径控制

Abstract：The morphology, structure and magnetic property of the nano–Fe3O4 particles synthesized by a reverse coprecipitation method were characterized by using transmission electron microscope (TEM), X–ray diffraction (XRD) and vibrating sample magnetometer (VSM). The results show that nearly spherical Fe3O4 nanoparticles with a spinel structure were obtained which exhibited superparamagnetic behavior at room temperature. The nanoparticles was smaller and more uniform compared with those by the normal coprecipitation method.The size of the nanoparticles increased with the synthesized temperature increasing, and decreased with pH value increasing.

Key words： inorganic non-metallic materials nano–Fe3O4 reverse coprecipitation superparamagnetism controlling the size of Fe3O4

收稿日期: 2011-06-20

ZTFLH:

TQ138.1

基金资助:

国家自然科学基金50832004、50972121和高等学校学科创新引智计划B08040资助项目。

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	程三旭
	李克智
	齐乐华
44.8K

链接本文:

https://www.cjmr.org/CN/ 或 https://www.cjmr.org/CN/Y2011/V25/I5/489

1 XU Meng, ZHANG Yunsong, ZHANG Zhiming, SHEN Yaou, ZHAO Maojun, PAN Guangtang, Study on the adsorption of Ca2+, Cd2+ and Pb2+ by magnetic Fe3O4 yeast treated with EDTA dianhydride, Chemical Engineering Journal, 168, 737(2011)

2 ZHAO Yuanbi, QIU Zumin, HUANG Jiaying, Preparation and analysis of Fe3O4 magnetic nanoparticles used as targeted-drug carriers, Chinese Journal of Chemical Engineering, 16(3), 451(2008)

3 QI Lehua, SU Lizheng, GUAN Juntao, LIU Jian, ZHOU Jiming, HUO Jinxing, LI Hejun, The appartus and method of aligned nano-fibre reinforced metal matrix composite, China, CN101787503A, 2010

(齐乐华, 苏力争, 关俊涛, 刘健, 周计明, 霍金星, 李贺军, 纳米纤维定向和定域增强金属基复合材料制备装置及制备方法, 中国, CN101787503A, 2010)

4 Anshu Sharma, Balram Tripathi, Y.K.Vijay, Dramatic improvement in properties of magnetically aligned CNTs/polymer nanocomposites, Journal of Membrane Science, 361, 89(2010)

5 ZHANG Li, NI Qingqing, Toshiaki Natsuki, FU Yaqin, Carbon nanotubes/magnetite hybrids prepared by a facile synthesis process and their magnetic properties, Applied Surface Science, 255, 8676(2009)

6 ZHAN Yingqing, ZHAO Rui, LEI Yajie, MENG Fanbin, ZHONG Jiachun, LIU Xiaobo, A novel carbon nanotubes/Fe3O4 inorganic hybrid material: Synthesis, characterization and microwave electromagnetic properties, Journal of Magnetism Magnetic Materials, 323, 1006(2011)

7 D.Shi, J.P.Cheng, F.Liu, X.B.Zhang, Controlling the size and size distribution of magnetite nanoparticles on carbon nanotubes, Journal of Alloys and Compounds, 502, 365(2010)

8 Young Ha Kim, Soo Jin Park, Roles of nanosized Fe3O4 on supercapacitive properties of carbon nanotubes, Current Applied Physics, 11, 462(2011)

9 WANG Yongliang, LI Baoqiang, ZHOU Yu, JIA Dechang, Influence of amino and carboxylic groups on the synthesis of magnetite nanoparticles, Journal of Rare Metal Materials and Engineering, 38(S2), 1099(2009)

(王永亮, 李保强, 周玉, 贾德昌, 氨基与羧基对Fe3O4纳米颗粒合成的影响, 稀有金属材料与工程, 38(S2), 1099(2009))

10 NING Guiling, Advanced Inorganic Syntheses (Shanghai, East China University of Science and Technology Press, 2007) p.109)

(宁桂玲, 高等无机合成 (上海, 华东理工大学出版社, 2007) p.109)

11 Hiromichi Aono, Hideyuki Hirazawa, Takashi Naohara, Tsunehiro Maehara, Hiroyuki Kikkawa, Yuji Watanabe, Synthesis of fine magnetite powder using reverse coprecipitation method and its heating properties by applying AC magnetic field, Materials Research Bulletin, 40, 1126(2005)

12 FANG Jingxin, The preparation of magnetic fluid by chemical coprecipitation method, Master’s degree thesis, Dalian Jiaotong University, (2006)

(房井新, 共沉淀法制备磁性液体, 硕士学位论文, 大连交通大学(2006))

13 WEI Yongqiang, LAI Qiongyu, YU Ding, JI Xiaoyang, Suspending percentage stability analysis of Fe3O4 magnetic fluid, Chinese Journal of Inorganic Chemistry, 19(4), 411(2003)

(韦勇强, 赖琼钰, 余鼎, 吉晓洋, Fe3O4磁液的悬浮率测定及稳定性研究, 无机化学学报, 19(4), 411(2003))

14 JIANG Cuiyu, SONG Hao,SONG Linhua, SONG Guangwei, GENG Yi, WANG Yuxin, Preparation and characterization of water-based Fe3O4 magnetic fluid by reverse titration coprecipitation method, Journal of China University of Petroleum, 34(6), 136(2010)

(姜翠玉, 宋浩, 宋林花, 宋光伟, 耿毅, 王钰新, 基于反滴加--共沉淀法的水基Fe3O4磁流体制备及性能表征, 中国石油大学学报(自然科学版), 34(6), 136(2010))

15 ZHAO Huijun,WANG Deping, HUANGWenhai, ZHANG Zhongjie, Influnce of chemical modification on the performence of Fe3O4 magnitic microspheres, Chinese Journal of Materials Research, 18(5), 494(2004)

(赵慧君, 王德平, 黄文, 张中杰, 化学修饰对Fe3O4磁性微球性能的影响, 材料研究学报, 18(5), 494(2004))

16 Toshio Takada, Masao Kiyama, Preparation of ferrites by wet method, Proceeding International Conference, 69(1970)

17 XU Huarui, LI Fengsheng, CHEN Shulin, SONG Hongchang, Prepared nano-particles by precipitation method, New Technology Domestic and International, (5), 29(1996)

(徐华蕊, 李凤生, 陈舒林, 宋洪昌, 沉淀法制备纳米级粒子的研究, 国内外新技术, (5), 29(1996))

18 QIN Runhua, JIANG Wei, LIU Hongying, LI Fengsheng, Preparation and superparamagnetism of Fe3O4 nanoparticles, Journal of Functional Materials, 38(6), 902(2007)

(秦润华, 姜炜, 刘宏英, 李凤生, Fe3O4纳米粒子的制备与超顺磁性, 功能材料, 38(6), 902(2007))

[1]	宋莉芳, 闫佳豪, 张佃康, 薛程, 夏慧芸, 牛艳辉. 碱金属掺杂MIL125的CO₂ 吸附性能[J]. 材料研究学报, 2023, 37(9): 649-654.
[2]	邵鸿媚, 崔勇, 徐文迪, 张伟, 申晓毅, 翟玉春. 空心球形AlOOH的无模板水热制备和吸附性能[J]. 材料研究学报, 2023, 37(9): 675-684.
[3]	任富彦, 欧阳二明. g-C₃N₄ 改性Bi₂O₃ 对盐酸四环素的光催化降解[J]. 材料研究学报, 2023, 37(8): 633-640.
[4]	刘明珠, 樊娆, 张萧宇, 马泽元, 梁城洋, 曹颖, 耿仕通, 李玲. SnO₂ 作散射层的光阳极膜厚对量子点染料敏化太阳能电池光电性能的影响[J]. 材料研究学报, 2023, 37(7): 554-560.
[5]	李延伟, 罗康, 姚金环. Ni(OH)₂ 负极材料的十二烷基硫酸钠辅助制备及其储锂性能[J]. 材料研究学报, 2023, 37(6): 453-462.
[6]	余谟鑫, 张书海, 朱博文, 张晨, 王晓婷, 鲍佳敏, 邬翔. N掺杂生物炭的制备及其对Co²⁺ 的吸附性能[J]. 材料研究学报, 2023, 37(4): 291-300.
[7]	朱明星, 戴中华. SrSc_0.5Nb_0.5O₃ 改性BNT基无铅陶瓷的储能特性研究[J]. 材料研究学报, 2023, 37(3): 228-234.
[8]	刘志华, 岳远超, 丘一帆, 卜湘, 阳涛. g-C₃N₄/Ag/BiOBr复合材料的制备及其光催化还原硝酸盐氮[J]. 材料研究学报, 2023, 37(10): 781-790.
[9]	周毅, 涂强, 米忠华. 制备方法对磷酸盐微晶玻璃结构和性能的影响[J]. 材料研究学报, 2023, 37(10): 739-746.
[10]	谢锋, 郭建峰, 王海涛, 常娜. ZnO/CdS/Ag复合光催化剂的制备及其催化和抗菌性能[J]. 材料研究学报, 2023, 37(1): 10-20.
[11]	余超, 邢广超, 吴郑敏, 董博, 丁军, 邸敬慧, 祝洪喜, 邓承继. 亚微米Al₂O₃ 对重结晶碳化硅的作用机制[J]. 材料研究学报, 2022, 36(9): 679-686.
[12]	方向明, 任帅, 容萍, 刘烁, 高世勇. 自供能Ag/SnSe纳米管红外探测器的制备和性能研究[J]. 材料研究学报, 2022, 36(8): 591-596.
[13]	李福禄, 韩春淼, 高嘉望, 蒋健, 许卉, 李冰. 氧化石墨烯的变温发光[J]. 材料研究学报, 2022, 36(8): 597-601.
[14]	朱晓东, 夏杨雯, 喻强, 杨代雄, 何莉莉, 冯威. Cu掺杂金红石型TiO₂ 的制备及其光催化性能[J]. 材料研究学报, 2022, 36(8): 635-640.
[15]	熊庭辉, 蔡文汉, 苗雨, 陈晨龙. ZnO纳米棒阵列和薄膜的同步外延生长及其光电化学性能[J]. 材料研究学报, 2022, 36(7): 481-488.

Viewed

Full text

Abstract

Cited

Shared

Discussed