材料研究学报  2011, Vol. 25 Issue (1): 84-88

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Ni 2+ 掺杂近化学计量比铌酸锂晶体的近红外发光特性

钟月锋, 万云涛, 夏海平

宁波大学光电子功能材料重点实验室 宁波 315211

The Near–infrared Luminescence Property of Ni2+–doped Near–stoichiometric LiNbO3 Single Crystals

ZHONG Yuefeng, WAN Yuntao, XIA Haiping

Key Laboratory of Photo--electronic Materials, Ningbo University, Ningbo 315211

钟月锋 万云涛 夏海平. Ni ²⁺ 掺杂近化学计量比铌酸锂晶体的近红外发光特性[J]. 材料研究学报, 2011, 25(1): 84-88.
, , . The Near–infrared Luminescence Property of Ni2+–doped Near–stoichiometric LiNbO3 Single Crystals[J]. Chin J Mater Res, 2011, 25(1): 84-88.

摘要 参考文献 相关文章 Metrics 全文: PDF(868 KB)   摘要: 研究了Ni2+掺杂近化学计量比铌酸锂(Ni2+:SLN)晶体的近红外发光特性。用980 nm LD光激发, Ni2+:SLN单晶的近红外发光中心位于1087 nm, 荧光峰半高宽约为72 nm。晶体荧光衰减特性的测定结果表明, 其室温荧光寿命为~240 μ s。晶体的近红外的宽带发光, 源于Ni2+离子八面体格位的3T2g(3F)→3A2g(3F)能级跃迁。 关键词 ： 无机非金属材料 ,   镍掺杂近化学计量比铌酸锂晶体 ,   近红外发光 ,  荧光峰半高宽 ,  荧光寿命     Abstract：The near–infrared luminescence properties of Ni2+ doped the near–stoichiometric LiNbO3 (SLN) single crystals have been investigated. Under a laser diode excitation source at 980nm, a near–infrared luminescence in Ni2+:SLN single crystals centers at 1087 nm with its FWHM about 72 nm was found. The fluorescence decay properties of crystal were measured, and the fluorescence lifetime of Ni2+:SLN single crystals was as long as 240 μs even at room temperature. The observed near–infrared fluorescence can be attributed to the 3T2g(3F) →3 A2g(3F) transition of Ni2+ in octahedral sites. Key words： inorganic non–metallic materials    Ni2+–doped near–stoichiometric LiNbO3 single crystal    near–infrared luminescence    FWHM    fluorescence lifetime 收稿日期: 2010-06-24      ZTFLH:  TB321   基金资助: 国家自然科学基金50972061、浙江省杰出青年科学基金R4100364、宁波市自然科学基金(2009A610007, 2010A610185)以及宁波大学王宽诚幸福基金资助项目。 服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 钟月锋 万云涛 夏海平 44.8K 链接本文: https://www.cjmr.org/CN/      或      https://www.cjmr.org/CN/Y2011/V25/I1/84 1 J.M.Breteau, D.Meichenin et F. Auzel, Etude du laser accordable MgF2:Ni2+, Phys.Appl., 22, 1419(1987) 2 Y.Suzuki, W.A.Sibley, O.H.El Bayoumi, T.M.Roberts, B.Bendow, Optical properties of transition–metal ions in zirconium–based metal fluoride glasses and MgF2 crystals, Phys. Rev. B, 35, 4472(1987) 3 T.Suzuki, Y.Ohishi, Broadband 1400 nm emission from Ni2+ in zinc-alumino-silicate glass, Appl. Phys. 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