纳米热障涂层材料Ln2(Zr0.7Ce0.3)2O7(Ln=La, Nd, Sm, Gd)的热物性能

doi:10.11901/1005.3093.2023.111

材料研究学报

2023, Vol. 37

Issue (11): 855-861 DOI: 10.11901/1005.3093.2023.111

研究论文

本期目录 | 过刊浏览

纳米热障涂层材料Ln₂(Zr_0.7Ce_0.3)₂O₇(Ln=La, Nd, Sm, Gd)的热物性能

王月¹, 付博研¹, 陈双龙¹, 邹兵林², 王春杰¹(

)

^1.渤海大学物理科学与技术学院锦州 121013
^2.中国科学院长春应用化学研究所稀土资源利用国家重点实验室长春 130022

Thermophysical Properties of Ln₂(Zr_0.7Ce_0.3)₂O₇ (Ln=La, Nd, Sm, Gd) Nanomaterials for Thermal Barrier Coatings

WANG Yue¹, FU Boyan¹, CHEN Shuanglong¹, ZOU Binglin², WANG Chunjie¹(

)

^1.College of Physical Science and Technology, Bohai University, Jinzhou 121013, China
^2.State Key Laboratory of Rare Earth Resources Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

引用本文:

王月, 付博研, 陈双龙, 邹兵林, 王春杰. 纳米热障涂层材料Ln₂(Zr_0.7Ce_0.3)₂O₇(Ln=La, Nd, Sm, Gd)的热物性能[J]. 材料研究学报, 2023, 37(11): 855-861.
Yue WANG, Boyan FU, Shuanglong CHEN, Binglin ZOU, Chunjie WANG. Thermophysical Properties of Ln₂(Zr_0.7Ce_0.3)₂O₇ (Ln=La, Nd, Sm, Gd) Nanomaterials for Thermal Barrier Coatings[J]. Chinese Journal of Materials Research, 2023, 37(11): 855-861.

全文: PDF(4119 KB) HTML

摘要:

用水热合成法制备纳米热障涂层材料Ln₂(Zr_0.7Ce_0.3)₂O₇ (Ln=La, Nd, Sm, Gd)，表征其晶体结构、形貌、晶格参数、平均粒径尺寸和比表面积并研究了相关的热物性能及其机理。对XRD谱和Raman谱的分析表明，La₂(Zr_0.7Ce_0.3)₂O₇、Nd₂(Zr_0.7Ce_0.3)₂O₇和Sm₂(Zr_0.7Ce_0.3)₂O₇均为烧绿石结构，而Gd₂(Zr_0.7Ce_0.3)₂O₇为萤石结构。结合SEM观察、体积收缩以及相对密度，分析了块材的抗烧结性能。系统对比研究了晶体生长行为、热膨胀系数和热导率等热物性能。结果表明：随着Ln离子半径的减小(La>Nd>Sm>Gd)Ln₂(Zr_0.7Ce_0.3)₂O₇ (Ln=La, Nd, Sm, Gd)纳米材料的晶体生长活化能和热膨胀系数均呈增大的趋势，而热导率则呈降低的趋势。

关键词 ：无机非金属材料, 热障涂层材料, 热物性能, 晶体生长活化能

Abstract：

Thermal barrier coatings are widely used in the protection of engine turbine blade, in this paper, Ln₂(Zr_0.7Ce_0.3)₂O₇ (Ln=La, Nd, Sm, Gd) nanomaterials for the applications of thermal barrier coatings were synthesized by hydrothermal method, the crystallographic structures, morphologies and related thermophysical properties of powders and their bulk materials were comparatively assessed via various techniques. The analysis results of XRD and Raman spectra indicate that La₂(Zr_0.7Ce_0.3)₂O₇, Nd₂(Zr_0.7Ce_0.3)₂O₇ and Sm₂(Zr_0.7Ce_0.3)₂O₇ are pyrochlore structures, while Gd₂(Zr_0.7Ce_0.3)₂O₇ belongs to fluorite type. The lattice parameters, average particle sizes and specific surface areas were also characterized. The volume shrinkage / relative density, the sintering-resistance properties of the four bulk materials were evaluated by SEM observation. Additionally, their thermophysical properties (such as the activation energy of crystal growth, thermal expansion coefficient, and thermal conductivity) were investigated in detail. As the ionic radii of Ln decreasing, the activation energy of crystal growth and thermal expansion coefficient of Ln₂(Zr_0.7Ce_0.3)₂O₇ (Ln=La, Nd, Sm, Gd) increased, however the thermal conductivity is just the opposite.

Key words： inorganic non-metallic materials thermal barrier coating materials thermophysical property activation energy of crystal growth

收稿日期: 2023-02-23

ZTFLH:

TG174.45

基金资助:国家自然科学基金(12004050);辽宁省教育厅项目(LJKMZ20221493);辽宁省教育厅项目(JYTMS20231624)

通讯作者: 王春杰，教授，cjwang@foxmail.com，研究方向为纳米热障涂层材料的制备及性能

Corresponding author: WANG Chunjie, Tel: (0416)3400145, E-mail: cjwang@foxmail.com

作者简介: 王月，女，1982年生，副教授

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	王月
	付博研
	陈双龙
	邹兵林
	王春杰
44.8K

链接本文:

https://www.cjmr.org/CN/10.11901/1005.3093.2023.111 或 https://www.cjmr.org/CN/Y2023/V37/I11/855

图1 Ln2(Zr0.7Ce0.3)2O7(Ln=La, Nd, Sm, Gd)的TG-DSC曲线

图2 Ln2(Zr0.7Ce0.3)2O7(Ln=La, Nd, Sm, Gd)在不同温度下的XRD谱

表1 Ln2(Zr0.7Ce0.3)2O7 (Ln=La, Nd, Sm, Gd)样品的初始晶粒尺寸、晶格参数以及比表面积

图3 Ln2(Zr0.7Ce0.3)2O7(Ln=La, Nd, Sm, Gd)在1450℃热处理后的拉曼光谱

图4 Ln2(Zr0.7Ce0.3)2O7 (Ln=La, Nd, Sm, Gd)在不同温度下的平均粒径尺寸

图5 Ln2(Zr0.7Ce0.3)2O7 (Ln=La, Nd, Sm, Gd)块材在1450℃热处理后的SEM照片

表2 Ln2(Zr0.7Ce0.3)2O7 (Ln=La, Nd, Sm, Gd)块材在1450℃热处理后的体积收缩和相对密度数值

图6 Ln2(Zr0.7Ce0.3)2O7 (Ln=La, Nd, Sm, Gd)样品的热膨胀系数和热导率及其随温度的变化

1	Sankar V, Ramkumar P, Sebastian D, et al. Optimized thermal barrier coating for gas turbine blades [J]. Mater. Today., 2019, 11: 912
2	Jonnoalagadda K P, Eriksson R, Li X H, et al. Thermal barrier coatings: life model development and validation [J]. Surf. Coating. Technol., 2019, 362: 293 doi: 10.1016/j.surfcoat.2019.01.117
3	Li R Y, Xie M, Zhang Y H, et al. Physical properties of Er₂O₃ doped Gd₂(Zr_0.8Ti_0.2)₂O₇ ceramic materials [J]. Chin. J. Mater. Res., 2022, 36: 49
3	李瑞一, 谢敏, 张永和等. Er₂O₃掺杂Gd₂(Zr_0.8Ti_0.2)₂O₇陶瓷的物理性能 [J]. 材料研究学报, 2022, 36: 49 doi: 10.11901/1005.3093.2021.230
4	Li Y, Chen X L, Sun C, et al. Preparation and performance of LnMgAl₁₁O₁₉(Ln=La, Nd) powders for thermal barrier coating [J]. Chin. J. Mater. Res., 2019, 33: 409
4	李莹, 陈小龙, 孙超等. 热障涂层陶瓷层材料LnMgAl₁₁O₁₉ (Ln=La, Nd)粉体的性能 [J]. 材料研究学报, 2019, 33: 409
5	Wang Y, Shao B, Fu B, et al. Comparative researches on the thermophysical properties of nano-sized La₂(Zr_0.7Ce_0.3)₂O₇ synthesized by different routes [J]. Nanomaterials., 2022, 12: 2487 doi: 10.3390/nano12142487
6	Xu Z, He L, Mu R, et al. Influence of the deposition energy on the composition and thermal cycling behavior of La₂(Zr_0.7Ce_0.3)₂O₇ coatings [J]. J. Eur. Ceram. Soc., 2009, 29: 1771 doi: 10.1016/j.jeurceramsoc.2008.10.005
7	Zhang H, Li Z, Xu Q, et al. Preparation and thermophysical properties of Sm₂(Zr_0.7Ce_0.3)₂O₇ ceramic [J]. Adv. Eng. Mater., 2008, 10: 139 doi: 10.1002/adem.v10:1/2
8	Wang C, Wang Y, Fan X. Preparation and thermophysical properties of La₂(Zr_0.7Ce_0.3)₂O₇ ceramic via sol-gel process [J]. Surf. Coating. Technol., 2012, 212: 88 doi: 10.1016/j.surfcoat.2012.09.026
9	Wang C, Wang Y. Thermophysical properties of La₂(Zr_0.7Ce_0.3)₂O₇ prepared by hydrothermal synthesis for nano-sized thermal barrier coatings [J]. Ceram. Int., 2015, 41: 4601 doi: 10.1016/j.ceramint.2014.12.003
10	Zhao F A, Xiao H Y, Bai X M, et al. Effects of doping Yb³⁺, La³⁺, Ti⁴⁺, Hf⁴⁺, Ce⁴⁺ cations on the mechanical properties, thermal conductivity, and electronic structures of Gd₂Zr₂O₇ [J]. J. Alloy. Comp., 2019, 776: 306 doi: 10.1016/j.jallcom.2018.10.240
11	Duarte W, Vardelle M, Rossignol S, et al. Effect of the precursor nature and preparation mode on the coarsening of La₂Zr₂O₇ compounds [J]. Ceram. Int., 2016, 42: 1197 doi: 10.1016/j.ceramint.2015.09.051
12	Zhang P, Navrotsky A, Guo B, et al. Energetics of cubic and monoclinic yttrium oxide polymorphs: phase transitions, surface enthalpies, and stability at the nanoscale [J]. J. Phys. Chem. C., 2008, 112: 932 doi: 10.1021/jp7102337
13	Kaliyaperumal C, Sankarakumar A, Palanisamy J, et al. Fluorite to pyrochlore phase transformation in nanocrystalline Nd₂Zr₂O₇ [J]. Mater. Lett., 2018, 228: 493 doi: 10.1016/j.matlet.2018.06.087
14	Wang C, Wang Y, Cheng Y, et al. Effects of surfactants on the structure and crystal growth behavior of Sm₂Zr₂O₇ nanocrystalline [J]. Powder Technol., 2012, 225: 130 doi: 10.1016/j.powtec.2012.03.050
15	Wang C, Wang Y, Cheng Y, et al. Preparation and thermophysical properties of nano-sized Ln₂Zr₂O₇ (Ln=La, Nd, Sm, and Gd) ceramics with pyrochlore structure [J]. J. Mater. Sci., 2012, 47: 4392 doi: 10.1007/s10853-012-6293-6
16	Qu Z, Wan C, Pan W, et al. Thermal expansion and defect chemistry of MgO doped Sm₂Zr₂O₇ [J]. Chem. Mater., 2007, 19: 4913 doi: 10.1021/cm071615z
17	Tong Y, Lu L, Yang X, et al. Characterization and their photocatalytic properties of Ln₂Zr₂O₇ (Ln=La, Nd, Sm, Dy, Er) nanocrystals by stearic acid method [J]. Solid. State. Sci., 2008, 10: 1379 doi: 10.1016/j.solidstatesciences.2008.01.027
18	Kutty K V G, Rajagopalan S, Mathews C K, et al. Thermal expansion behavior of some rare earth oxide pyrochlores [J]. Mater. Res. Bull., 1994, 29: 759 doi: 10.1016/0025-5408(94)90201-1
19	Wang C, Wang Y, Zhang A, et al. The influence of ionic radii on the grain growth and sintering-resistance of Ln₂Ce₂O₇ (Ln=La, Nd, Sm, Gd) [J]. J. Mater. Sci., 2013, 48: 8133 doi: 10.1007/s10853-013-7625-x
20	Li J G, Wang Y, Ikegami T, et al. Densification below 1000℃ and grain growth behaviors of yttria doped ceria ceramics [J]. Solid State Ionics., 2008, 179: 951 doi: 10.1016/j.ssi.2008.01.053
21	Mazaheri M, Simchi A, Dourandish M, et al. Master sintering curves of a nanoscale 3Y-TZP powder compacts [J]. Ceram. Int., 2009, 35: 547 doi: 10.1016/j.ceramint.2008.01.008
22	Wang C, Wang Y. A study of phase evolution and crystal growth for nano-sized monoclinic Y₄Al₂O₉ as a novel thermal barrier coatings [J]. Ceram. Int., 2019, 45: 19679 doi: 10.1016/j.ceramint.2019.06.217
23	Zhang H, Xu Q, Wang F, et al. Preparation and thermophysical properties of (Sm_0.5La_0.5)₂Zr₂O₇ and (Sm_0.5La_0.5)₂(Zr_0.8Ce_0.2)₂O₇ ceramics for thermal barrier coatings [J]. J. Alloy. Comp., 2009, 475: 624 doi: 10.1016/j.jallcom.2008.07.068
24	Dean J. Lang's Handbook of Chemistry [M]. 13th Ed., New York: McGraw-Hill Book Co, 1985: 37
25	Wan C, Qu Z, Du A, et al. Influence of B site substituent Ti on the structure and thermophysical properties of A2B2O7-type pyrochlore Gd₂Zr₂O₇ [J]. Acta Mater., 2009, 57: 4782 doi: 10.1016/j.actamat.2009.06.040
26	Mazaheri M, Simchi A, Dourandish M, et al. Master sintering curves of a nanoscale 3Y-TZP powder compacts [J]. Ceram Inter., 2009, 35: 547 doi: 10.1016/j.ceramint.2008.01.008
27	Wan C, Qu Z, Du A, et al. Influence of B site substituent Ti on the structure and thermophysical properties of A₂B₂O₇-type pyrochlore Gd₂Zr₂O₇ [J]. Acta Mater., 2009, 57: 4782 doi: 10.1016/j.actamat.2009.06.040
28	Wan C, Pan W, Xu Q, et al. Effect of point defects on the thermal transport properties of (La _x Gd_1- _x )₂Zr₂O₇: experiment and theoretical model [J]. Phys. Rev. B., 2006, 74: 144109-1 doi: 10.1103/PhysRevB.74.144109
29	Berman R, Sciama D W. Wilkinson D H,et al. Thermal Conduction in Solids [M]. Oxford: Clarendon Press, 1976: 66
30	Zhang H, Xu Q, Wang F, et al. Preparation and thermophysical properties of (Sm_0.5La_0.5)₂Zr₂O₇ and (Sm_0.5La_0.5)₂(Zr_0.8Ce_0.2)₂O₇ ceramics for thermal barrier coatings [J]. J. Alloy. Comp., 2009, 475: 624 doi: 10.1016/j.jallcom.2008.07.068
31	Zhou H, Yi D, Yu Z, et al. Preparation and thermophysical properties of CeO₂ doped La₂Zr₂O₇ ceramic for thermal barrier coatings [J]. J. Alloy. Compd., 2007, 438: 217 doi: 10.1016/j.jallcom.2006.08.005
32	Wang C, Hu Z Q, Wu S J, et al. Preparation and properties of La₂O₃ doped BST/Mg₂TiO₄ microwave composite ceramics [J]. Chin. J. Mater. Res., 2011, 25: 109
32	王成, 胡作启, 伍双杰等. La₂O₃掺杂BST/Mg₂TiO₄微波复核陶瓷的制备和性能 [J]. 材料研究学报, 2011, 25: 109
33	Guan Z D, Zhang Z T, Jiao J S. Physical Properties of Inorganic Materials [M]. Beijing: Tsinghua Univiersity Press, 1992: 144
33	关振铎, 张中太, 焦金生. 无机材料物理性能 [M]. 北京: 清华大学出版社, 1992: 144
34	Cahill D G, Watson S K, Pohl R O, et al. Lower limit to the thermal conductivity of disordered crystals [J]. Phys. Rev. B., 1992, 46: 6131-1 pmid: 10002297
35	Clarke D R. Materials selection guidelines for low thermal conductivity thermal barrier coatings [J]. Surf. Coating. Technol., 2003, 163: 67
36	Schelling P K, Phillpot S R, Grimes R W, et al. Optimum pyrochlore compositions for low thermal conductivity by simulation [J]. Philos. Mag. Lett., 2004, 84: 127 doi: 10.1080/09500830310001646699

[1]	宋莉芳, 闫佳豪, 张佃康, 薛程, 夏慧芸, 牛艳辉. 碱金属掺杂MIL125的CO₂ 吸附性能[J]. 材料研究学报, 2023, 37(9): 649-654.
[2]	邵鸿媚, 崔勇, 徐文迪, 张伟, 申晓毅, 翟玉春. 空心球形AlOOH的无模板水热制备和吸附性能[J]. 材料研究学报, 2023, 37(9): 675-684.
[3]	任富彦, 欧阳二明. g-C₃N₄ 改性Bi₂O₃ 对盐酸四环素的光催化降解[J]. 材料研究学报, 2023, 37(8): 633-640.
[4]	刘明珠, 樊娆, 张萧宇, 马泽元, 梁城洋, 曹颖, 耿仕通, 李玲. SnO₂ 作散射层的光阳极膜厚对量子点染料敏化太阳能电池光电性能的影响[J]. 材料研究学报, 2023, 37(7): 554-560.
[5]	李延伟, 罗康, 姚金环. Ni(OH)₂ 负极材料的十二烷基硫酸钠辅助制备及其储锂性能[J]. 材料研究学报, 2023, 37(6): 453-462.
[6]	余谟鑫, 张书海, 朱博文, 张晨, 王晓婷, 鲍佳敏, 邬翔. N掺杂生物炭的制备及其对Co²⁺ 的吸附性能[J]. 材料研究学报, 2023, 37(4): 291-300.
[7]	朱明星, 戴中华. SrSc_0.5Nb_0.5O₃ 改性BNT基无铅陶瓷的储能特性研究[J]. 材料研究学报, 2023, 37(3): 228-234.
[8]	王胜, 周俏亭, 占慧敏, 陈晶晶. 单晶碳化硅接触中亚表层损伤与破坏机理的原子尺度分析[J]. 材料研究学报, 2023, 37(12): 943-951.
[9]	孙玉伟, 陈畴, 祁昕, 任楚奇, 汤茜, 滕洪辉, 任百祥. Ag₃PO₄/MIL-125(Ti) Z型异质结的构建及其光催化还原Cr(VI)的性能[J]. 材料研究学报, 2023, 37(11): 871-880.
[10]	刘志华, 岳远超, 丘一帆, 卜湘, 阳涛. g-C₃N₄/Ag/BiOBr复合材料的制备及其光催化还原硝酸盐氮[J]. 材料研究学报, 2023, 37(10): 781-790.
[11]	周毅, 涂强, 米忠华. 制备方法对磷酸盐微晶玻璃结构和性能的影响[J]. 材料研究学报, 2023, 37(10): 739-746.
[12]	谢锋, 郭建峰, 王海涛, 常娜. ZnO/CdS/Ag复合光催化剂的制备及其催化和抗菌性能[J]. 材料研究学报, 2023, 37(1): 10-20.
[13]	余超, 邢广超, 吴郑敏, 董博, 丁军, 邸敬慧, 祝洪喜, 邓承继. 亚微米Al₂O₃ 对重结晶碳化硅的作用机制[J]. 材料研究学报, 2022, 36(9): 679-686.
[14]	方向明, 任帅, 容萍, 刘烁, 高世勇. 自供能Ag/SnSe纳米管红外探测器的制备和性能研究[J]. 材料研究学报, 2022, 36(8): 591-596.
[15]	李福禄, 韩春淼, 高嘉望, 蒋健, 许卉, 李冰. 氧化石墨烯的变温发光[J]. 材料研究学报, 2022, 36(8): 597-601.

Viewed

Full text

Abstract

Cited

Shared

Discussed