Construction of Super-hydrophobic Structure on Surface of Super Ferritic Stainless Steel B44660 and Its Corrosion Resistance

doi:10.11901/1005.3093.2020.154

Chinese Journal of Materials Research

2021, Vol. 35

Issue (1): 7-16 DOI: 10.11901/1005.3093.2020.154

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Construction of Super-hydrophobic Structure on Surface of Super Ferritic Stainless Steel B44660 and Its Corrosion Resistance

ZHANG Dalei(

), WEI Enze, JING He, YANG Liuyang, DOU Xiaohui, LI Tongyue

School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, China

Cite this article:

ZHANG Dalei, WEI Enze, JING He, YANG Liuyang, DOU Xiaohui, LI Tongyue. Construction of Super-hydrophobic Structure on Surface of Super Ferritic Stainless Steel B44660 and Its Corrosion Resistance. Chinese Journal of Materials Research, 2021, 35(1): 7-16.

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Abstract

A uniform and dense superhydrophobic film on the surface of super ferritic stainless steel B44660 was prepared via spontaneous polymerization of dopamine in the presence of low surface energy substances ODA and PFDT. Then the wettability, surface morphology and chemical structure of the steel with simple- and modified-dopamine coatings were characterized by means of water spray condensation experiment, scanning electron microscope (SEM), X-ray energy spectrum analysis (EDS), impedance spectroscopy and polarization curve tests. The results show that the super ferritic stainless steel with simple dopamine coating is hydrophilic, and however the super ferritic stainless steel surface with super hydrophobic coating has lower corrosion current density and higher coating resistance, the modification treatment can obviously improve the corrosion resistance of the simple dopamine coating on super ferritic stainless steel surface. The super-hydrophobic film formed on the surface of the simple dopamine coating presents large amount of "micro-nano structured air valleys", which prevents the diffusion of strongly corrosive chloride ions between the solution and the solid interface and the electrochemical reaction of the interface. Therefore, the corrosion current density is reduced, correspondingly improving the corrosion resistance of the coating.

Key words: materials failure and protection super hydrophobic film dopamine self-polymerization super ferritic stainless steel corrosion behavior

Received: 08 May 2020

ZTFLH:

TG174.4

Fund: National Natural Science Foundation of China(51774314);Natural Science Foundation in Shandong Province(ZR2018MEM002);the Fundamental Research Funds for the Central Universities(19CX05001A)

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	Dalei ZHANG
	Enze WEI
	He JING
	Liuyang YANG
	Xiaohui DOU
	Tongyue LI

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https://www.cjmr.org/EN/10.11901/1005.3093.2020.154 OR https://www.cjmr.org/EN/Y2021/V35/I1/7

Table 1 Chemical composition of SFSS (mass fraction, %)

Table 2 Main experimental reagents

Table 3 Average roughness of B44660 sample before modification

Fig.1 Schematic diagram of SFSS/PDA/PFDT and SFSS/PDA/ODA preparation process

Fig.2 Macroscopic appearance of SFSS/PDA/ODA and SFSS/PDA/PFDT surfaces

Fig.3 SEM and EDS analysis of SFSS/PDA/ODA (a, b) and SFSS/PDA/PFDT (c, d)

Fig.4 Average WCA of SFSS/PDA/ODA and SFSS/PDA/PFDT in different roughness of group B1-B4

Fig.5 Before modification of SFSS B44660 (a, b, c) and SFSS/PDA/PFDT (d, e, f) surface water mist condensation state

Fig.6 Microbial attachment diagram under fluorescence microscope (a) Modified front super iron B44660; (b) SFSS/PDA/PFDT

Fig.7 Before modification Super Iron B44660, SFSS/PDA/ODA and SFSS/PDA/PFDT were immer-sed in Polarization curve in 3.5% NaCl aqueous solution

Table 4 Before modification Super Iron B44660, SFSS/PDA/ODA and SFSS/PDA/PFDT were immersed in Electrochemical fitting parameters in 3.5% NaCl aqueous solution

Fig.8 Electrochemical impedance spectroscopy of superiron B44660, SFSS/PDA/ODA and SFSS/PDA/PFDT before modification in 3.5% NaCl aqueous solution (a) Nyquist plot; (b), (c) Bode plot

Fig.9 Equivalent circuit diagram: (a) Modified front super iron B44660; (b) SFSS/PDA/PFDT and SFSS/PDA/ODA

Table 5 Modified front super iron B44660, SFSS/PDA/ODA and SFSS/PDA/PFDT immersed in 3.5% NaCl aqueous solution

Fig.10 Microtopography of modified front super iron B44660 (a, b); (c, d) SFSS/PDA/PFDT

Fig.11 Schematic diagram of corrosion mechanism (between different SFSS coatings and corrosive media) (a) SFSS; (b) SFSS/PDA/PFDT

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