Preparation of Graphene/Ni-Cu Alloy Composite on Ni-Cu Alloy Template Made by Selective Laser Melting

doi:10.11901/1005.3093.2020.185

Chinese Journal of Materials Research

2021, Vol. 35

Issue (1): 1-6 DOI: 10.11901/1005.3093.2020.185

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Preparation of Graphene/Ni-Cu Alloy Composite on Ni-Cu Alloy Template Made by Selective Laser Melting

LIU Zhufeng¹, HUANG Yaodong¹, YANG Xiao¹, HE Yuanjing², LI Zhaoqing¹(

), YAN Chunze¹^,³

^1.State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
^2.The Open University of China Ministry of Information Technology (Engineering Center), Beijing 100039, China
^3.Shenzhen Huazhong University of Science and Technology Research Institute, Shenzhen 518057, China

Cite this article:

LIU Zhufeng, HUANG Yaodong, YANG Xiao, HE Yuanjing, LI Zhaoqing, YAN Chunze. Preparation of Graphene/Ni-Cu Alloy Composite on Ni-Cu Alloy Template Made by Selective Laser Melting. Chinese Journal of Materials Research, 2021, 35(1): 1-6.

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Abstract

The Ni-Cu alloy was prepared by selective laser melting (SLM) additive manufacturing technology, and then was used as substrate material for preparation of graphene/Ni-Cr composite by chemical vapor deposition (CVD). The optimized SLM forming parameters are: 200 W laser power, scanning speed 800 mm/s, single layer thickness 0.05 mm, and scanning pitch 0.06. mm. The as prepared Ni-Cu alloy has a density of up to 98.65% and a Rockwell hardness of 127.4 HV1. Then the CVD deposition process of graphene on the Ni-Cu alloy as substrate material was investigated. Results show that graphene can generate on the surface of Ni-Cu alloy at the reaction temperature range of 900~1100℃ and graphene/Ni-Cu alloy composite material was obtained. The thickness of the generated graphene layer gradually decreased with the increase of the reaction temperature. The thermal conductivity of the prepared graphene/Ni-Cu alloy composite material was characterized. The top graphene layer can increase the thermal diffusion coefficient of the Ni-Cu alloy material by 12.5%, which presents a good application prospect for the composite in fields such as radiator, thermal conductive materials and so on.

Key words: composite selective laser melting Ni-Cu alloy graphene Chemical Vapor Deposition thermal conductivity

Received: 25 May 2020

ZTFLH:

TB331

Fund: National Natural Science Foundation of China(51671091);Science,Technology and Innovation Commission of Shenzhen Municipality(JCYJ20180213102634650)

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	Zhufeng LIU
	Yaodong HUANG
	Xiao YANG
	Yuanjing HE
	Zhaoqing LI
	Chunze YAN

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https://www.cjmr.org/EN/10.11901/1005.3093.2020.185 OR https://www.cjmr.org/EN/Y2021/V35/I1/1

Fig.1 Schematic diagram of preparation process of Ni-Cu alloy/graphene composite

Fig.2 SEM micrographs and particle size distribution of metal powders (a) (d) Cu, (b) (e) Ni, (a) (d) Ni-Cu

Fig.3 X-ray diffraction patterns (a) and SEM micrograph (b) of SLM forming materials

Fig.4 Elemental distribution of the SLM forming materials. (a) elemental distribution, (b) CuK, (c) NiK

Table 1 Element contents of the SLM forming materials

Fig.5 Raman spectra and IG/I2D and 2Dw (b) of graphene growth as a function of temperature

Fig.6 Thermal conductivity of Ni-Cu alloy/graphene composite

Fig.7 Analysis of Thermal Conductivity of Ni-Cu alloy/graphene composite

1	Kruth J. P., Froyen L., Vaerenbergh J. V., et al. Selective laser melting of iron-based powder [J]. Mater. Process. Technol., 2004,149: 616
2	Losurdo M., Giangregorio M. M., Capezzuto P., et al. Graphene CVD growth on copper and nickel: role of hydrogen in kinetics and structure [J]. PCCP, 2011, 13: 20836
3	Muñoz R., Gómez-Aleixandre C., Review of CVD synthesis of graphene [J]. Chem. Vap. Deposition, 2013, 19: 297
4	Stefan T., Alfonso R., Paul H., et al. Engineering polycrystalline Ni films to improve thickness uniformity of the chemical-vapor-deposition-grown graphene films [J]. Nanotechnology, 2010, 21: 015601
5	Robinson Z. R., Tyagi P., Murray T. M., et al. Substrate grain size and orientation of Cu and Cu-Ni foils used for the growth of graphene films [J]. Journal of Vacuum Science & Technology A Vacuum Surfaces & Films, 2011, 30: 011401-011401-011407
6	Hsieh Y. P., Wang Y. W., Ting C. C., et al. Effect of catalyst morphology on the quality of CVD grown graphene [J]. Journal of Nanomaterials, 2013 (2013) 6
7	Hodge N.E., Ferencz R.M., Solberg J.M., Implementation of a thermomechanical model for the simulation of selective laser melting [J]. Comput. Mech., 2014, 54: 33
8	Yan C., Hao L., Hussein A., et al. Advanced lightweight 316L stainless steel cellular lattice structures fabricated via selective laser melting [J]. Mater. Design, 2014, 55: 533
9	Wang X., Dong L., Zhang B., et al. Controlled growth of Cu–Ni nanowires and nanospheres for enhanced microwave absorption properties [J]. Nanotechnology, 2016, 27: 125602
10	Bai Z., Chen X., Yang K., et al. Hydrogenation of dicyclopentadiene resin and its monomer over high efficient CuNi alloy catalysts [J]. ChemistrySelect, 2019, 4: 6035
11	Yan C., Liang H., Hussein A., et al. Microstructure and mechanical properties of aluminium alloy cellular lattice structures manufactured by direct metal laser sintering [J]. Materials Science & Engineering A, 2015, 628: 238
12	Yan C., Liang H., Raymont D.. Evaluations of cellular lattice structures manufactured using selective laser melting [J]. International Journal of Machine Tools & Manufacture, 2012, 62: 32
13	Habib M. R., Liang T., Yu X., et al. A review of theoretical study of graphene chemical vapor deposition synthesis on metals: nucleation, growth, and the role of hydrogen and oxygen [J]. Rep. Prog. Phys., 2018, 81: 036501
14	Cunha T. H. R., Ek-Weis J., Lacerda R. G., et al. Graphene chemical vapor deposition at very low pressure: The impact of substrate surface self-diffusion in domain shape [J]. Appl. Phys. Lett., 2014, 105: 1312
15	A. K. Geim, Graphene: status and prospects [J]. Science, 2009, 324: 1530
16	Park B. J., Choi J. S., Eom J. H., et al. Defect-free graphene synthesized directly at 150℃ via chemical vapor deposition with no transfer [J]. ACS Nano, 2018, 12: 2008
17	Nan L., Lei F., Boya D., et al. Universal segregation growth approach to wafer-size graphene from non-noble metals [J]. Nano Lett., 2011, 11: 297
18	Shu H., Tao X. M., Ding F.. What are the active carbon species during graphene chemical vapor deposition growth? [J]. Nanoscale, 2015, 7: 1627
19	Ferrari A. C., Meyer J. C., Scardaci V., et al. Raman spectrum of graphene and graphene layers [J]. Phys. Rev. Lett., 2006, 97: 187401
20	Fang W., Hsu A. L., Song Y., et al. A review of large-area bilayer graphene synthesis by chemical vapor deposition [J]. Nanoscale, 2015, 7: 20335
21	Balandin A. A., Ghosh S., Bao W., et al. Superior thermal conductivity of single-layer graphene [J]. Nano Lett., 2008, 8: 902
22	Cabrera H., Mendoza D., Benítez J. L., et al. Thermal diffusivity of few-layers graphene measured by an all-optical method [J]. Journal of Physics D Applied Physics, 2015, 48: 465501
23	Karcher H.. The triply periodic minimal surfaces of Alan Schoen and their constant mean curvature companions [J]. Manuscripta Mathematica, 1989, 64(3): 291
24	Yang Z., Yan C., Liu J., et al. Designing 3D graphene networks via a 3D-printed Ni template [J]. RSC Adv., 2015, 5(37): 29397
25	Balandin A. A.. Thermal properties of graphene and nanostructured carbon materials [J]. Nat. Mater., 2011, 10(8): 569

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