Assessment on Corrosion Behavior of Q235 Steel in a Simulated Concrete Pore Liquid Containing Chloride by Electrochemical Noise

doi:10.11901/1005.3093.2020.550

Chinese Journal of Materials Research

2021, Vol. 35

Issue (7): 526-534 DOI: 10.11901/1005.3093.2020.550

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Assessment on Corrosion Behavior of Q235 Steel in a Simulated Concrete Pore Liquid Containing Chloride by Electrochemical Noise

TANG Rongmao, LIU Guangming(

), LIU Yongqiang, SHI Chao, ZHANG Bangyan, TIAN Jihong, GAN Hongyu

School of Material Science and Engineering, Nanchang Hangkong University, Nanchang 330063, China

Cite this article:

TANG Rongmao, LIU Guangming, LIU Yongqiang, SHI Chao, ZHANG Bangyan, TIAN Jihong, GAN Hongyu. Assessment on Corrosion Behavior of Q235 Steel in a Simulated Concrete Pore Liquid Containing Chloride by Electrochemical Noise. Chinese Journal of Materials Research, 2021, 35(7): 526-534.

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Abstract

The corrosion process of Q235 steel in 0.5 mol/L NaCl saturated Ca(OH)₂ solution (SCP) was investigated by electrochemical noise technology (EN) and electrochemical impedance spectroscopy (EIS), and the noise data were analyzed in time domain analysis and frequency domain analysis, and the impedance spectrum data were analyzed by way of equivalent circuit. The surface morphology and structure of the tested Q235 steel were characterized by SEM combined with EDS and XRD. The results show that the corrosion process of Q235 steel in SCP solution can be differentiated into three stages: (Ⅰ) the formation and cracking stage of passivation film, (Ⅱ) the metastable pitting corrosion stage and (Ⅲ) the Ca²⁺ deposition and corrosion product formation stage. In the stage (I), the amplitude of current noise fluctuation, the current noise standard deviation S_I and the white noise level W_I are relatively small, but the noise resistance R_n is relatively large; In the stage (Ⅱ), the amplitude of current noise fluctuation is large, S_I and W_I show a step-wise increase, and R_n decreases significantly; In the stage (Ⅲ), the amplitude of current noise fluctuation increases to 200nA, and S_I, W_I, R_n fluctuate relatively smoothly. When Q235 steel is corroded in SCP solution for 10 days, Fe₂O₃ with dispersed CaCO₃ crystallites can be observed on the surface of Q235 steel. At this time Warburg impedance appears, while the corrosion reaction is jointly controlled by the charge transfer and O₂ diffusion process.

Key words: material failure and protection Corrosion behavior research Electrochemical noise Simulated concrete pore liquid Q235 steel

Received: 22 December 2020

ZTFLH:

TG172.6+3

Fund: National Natural Science Foundation of China(51961028)

About author: LIU Guangming, Tel: 13207006808; E-mail: gemliu@126.com

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	Rongmao TANG
	Guangming LIU
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	Chao SHI
	Bangyan ZHANG
	Jihong TIAN
	Hongyu GAN

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https://www.cjmr.org/EN/10.11901/1005.3093.2020.550 OR https://www.cjmr.org/EN/Y2021/V35/I7/526

Fig.1 Time-domain spectrograms of de-DC drift of Q235 steel corroded in SCP solution for different times (a) 1 d; (b) 3 d; (c) 7 d; (b) 10 d

Fig.2 Time-domain statistics of Q235 steel corrosion in SCP solution for different times (a) Current noise standard deviation S_I; (b) Noise resistance R_n

Fig.3 PSD of Q235 steel corroded in SCP solution for different time (a) 1 d; (b) 4 d; (c) 7 d; (b) 10 d

Fig.4 W_I value change of Q235 steel corrosion in SCP solution for different time

Fig.5 Electrochemical impedance spectroscopy of Q235 steel corrosion in SCP solution for different time (a) Nyquist; (b) Bode

Fig.6 Equivalent circuit of Q235 steel corroded in SCP solution for different time (a) R(Q(R(QR))); (b) R(Q(R(Q(RW))))

Table 1 EIS fitting parameters of Q235 steel corrosion in SCP solution for different time

Fig.7 XRD pattern of 10 d corrosion of Q235 steel in SCP solution

Fig.8 SEM morphology of Q235 steel corroded in SCP solution for 10 d (a) surface morphology of Q235 steel; (b) pitting morphology of Q235 steel

Table 2 Surface EDS test results of Q235 steel after corrosion in SCP solution for 10 d

Fig.9 Model diagram of the corrosion process of Q235 steel in SCP solution (a) Passivation film formation and fracture stage; (b) Metastable pitting corrosion stage; (c) Ca²⁺ deposition and corrosion product formation stage

1	Hu R G. Electrochemical study on corrosion process of steel rebar/concrete system [D]. Xiamen: Xiamen University, 2004
	胡融刚. 钢筋/混凝土体系腐蚀过程的电化学研究 [D]. 厦门: 厦门大学, 2004
2	Yi B, Lin D Y, Chen Y X, et al. Effect of Cl^- and SO₄^2- on corrosion behavior of reinforcing steel in simulated concrete pore solutions [J]. Corros. Sci. Prot. Technol., 2016, 28(002): 97
	易博, 林德源, 陈云翔等. Cl^-和SO₄^2-对模拟混凝土孔隙液中钢筋腐蚀行为的影响 [J]. 腐蚀科学与防护技术, 2016, 28(002): 97
3	Li K Q, Yang L J, Xu Y Z, et al. Influence of SO₄^2- on the corrosion behavior of Q235B steel bar in simulated pore solution [J]. Acta Metall. Sin., 2019, 055(004): 457
	李恺强, 杨璐嘉, 徐云泽等. SO₄^2-对模拟孔隙液中Q235B钢筋腐蚀行为的影响 [J]. 金属学报, 2019, 055(004): 457
4	Song J. Corrosion behavior of 304 stainless steel and Q235 carbon steel by electrochemical noise technique [D]. Tianjin: Tianjin University, 2012
	宋杰. 304不锈钢和Q235碳钢腐蚀行为的电化学噪声检测研究 [D]. 天津: 天津大学, 2012
5	Zhao B, Li J H, Hu R G, et al. Study on the corrosion behavior of reinforcing steel in cement mortar by electrochemical noise measurements [J]. Electrochim. Acta., 2007, 52(12): 3976
6	Naghizade R., Shahidi Zandi M., Hosseini S. M. A.. Electrochemical noise analysis of corrosion behaviour of asymmetric electrodes made of mild steel in NaHCO₃ solutions at different NaCl concentrations [J]. Meas., 2020, 43(155): 107501
7	Li Z, Lv J, Niu Z M, et al. Electrochemical noise of corrosion of X80 pipeline steel in Xinzhou soil environment [J]. Corros. Prot.,2017, 38(08): 608
	李治, 吕建, 牛智民等. X80管线钢在新洲土壤中腐蚀的电化学噪声 [J]. 腐蚀与防护, 2017, 38(08): 608
8	Cui J, Yu D Y, Long Z W, et al. Application of electrochemical noise (EN) technology to evaluate the passivation performances of adsorption and film-forming type corrosion inhibitors [J]. J. Electroanal. Chem., 2019, 48(8): 855
9	Li J, Zhao L, Li B W, et al. Electrochemical noise characteristics of pitting corrosion of 304 stainless steel [J]. J. Chin. Soc. Corros. Prot., 2012, 32(03): 235
	李季, 赵林, 李博文等. 304不锈钢点蚀的电化学噪声特征 [J].中国腐蚀与防护学报, 2012, 32(03): 235
10	Dong Z H, Guo X P, Zheng J S, et al. Characteristics of electrochemical noise in local corrosion of 16Mn steel [J]. J. Chin. Soc. Corros. Prot., 2002, 22(05): 35
	董泽华, 郭兴蓬, 郑家燊等. 16Mn钢局部腐蚀中的电化学噪声特征 [J]. 中国腐蚀与防护学报, 2002, 22(05): 35
11	Hu R G, Ye C Q, Dong S G, et al. Electrochemical noise measurement and wavelet analysis of steel bars in simulated concrete hole solution [J]. Electrochem., 2010, 16(02): 137
	胡融刚, 叶陈清, 董士刚等. 模拟混凝土孔溶液中钢筋电化学噪音测量及小波分析 [J]. 电化学, 2010, 16(02): 137
12	Deng J H, Wang G, Hu J Z, et al. Simulation of pitting corrosion behavior of 304 stainless steel in marine atmosphere based on electrochemical noise research [J]. Electrochem., 2020, 26(02): 298
	邓俊豪, 王贵, 胡杰珍等. 基于电化学噪声研究模拟海洋大气环境下304不锈钢的点蚀行为 [J]. 电化学, 2020, 26(02): 298
13	Xia D H, Song S Z, Behnamian Y. Detection of corrosion degradation using electrochemical noise (EN): review of signal processing methods for identifying corrosion forms [J]. Corros. Eng. Sci. Technol., 2016, 51(7): 527
14	An P L, Liang P, Ren J M, et al. Characteristics on electrochemical noise of pitting corrosion for high nitrogen austenitic stainless steels [J]. J. Chin. Soc. Corros. Prot., 2018, 38(01): 26
	安朋亮, 梁平, 任建民等. 高氮奥氏体不锈钢点蚀行为的电化学噪声特征 [J]. 中国腐蚀与防护学报, 2018, 38(01): 26
15	Xia D H, Song S, Behnamian Y, et al. Review—Electrochemical Noise Applied in Corrosion Science: Theoretical and Mathematical Models towards Quantitative Analysis [J]. J. Electrochem. Soc.,2020, 167(8): 081507
16	Zhang J Q, Zhang S, Wang J M, et al. Analysis and application of electrochemical noise——Ⅰ. Principles of electrochemical noise analysis [J]. J. Chin. Soc. Corros. Prot., 2001, 21(05): 55
	张鉴清, 张昭, 王建明等. 电化学噪声的分析与应用——Ⅰ. 电化学噪声的分析原理 [J]. 中国腐蚀与防护学报, 2001, 21(05): 55
17	Hu L H, Du N, Wang M F, et al. Electrochemical noise and electrochemical impedance spectroscopy to monitor the initial pitting behavior of 1Cr18Ni9Ti stainless steel [J]. J. Chin. Soc. Corros. Prot., 2007, 27(04): 233
	胡丽华, 杜楠, 王梅丰等. 电化学噪声和电化学阻抗谱监测1Cr18Ni9Ti不锈钢的初期点蚀行为 [J]. 中国腐蚀与防护学报, 2007, 27(04): 233
18	Han L. A review on electrochemical noise analysis [J]. Corros. Prot., 2015, 36(01): 84
	韩磊. 电化学噪声数据处理方法概述 [J]. 腐蚀与防护, 2015, 36(01): 84
19	Wang X, Wang J, Yue X. Characterization of corrosion process of Q235 carbon steel in simulated concrete pore solution by EIS and EN techniques [J]. Int. J. Electrochem. Sci., 2014, 9(11): 6558
20	Ye C Q, Hu R G, Dong S G, et al. EIS analysis on chloride-induced corrosion behavior of reinforcement steel in simulated carbonated concrete pore solutions [J]. J. Electroanal. Chem., 2013, 688(4): 275
21	Zhu Y C, Liu G M, Wang J J, et al. Electrochemical corrosion behaviors of typical grounding materials in water-saturated acid red soil [J]. Mater. Mech. Eng., 2020, 44(09): 36
	朱亦晨, 刘光明, 王金金等. 典型接地材料在水饱和酸性红壤中的电化学腐蚀行为 [J]. 机械工程材料, 2020, 44(09): 36
22	Lin B. Study on inhibition effect of some organic inhibitors on carbon steel in carbonated simulatied concrete pore solutions [D]. Beijing: Beijing university of chemical technology, 2019
	林冰. 模拟碳化混凝土孔隙液中几种有机缓蚀剂对碳钢的缓蚀作用 [D]. 北京: 北京化工大学, 2019
23	Du Y L, Zhang J X, Jiang J, et al. Corrosion behavior of reinforced steel in simulated pore solution with gradual augment of Cl^- [J]. J. Chin. Soc. Corros. Prot., 2013, 33(04): 331
	杜雅莉, 张俊喜, 蒋俊等. Cl^-浓度渐变的混凝土孔隙液中钢筋的腐蚀过程 [J]. 中国腐蚀与防护学报, 2013, 33(04): 331

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