CoCrFeNiTi x 高熵合金涂层的显微组织和耐磨性能

doi:10.11901/1005.3093.2021.428

材料研究学报

2023, Vol. 37

Issue (3): 219-227 DOI: 10.11901/1005.3093.2021.428

研究论文

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CoCrFeNiTi _x 高熵合金涂层的显微组织和耐磨性能

田志刚, 李新梅(

), 秦忠, 王晓辉, 刘伟斌, 黄永

新疆大学机械工程学院乌鲁木齐 830047

Microstructure and Wear Resistance of CoCrFeNiTi _x High Entropy Alloy Coating

TIAN Zhigang, LI Xinmei(

), QIN Zhong, WANG Xiaohui, LIU Weibin, HUNG Yong

School of Mechanical Engineering, Xinjiang University, Urumqi 830047, China

引用本文:

田志刚, 李新梅, 秦忠, 王晓辉, 刘伟斌, 黄永. CoCrFeNiTi _x 高熵合金涂层的显微组织和耐磨性能[J]. 材料研究学报, 2023, 37(3): 219-227.
Zhigang TIAN, Xinmei LI, Zhong QIN, Xiaohui WANG, Weibin LIU, Yong HUNG. Microstructure and Wear Resistance of CoCrFeNiTi _x High Entropy Alloy Coating[J]. Chinese Journal of Materials Research, 2023, 37(3): 219-227.

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摘要:

用激光熔覆工艺在40Cr钢表面制备CoCrFeNiTi _x (x=0、0.2、0.5、0.8)高熵合金涂层并计算其热力学参数，使用X射线衍射仪(XRD)、扫描电镜(SEM)、能谱仪(EDS)、显微硬度仪、摩擦磨损试验机等手段检测合金的物相组成、组织、元素分布、硬度及耐磨性，研究了Ti元素含量对其显微组织和耐磨性能的影响。结果表明：随着Ti元素含量的提高，合金物相在面心立方(FCC)结构的基础上形成了体心立方(BCC)结构，熔覆层中部的组织由晶界明显、晶粒分布均匀的等轴晶组成，最后形成了柱状树枝晶；随着Ti元素含量的提高，合金横截面的硬度逐渐提高，最高为412.32 HV_0.2，比基体的硬度提高了1.8倍；涂层的磨损量和摩擦系数均随之降低，Ti含量为0.8时涂层其耐磨性能最优，磨损量最小为6.8 mg，摩擦系数为0.35。涂层的磨损机制，以磨粒磨损、粘着磨损和氧化磨损为主。

关键词 ：金属材料, 高熵合金涂层, 激光熔覆, 耐磨性能

Abstract：

CoCrFeNiTi _x (x=0, 0.2, 0.5, 0.8) high-entropy alloy coating was prepared on 40Cr steel surface by laser cladding technology and its thermodynamic parameters were calculated. The phase composition, microstructure, element distribution, hardness and wear resistance of the alloy were detected by X-ray diffractometer (XRD), scanning electron microscope (SEM), energy dispersive spectrometer (EDS), microhardness tester and friction and wear tester. The effects of Ti content on the microstructure and wear resistance of the alloy were investigated. The results show that with the increase of Ti content, the alloy phase forms a body-centered cubic (BCC) structure on the basis of the face-centered cubic (FCC) structure. The microstructure in the middle of the cladding layer is composed of equiaaxial crystals with obvious grain boundaries and uniform grain distribution, and finally the columnar dendrites are formed. With the increase of Ti content, the hardness of cross section of the alloy increases gradually, and the highest is 412.32 HV_0.2, which is 1.8 times higher than that of the matrix. The wear amount and friction coefficient of the coating decrease accordingly. When Ti content is 0.8, the coating has the best wear resistance, the minimum wear amount is 6.8mg, and the friction coefficient is 0.35. The wear mechanism of coating is mainly abrasive wear, adhesive wear and oxidation wear.

Key words： metallic materials high entropy alloy coating laser cladding wear resistance

收稿日期: 2021-07-28

ZTFLH:

TG131

基金资助:国家自然科学基金(52161017);国家自然科学基金(51865055);新疆维吾尔自治区自然科学基金(2022D01C386)

通讯作者: 李新梅，教授，35335499@qq.com，研究方向为材料表面改性

Corresponding author: LI Xinmei, Tel: 17716909771, E-mail: 35335499@qq.com

作者简介: 田志刚，男，1994年生，硕士生

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表1 40Cr钢材料化学成分

表2 实验工艺参数

表3 CoCrFeNiTi x 高熵合金的相关计算参数

表4 CoCrFeNiTi x 高熵合金中不同原子对的ΔHijmix混合焓(kJ/mol)[26]

图1 CoCrFeNiTi x (x=0, 0.2, 0.5, 0.8)高熵合金的XRD图谱

图2 CoCrFeNiTi x (x=0、0.2、0.5、0.8)高熵合金的SEM图

表5 CoCrFeNiTi x 高熵合金涂层的微区EDS分析

图3 CoCrFeNiTi x (x=0，0.5)高熵合金面扫描和元素分布

图4 CoCrFeNiTi x (x=0、0.2、0.5、0.8)的显微硬度

图5 CoCrFeNiTi x (x=0、0.2、0.5、0.8)高熵合金涂层的磨损量和平均摩擦系数

图6 CoCrFeNiTi x (x=0、0.2、0.5、0.8)高熵合金涂层的磨损痕迹3D形貌

图7 40Cr钢和CoCrFeNiTi x (x=0、0.2、0.5、0.8)高熵合金涂层的磨损表面形貌

表6 CoCrFeNiTi x (x=0、0.2、0.5、0.8)高熵合金涂层的磨损表面EDS能谱分析(原子分数, %)

1	Yeh J W, Chen S K, Lin S J, et al. Microstructural control and properties optimization of high-entropy alloys [J]. Advanced Engineering Materials, 2004, 6: 299 doi: 10.1002/(ISSN)1527-2648
2	Yeh J W, Chen S K, Lin S J, et al. Nanostructured high-entropy alloys with multiple principal elements: Novel alloy design concepts and outcomes [J]. Advanced Engineering Materials, 2004, 6(5): 299 doi: 10.1002/(ISSN)1527-2648
3	Tsai M H, Yeh J W. High-entropy alloys: a critical review [J]. Materials Research Letters, 2014, 2(3): 107 doi: 10.1080/21663831.2014.912690
4	Otto F, Yang Y, Bei H, et al. Relative effects of enthalpy and entropy on the phase stability of equiatomic high-entropy alloys [J]. Acta Materialia, 2013, 61(7): 2628 doi: 10.1016/j.actamat.2013.01.042
5	Cantor B, Chang I, Knight P, et al. Microstructural development in equiatomic multicomponent alloys [J]. Materials Science and Engineering: A, 2004, 375
6	Yang Y, Hao Q F. Lattice distortion in high entropy alloys [J]. Acta Metall Sinica, 2021, 57(04): 385
6	杨勇, 赫全锋. 高熵合金中的晶格畸变 [J]. 金属学报, 2021, 57(04): 385
7	Yeh J W, Recent progress in high-entropy alloys [J]. European Journal of Control, 2006, 31(6): 633
8	Zhang W R, Liaw P K, Zhang Y. Science and technology in high-entropy alloys [J]. Science China Materials, 2018, 61(1): 2 doi: 10.1007/s40843-017-9195-8
9	Nong Z S, Lei Y N, Zhu J C. Wear and oxidation resistances of AlCrFeNiTi-based high entropy alloys [J]. Intermetallics, 2018, 101: 144 doi: 10.1016/j.intermet.2018.07.017
10	Nene S S, Frank M, Liu K, et al. Corrosion-resistant high entropy alloy with high strength and ductility [J]. Scripta Materialia, 2019, 166: 168 doi: 10.1016/j.scriptamat.2019.03.028
11	Erdogan A, Dleker K M, Zeytin S. Effect of laser re-melting on electric current assistive sintered CoCrFeNiAl _x Ti _y high entropy alloys: Formation, micro-hardness and wear behaviors [J]. Surface and Coatings Technology, 2020, 399: 126179 doi: 10.1016/j.surfcoat.2020.126179
12	Zhu L D, Xue P S, Lan Q, et al. Recent research and development status of laser cladding: A review [J]. Optics and Laser Technology, 2021, 138
13	Jyoti M, Akash V, Pringal P, et al. Wear, erosion and corrosion behavior of laser cladded high entropy alloy coatings–A review [J]. Materials Today: Proceedings, 2020, 38: 2824 doi: 10.1016/j.matpr.2020.08.763
14	Samuel A U, Fayomi O S I, Omotosho A. O. Prospect of high entropy alloys (HETAs) for advance application [J]. IOP Conference Series: Materials Science and Engineering, 2021, 1107(1): 012162
15	Siddiqui A A, Dubey A K. Recent trends in laser cladding and surface alloying [J]. Optics & Laser Technology, 2021, 134(8): 106619
16	Zhang S, Han B, Li M, et al. Investigation on solid particles erosion resistance of laser cladded CoCrFeNiTi high entropy alloy coating [J]. Intermetallics, 2021, 131(9): 107111 doi: 10.1016/j.intermet.2021.107111
17	Gu Z, Xi S, Sun C. Microstructure and properties of laser cladding and CoCr2.5FeNi2Ti _x high-entropy alloy composite coatings [J]. Journal of Alloys and Compounds, 2019, 819
18	Liu Q, Wang X Y, Huang Y B, et al. Effect of Mo content on microstructure and Corrosion Resistance of CoCrFeNiMo high entropy alloy [J]. Chinese Journal of Materials Research, 2020, 34(11): 868
18	刘谦, 王昕阳, 黄燕滨等. Mo含量对CoCrFeNiMo高熵合金组织及耐蚀性能的影响 [J]. 材料研究学报, 2020, 34(11): 868
19	Zhang S, Han B, Li M, et al. Investigation on solid particles erosion resistance of laser cladded CoCrFeNiTi high entropy alloy coating[J]. Intermetallics, 2021, 131(9): 107111 doi: 10.1016/j.intermet.2021.107111
20	Soni V K, Sanyal S, Sinha S K. Phase evolution and mechanical properties of novel FeCoNiCuMo _x high entropy alloys [J]. Vacuum, 2020, 174: 109173 doi: 10.1016/j.vacuum.2020.109173
21	Huang L, Wang X, Jia F, et al. Effect of Si element on phase transformation and mechanical properties for FeCoCrNiSi _x high entropy alloys [J]. Materials Letters, 2021, 282(12815): 128809 doi: 10.1016/j.matlet.2020.128809
22	Zhang Y, Zhou Y J, Lin J P, et al. Solid‐solution phase formation rules for multi‐component alloys [J]. Advanced Engineering Materials, 2008, 10(6): 534 doi: 10.1002/(ISSN)1527-2648
23	Yang X, Chen, S Y, Cotton, J D, et al. Phase stability of low-density, multiprincipal component alloys containing aluminum, magnesium, and lithium. Jom, 2014, 66 (10), 2009 doi: 10.1007/s11837-014-1059-z
24	Guo S, Hu Q, Ng C, et al. More than entropy in high-entropy alloys: Forming solid solutions or amorphous phase [J]. Intermetallics, 2013, 41: 96 doi: 10.1016/j.intermet.2013.05.002
25	Dong Y, Yi P, et al. Effects of electro-negativity on the stability of topologically close-packed phase in high entropy alloys [J]. Intermetallics, 2014, 52: 105 doi: 10.1016/j.intermet.2014.04.001
26	Akira T, Akihisa I. Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element [J]. Materials Transnctions, 2005, 46(12): 2817
27	Gu Z, Xi S Q, Sun C F. Microstructure and properties of laser cladding and CoCr2.5FeNi2Ti _x high-entropy alloy composite coatings [J]. Journal of Alloys and Compounds, 2020, 819(C)
28	Hui Z, He Y Z, Pan Y, et al. Phase selection, microstructure and properties of laser rapidly solidified FeCoNiCrAl₂Si coating [J]. Intermetallics, 2011, 19(8): 1130 doi: 10.1016/j.intermet.2011.03.017
29	Ma M X, Wang Z X, Zhou J C Z, al et,. Effect of Ti doping on microstructure and wear resistance of CoCrCuFeMn high entropy alloy [J]. Chinese Journal of Mechanical Engineering, 2020, 56(10): 110
29	马明星, 王志新, 周家臣等. Ti掺杂对CoCrCuFeMn高熵合金组织结构和耐磨性的影响 [J]. 机械工程学报, 2020, 56(10): 110 doi: 10.3901/JME.2020.10.110
30	Jin B, Zhang N, Yu H, et al. AlxCoCrFeNiSi high entropy alloy coatings with high microhardness and improved wear resistance [J]. Surface and Coatings Technology, 2020, 402(4): 126328 doi: 10.1016/j.surfcoat.2020.126328

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