电沉积氧化锌纳米柱的带隙和近带边发射蓝移

doi:10.11901/1005.3093.2020.086

材料研究学报

2020, Vol. 34

Issue (11): 875-880 DOI: 10.11901/1005.3093.2020.086

研究论文

本期目录 | 过刊浏览

电沉积氧化锌纳米柱的带隙和近带边发射蓝移

汤洋¹^,²(

)

^1.国家能源集团绿色能源与建筑研究中心北京 102211
^2.北京低碳清洁能源研究院北京 102211

Band Gap Energy and Near Band Edge Emission Blue Shifts of ZnO Nanorods Prepared by Electrodeposition

TANG Yang¹^,²(

)

^1.Center for Green Energy and Architecture, China Energy Investment Corporation, Beijing 102211, China
^2.National Institute of Clean-and-Low-Carbon Energy, Beijing 102211, China

引用本文:

汤洋. 电沉积氧化锌纳米柱的带隙和近带边发射蓝移[J]. 材料研究学报, 2020, 34(11): 875-880.
Yang TANG. Band Gap Energy and Near Band Edge Emission Blue Shifts of ZnO Nanorods Prepared by Electrodeposition[J]. Chinese Journal of Materials Research, 2020, 34(11): 875-880.

全文: PDF(3826 KB) HTML

摘要:

用电化学沉积方法制备了ZnO纳米柱阵列。在Zn(NO₃)₂基础电解液中加入新电解质并引入NH₄NO₃ 和Ga(NO₃)₃，实现了对ZnO纳米柱阵列的带隙、近带边发射、斯托克斯位移、直径、密度等物理性质的设计和裁剪。可在63~77 nm操控纳米柱的直径。增加电解液中的Ga(NO₃)₃浓度，阵列的密度可降低到7.0×10⁹/cm²。新加入电解液中的盐类使ZnO纳米柱的带隙蓝移~50 meV并使光致发光图谱中的近带边发射蓝移53~73 meV以及斯托克斯位移蓝移23 meV，表明可对其非辐射复合进行抑制设计和裁剪。

关键词 ：无机非金属材料, 氧化锌, 电沉积, 硝酸镓, 带隙蓝移, 近带边发射

Abstract：

ZnO nanorod arrays were fabricated by electrodeposition in the traditional electrolytes incorporated with addition of salts such as NH₄NO₃ and Ga(NO₃)₃, so that the phyisical properties, such as the diameter, density, band gap energy, near band edge emission and stokes shift of the prepared ZnO nanorod arrays may be designed and tailored. Namely their diameter can be adjusted between 63 nm to 77 nm. With the use of Ga(NO₃)₃ as the additive, the density of ZnO nanorod arrays can be decreased to 7.0×10⁹/cm²; the band gap energy of the ZnO nanorod arrays showed blue shift from 53 meV to 73 meV with the stokes shift of 23 meV, which indicated that the new process of involving the Ga(NO₃)₃ resulted in the suppression of the non-radiative recombination.

Key words： inorganic nonmetallic materials ZnO electrodeposition gallium nitrate band gap blue shift near band edge emission

收稿日期: 2020-03-22

ZTFLH:

TM23

基金资助:国家自然科学基金(61404007);北京市优秀人才培养拔尖自然科学项目(2015000021223ZK38)

作者简介: 汤洋，男，1983年生，博士

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https://www.cjmr.org/CN/10.11901/1005.3093.2020.086 或 https://www.cjmr.org/CN/Y2020/V34/I11/875

图1 样品1~5的扫描电子显微镜照片

表1 ZnO纳米柱的直径和密度

图2 透射和反射光谱

图3 带隙线性拟合图谱，红色直线为线性拟合线

图4 室温光致发光图谱

图5 样品2~5的光致发光图谱在300~470 nm范围的高斯拟合曲线

表2 近带边发射峰位和斯托克斯位移

1	Jiang H, Jin Y M, Ye X, et al. Review of China's PV industry in the first half of 2020 and outlook in the second half of 2020 [J]. Solar Energy, 2020, 317(9): 5
1	江华, 金艳梅, 叶幸等. 2020年中国光伏产业上半年回顾与下半年展望 [J]. 太阳能, 2020, 317(9): 5
2	Xie L, Wang P, Li Z F, et al. Hydrothermal synthesis and photocatalytic activity of CuO/ZnO composite photocatalyst [J]. Chin. J. Mater. Res., 2019, 33: 728
2	谢亮, 王平, 李之锋等. CuO/ZnO复合光催化剂的制备和性能 [J]. 材料研究学报, 2019, 33: 728
3	Cao P, Bai Y. Preparation and photocatalytic properties of N-doped nano-ZnO/PVC composites [J]. Chin. J. Mater. Res., 2015, 29: 213
3	曹萍, 白越. N掺杂纳米ZnO/聚氯乙烯复合材料的制备和光催化性能 [J]. 材料研究学报, 2015, 29: 213
4	Chen Y, Zhang P, Shang Y H, et al. Controllable synthesis and photocatalytic activity of ZnO nano-cones with different aspect ratio [J]. Chin. J. Mater. Res., 2017, 31: 619
4	陈燕, 张萍, 尚永辉等. 不同纵横比ZnO纳米锥的可控合成及其光催化性能 [J]. 材料研究学报, 2017, 31: 619
5	Li G J, Wang Z, Wang Q, et al. Effect of oxidation time under high magnetic field on the microstructure and optical properties of oxidized co-doped ZnO films [J]. Acta Metall. Sin., 2014, 50: 1538
5	李国建, 王振, 王强等. 强磁场作用时间对氧化法制备的Co掺杂ZnO薄膜微观结构和光学性能的影响 [J]. 材料研究学报, 2014, 50: 1538
6	Hu Y, Xu S W, Li X, et al. Performance of self-powered UV photodetector based on ZnO/ZnS Heterojunction [J]. Chin. J. Mater. Res., 2019, 33: 523
6	胡轶, 徐思伟, 李想等. 自供能ZnO/ZnS异质结紫外探测器的性能研究 [J]. 材料研究学报, 2019, 33: 523
7	Zhao H X, Fang X, Wang Y B, et al. Formation of interface defects of ZnO/ZnS core-shell nanowires and its optical properties investigations [J]. Chin. Opt., 2019, 12: 872
7	赵海霞, 方铉, 王颜彬等. ZnO/ZnS核壳纳米线界面缺陷的形成及发光特性研究 [J]. 中国光学, 2019, 12: 872
8	Su S C, Yang X D, Hu C D. Fabrication of ZnO nanowall-network ultraviolet photodetector on Si substrates [J]. J. Semicond., 2011, 32: 074008
9	Sun X Y, Azad F, Wang S P, et al. Low-cost Flexible ZnO microwires array ultraviolet photodetector embedded in PAVL substrate [J]. Nano Res. Lett., 2018, 13: 277
10	Cao S Y, Zhang J J, Li W Q, et al. Near room temperature and large-area synthesis of ZnO/Cu₂O heterojunction for photocatalytic properties [J]. Chem. Phys. Lett., 2018, 692: 14
11	Amany A, Wang D B, Wang J Z, et al. Enhanced the UV response of AlN coated ZnO nanorods photodetector [J] J. Alloys Compd., 2019, 776: 111
12	Kim D, Yun I, Kim H. Fabrication of rough Al doped ZnO films deposited by low pressure chemical vapor deposition for high efficiency thin film solar cells [J]. Curr. Appl. Phys., 2010, 10(): S459
13	Luka G, Witkowski B S, Wachnicki L. Electrical and mechanical stability of aluminum-doped ZnO films grown on flexible substrates by atomic layer deposition [J]. Mater. Sci. Eng., 2014, 186B: 15
14	Coman T, Ursu E L, Nica V, al el. Improving the uncommon (110) growing orientation of Al-doped ZnO thin films through sequential pulsed laser deposition [J]. Thin Solid Films, 2014, 571: 198
15	Duygulu N E, Kodolbas A O, Ekerim A. Effects of argon pressure and r.f. power on magnetron sputtered aluminum doped ZnO thin films [J]. J. Cryst. Growth, 2014, 394: 116
16	Kumar A, Huang N, Staedler T, et al. Mechanical characterization of aluminum doped zinc oxide (Al: ZnO) nanorods prepared by sol-gel method [J]. Appl. Surf. Sci., 2013, 265: 758
17	Chen Z W, Zhan G H, Wu Y P, et al. Sol-gel-hydrothermal synthesis and conductive properties of Al-doped ZnO nanopowders with controllable morphology [J]. J. Alloys Compd., 2014, 587: 692
18	Tang Y, Chen J. Optical band gap blue shift and stokes shift in Al-doped ZnO nanorods by electrodeposition [J]. Chin. J. Lumin., 2014, 35: 1165
18	汤洋, 陈颉. 电沉积掺铝氧化锌纳米柱的光学带隙蓝移与斯托克斯位移 [J]. 发光学报, 2014, 35: 1165
19	Tang Y, Guo L D, Zhang Z G, et al. Aluminium doping and optical property control of electrodeposited zinc oxide nanorods induced by ammonium nitrate [J]. Opt. Precis. Eng., 2015, 23: 1288
19	汤洋, 郭逦达, 张增光等. 硝酸铵诱导电沉积氧化锌纳米柱的铝掺杂及光学性质操控 [J]. 光学·精密工程, 2015, 23: 1288
20	Chen J, Ye H, Aé L, et al. Tapered aluminum-doped vertical zinc oxide nanorod arrays as light coupling layer for solar energy applications [J]. Sol. Energ. Mat. Sol., 2011, 95C: 1437
21	Guo L D, Tang Y, Chiang F K, et al. Density-controlled growth and passivation of ZnO nanorod arrays by electrodeposition [J]. Thin Solid Films, 2017, 638: 426
22	Tang Y, Chen J, Greiner D, et al. Fast growth of high work function and high-quality ZnO nanorods from an aqueous solution [J]. J. Phys. Chem., 2011, 115C: 5239
23	Cho S, Jung S H, Jang J W, et al. Simultaneous synthesis of Al-doped ZnO nanoneedles and zinc aluminum hydroxides through Use of a seed layer [J]. Cryst. Growth Des., 2008, 8: 4553
24	Mahamuni S, Borgohain K, Bendre B S, et al. Spectroscopic and structural characterization of electrochemically grown ZnO quantum dots [J]. J. Appl. Phys., 1999, 85: 2861
25	Tang Y, Zhao Y, Zhang Z G, et al. Hydrothermal synthesis and properties of ZnO nanorod arrays [J] Chin. J. Mater. Res., 2015, 29: 529
25	汤洋, 赵颖, 张增光等. 氧化锌纳米柱阵列的水热合成及其性能 [J]. 材料研究学报, 2015, 29: 529

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