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材料研究学报  2015, Vol. 29 Issue (8): 589-594    DOI: 10.11901/1005.3093.2014.669
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6061-T6铝合金多道搭接FSP腐蚀性能
王淼1,刘强1,2(),张亚雄1,张南南1,刘满平1,2
1. 江苏大学材料科学与工程学院 镇江 212013
2. 江苏省高端结构材料重点实验室 镇江 212013
Corrosion Property of Al-Alloy 6061-T6 Processed by Multi-pass Friction Stir Processing
Miao WANG1,Qiang LIU1,2,**(),Yaxiong ZHANG1,Nannan ZHANG1,Manping LIU1,2
1. School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China
2. Jiangsu Province Key Laboratory of High-end Structural Materials, Zhenjiang 212013, China
引用本文:

王淼,刘强,张亚雄,张南南,刘满平. 6061-T6铝合金多道搭接FSP腐蚀性能[J]. 材料研究学报, 2015, 29(8): 589-594.
Miao WANG, Qiang LIU, Yaxiong ZHANG, Nannan ZHANG, Manping LIU. Corrosion Property of Al-Alloy 6061-T6 Processed by Multi-pass Friction Stir Processing[J]. Chinese Journal of Materials Research, 2015, 29(8): 589-594.

全文: PDF(5891 KB)   HTML
摘要: 

将6061-T6铝合金进行空冷、水冷的多道搭接搅拌摩擦加工(multi-pass FSP), 用金相显微镜、扫描电镜、透射电镜、浸泡腐蚀试验和电化学腐蚀等手段表征了核区材料的腐蚀性能。结果表明: 母材经这两种冷却方式的FSP改性后, 核区的晶粒明显细化, 腐蚀性能有显著的提高; 与母材相比, 核区的腐蚀电压较高, 腐蚀电流密度较小, 阻抗较大; 空冷FSP的核区材料比水冷的腐蚀性能更好。

关键词 材料失效与保护6061-T6铝合金搅拌摩擦加工核区腐蚀性能    
Abstract

The 6061-T6 aluminium alloy was modified by multi-pass friction stir process with air or water cooling. Corrosion behavior of the processed zone was investigated by immersion test and electrochemical corrosion test, as well as optical microscopy, SEM and TEM. The results show that the grain size of stirred zone was successfully refined and its corrosion resistance became better obviously after the base metal was modified by FSP with different cooling methods. Compared with the base metal, the nugget zone exhibited higher free-corrosion potential, smaller corrosion current density and greater corrosion impedance. Compared to FSP with water-cooling, the nugget zone prepared by FSP with air-cooling showed better corrosion resistance.

Key wordsmaterials failure and protection    6061-T6 aluminium alloy    friction stir process    nugget zone    corrosion property
收稿日期: 2014-11-12     
基金资助:* 江苏省材料摩擦学重点实验室基金Kjsmcx2011004,江苏大学高级人才基金11JDG140和江苏省自然科学基金BK2012715资助项目。
图1  母材、空冷FSP核区和水冷FSP核区的金相组织
图2  T6态母材、空冷FSP核区和水冷FSP核区各试样的晶间腐蚀形貌
图3  各试样的剥落腐蚀形貌T6态母材、空冷FSP核区、水冷FSP核区以及空冷FSP的EDS能谱
图4  各试样的极化曲线
Sample Ecorr(V) Icorr(A/cm2)
6061-T6 base matal -1.221 1.499×10-5
FSP by air-cooled -1.013 1.655×10-6
FSP by water-cooled -0.767 2.036×10-6
表1  电化学腐蚀参数
图5  各试样的Nyquist图
图6  T6态母材、空冷FSP核区以及水冷FSP核区试样的不同放大倍率透射电镜照片
1 ZHANG Xiaolong,Studies on Corrosion Resisting ProPerty of Frietion Stir Welded Joint of Ultrafine一grain Aluminium Alloy, Master Dissertation, Xi'an University of Architecture and Technology(2009)
1 (张小龙, 超细晶铝合金搅拌摩擦焊接接头腐蚀性能研究, 硕士学位论文, 西安建筑科技大学, (2009))
2 Mishra R S,Mahoney M W, Friction stir processing: a new grain refinement technique to achieve high strain rate superplasticity in commercial alloys, Materials Science Forum, 357, 507(2001)
3 Mishra R S,Ma Z Y, Friction stir welding and processing, Materials Science and Engineering, 50(1), 1(2005)
4 Magdy M,El-Rayesa, Ehab A, El-Danaf, The influence of multi-pass friction stir processing on the microstructural and mechanical properties of Aluminum Alloy 6082, Journal of Materials Processing Technology, 212, 1157(2012)
5 S. Pradeep,Vivek Pancholi, Effect of microstructural inhomogeneity on superplastic behaviour of multipass friction stir processed aluminium alloy, Materials Science & Engineering A 561, 78(2013)
6 Al-Fadhalah K J,Almazrouee A I, Aloraier A S. Microstructure and mechanical properties of multi-pass friction stir processed aluminum alloy 6063, Materials & Design, 53, 550(2014)
7 Bajt Z,Leban M, Kovac J, An attempt to detect varioustypes of stress -corrosion cracking on austenitic stainlesssteels by simultaneous measurements of acoustic emissionand electrochemical noise, Stroniski Vestnik -Journal of Mechanical Energineering, 54(1), 25(2008)
8 Ramadan S,Gaillet L, Tessier C, Assessment of the stress corrosion cracking in a chloride medium of cables used in prestressed concrete structures by the acoustic emission technique, Measurement Science and Technology, 19(11), 115702(2008)
9 Surekha K., Murty B. S, Prasad R. K.,Microstructural characterization and corrosion behavior of multipass friction stir processed AA2219 aluminium alloy, Surface Coatings Technology, 202(17), 4057(2008)
10 Wang D,Ni D R, Ma Z Y, Effect of pre-strain and two-step aging on microstructure and stress corrosion cracking of 7050 alloy, Materials Science and Engineering A, 494, 360(2008)
11 Kelly D. J, Robillson M. J,Influnence of heat treatment and grain shape on exfoliation corrosion of Al—Li alloy 8090, Corrosion, 49(10), 787(1993)
12 Posada M.,Murr, L. E., Niou, C. S., Roberson, D., Little, D., Arrowood, R., & George, D. Exfoliation and related microstructures in 2024 aluminum body skins on aging aircraft, Materials Characterization, 38(4), 259(1997)
13 ZHANG Hua,SUN Datong, ZHANG He, ZHAO Yanhua, MA Fangfang, XU Keren, Progress in corrosion behavior of friction stir welded aluminum alloy, Journal of Chinese Society for Corrosion and Protection, 33(3), 175(2013)
13 (张 华, 孙大同, 张 贺, 赵衍华, 马芳芳, 许可人, 铝合金搅拌摩擦焊接接头腐蚀行为研究进展, 中国腐蚀与防护学报, 33(3), 175(2013))
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