纳米介孔MCM--41--M/偶联剂体系对天然橡胶性能的影响

材料研究学报

2012, Vol. 26

Issue (3): 289-294

研究论文

本期目录 | 过刊浏览

纳米介孔MCM--41--M/偶联剂体系对天然橡胶性能的影响

王娜, 米龙, 姜森, 张静, 方庆红

沈阳化工大学材料科学与工程学院沈阳 110142

Effect of System of Nano–sized Mesoporous MCM–41–M/Coupling Agents on the Properties of Natural Rubber Composites

WANG Na, MI Long, JIANG Sen, ZHANG Jing, FANG Qinghong

School of Material Science and Engineering, Shenyang University of Chemical Technology, Shenyang 110142

引用本文:

王娜米龙姜森张静方庆红. 纳米介孔MCM--41--M/偶联剂体系对天然橡胶性能的影响[J]. 材料研究学报, 2012, 26(3): 289-294.
, . Effect of System of Nano–sized Mesoporous MCM–41–M/Coupling Agents on the Properties of Natural Rubber Composites[J]. Chin J Mater Res, 2012, 26(3): 289-294.

全文: PDF(1053 KB)

摘要: 制备了天然橡胶(NR)/MCM--41--M、NR/偶联剂化学改性纳米介孔MCM--41--M、NR/MCM--41--M/偶联剂复合材料, 研究了不同含量的MCM--41--M、不同种类偶联剂对MCM--41--M的改性以及偶联剂的添加方式对NR复合材料性能的影响。结果表明：MCM--41--M在NR中有明显的补强作用, 当代替3份炭黑时NR基复合材料的拉伸强度达到最大值, 比纯NR提高了12.7%。与MCM--41--M和KH--570直接添加到NR中相比, MCM--41--M经偶联剂KH--570改性使拉伸强度提高了50%。将MCM--41--M用偶联剂KH--570改性后添加到NR中, 使NR的玻璃化转变温度升高、玻璃化转变区的损耗角减小、储能模量提高到最大。

关键词 ：有机高分子材料, 天然橡胶, 纳米介孔MCM--41--M, 偶联改性

Abstract：The nano–sized mesoporous MCM–41–M, chemical modification of MCM–41–M by coupling agents, and four different coupling agents were used to prepare natural rubber(NR) composites. The effects of content of nano–sized mesoporous MCM–41–M, the kinds of coupling agents, and adding method of coupling agent on the mechanical properties of the composites were investigated. The results show that the MCM–41–M has better reinforcing effects in the NR matrix. The tensile strength of the NR composites raised by 12.7% compared with pure NR when the content(mass fraction) of MCM–41–M is 3%. Compared with NR/MCM–41–M/KH–570, the tensile strength of NR/KH–570 modified MCM–41–M raised by 50%. NR/KH–570 modified MCM–41–M shows a higher glass transition temperature, lower tanδ peak value and higher storage modulus under all temperature regions.

Key words： organic polymer materials natural rubber nano–sized mesoporous MCM–41–M coupling agent modification

收稿日期: 2012-01-12

ZTFLH:

TB324

基金资助:

国家自然科学基金51103086和51173110, 辽宁省高等学校杰出青年学者成长计划LJQ2011040资助项目。

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https://www.cjmr.org/CN/ 或 https://www.cjmr.org/CN/Y2012/V26/I3/289

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