Please wait a minute...
材料研究学报  2010, Vol. 24 Issue (1): 87-90    
  研究论文 本期目录 | 过刊浏览 |
TeO2-Nb2O5-P2O5系统玻璃成玻性能及其性能研究
林健1; 刘长城1; 杨希文2; 魏恒勇1; 庆睿1
1.同济大学材料科学与工程学院 上海 200092
2.台湾联合大学材料科学工程学系 台湾 36003
The Glass Forming Ability of TeO2–Nb2O5–P2O5 Glasses and Its Properties
LIN Jian1; LIU Changcheng1; YANG Hsiwen2 ; WEI Hengyong1; QING Rui1
1.College of Materials Science and Engineering; Tongji University; Shanghai 200092
2.Department of Materials Science and Engineering; National United University; Miao–Li 36003; Taiwan
引用本文:

林健 刘长城 杨希文 魏恒勇 庆睿. TeO2-Nb2O5-P2O5系统玻璃成玻性能及其性能研究[J]. 材料研究学报, 2010, 24(1): 87-90.
, , , , . The Glass Forming Ability of TeO2–Nb2O5–P2O5 Glasses and Its Properties[J]. Chin J Mater Res, 2010, 24(1): 87-90.

全文: PDF(779 KB)  
摘要: 

研究了TeO2--Nb2O5--P2O5三元系统的玻璃形成能力和相关理化性能。结果表明, 在TeO2(80%--90%), Nb2O5(0--20%), P2O5(0--20%)(摩尔分数)成分范围内可以形成性能良好的透明玻璃, 碲氧、磷氧和少量的铌氧结构单元共同构建了稳定的链状玻璃网络骨架。TeO2--Nb2O5--P2O5玻璃的转变温度为394--425℃、折射率为1.65--1.88。

关键词 无机非金属材料  碲酸盐 磷酸盐 氧化铌 玻璃 模压    
Abstract

The glass forming ability and the properties of TeO2--Nb2O5--P2O5 ternary system were investigated in this paper. It was found that the transparent glasses with good quality can be prepared in the range of TeO2 80\%--90%, Nb2O5 0--20%, P2O5 0--20% (molar fraction). The chain--like glass network was stabilized by constructing with tellurium--oxide, phosphorus--oxide and few niobium--oxide coordination polyhedra. The transition temperature of the TeO2--Nb2O5--P2O5 glasses is from 394 to 425℃, and its refractive index is from 1.65 to 1.88.

Key wordsinorganic non–metallic materials     tellurite    phosphate    niobium    glass    molding
收稿日期: 2009-05-06     
基金资助:

上海市科委纳米专项基金0852nm06500资助项目。

1 K.Masahide, Transferability of glass lens molding, SPIE, 6149, 61490M(2006)
2 J.Deegan, Glass molding makes aspheric lenses a practical choice, Photonics Spec., 41(8), 72(2007)
3 A.Y.Yi, C.Huang, F.Klocke, C.Brecher, G.Pongs, M.Winterschladen, A.Demmer, S.Lange, T.Bergs,
M.Merz, F.Niehaus, Development of a compression molding process for three–dimensional tailored free–form
glass optics, Appl. Opt., 45(25), 6511(2006)
4 W.Liang, J.Cheng, New phosphate glass for precision molding, Am. Ceram. Soc. Bull., 80(3), 62(2001)
5 Y.Kasuga, G.Suu, Optical glass, perform for precision press molding and its manufacturing method,
and optical element and its manufacturing method, JP2005206427A(2005)
6 K.Hayashi, Optical glass, perform for precise press–molding and production method therefor, and optical
element and production method therefore, JP2005263570A(2005)
7 LUO Liqing, LIN Jian, HUANG Wenhai, WANG Haibo, Optical performance of Nb2O5–TeO2 base glass, Photoelectronic Technology, 24(4), 223(2004)
(罗丽庆, 林健, 黄文旵, 王海波, 碲铌基玻璃光学透过性能, 光电子技术,  24(4), 223(2004))

8 J.Lin, W.H.Huang, Z.R.Sun, C.S.Ray, D.E.Day, Structure and non–linear optical performance of TeO2–Nb2O5–ZnO glasses, J. Non–Cryst. Solids, 336, 189(2004)
9 B.V.R.Chowdari, P.P.Kumari, Studies on Ag2O.MxOy.TeO2 (MxOy=WO3, MoO3 , P2O5 and B2O3) ionic conducting glasses, Solid State Ionics, 113-115, 665(1998)
10 K.Muruganandam, M.Seshasayee, Structural study of LiPO3–TeO2 glasses, J. Non–Cryst. Solids, 222,
131(1997)
11 U.Hoppe, E.Yousef, C.Russel, J.Neuefeind, A.C.Hannon, Structure of zinc and niobium tellurite glasses by neutron and X–ray diffraction, J. Phys: Condensed Matter, 16, 1645(2004)
12 M.M.Ahmad, E.S.Yousef, E.S.Moustafa, Dielectric properties of the ternary TeO2/Nb2O5/ZnO glasses, Physica
B, 371, 74(2006)
13 O.Cozar, D.A.Magdas, L.Nasdala, I.Ardelean, G.Damain, Raman spectroscopic study of some lead phosphate glasses with tungsten ions, J. Non–Cryst. Solids, 352, 3121(2006)
14 M.A.Karakassides, A.Saranti, I.Koutselas, Preparation and structural study of binary phosphate glasses with high calcium and/or magnesium content, J. Non–Cryst. Solids, 347, 69(2004)

[1] 宋莉芳, 闫佳豪, 张佃康, 薛程, 夏慧芸, 牛艳辉. 碱金属掺杂MIL125CO2 吸附性能[J]. 材料研究学报, 2023, 37(9): 649-654.
[2] 邵鸿媚, 崔勇, 徐文迪, 张伟, 申晓毅, 翟玉春. 空心球形AlOOH的无模板水热制备和吸附性能[J]. 材料研究学报, 2023, 37(9): 675-684.
[3] 任富彦, 欧阳二明. g-C3N4 改性Bi2O3 对盐酸四环素的光催化降解[J]. 材料研究学报, 2023, 37(8): 633-640.
[4] 刘明珠, 樊娆, 张萧宇, 马泽元, 梁城洋, 曹颖, 耿仕通, 李玲. SnO2 作散射层的光阳极膜厚对量子点染料敏化太阳能电池光电性能的影响[J]. 材料研究学报, 2023, 37(7): 554-560.
[5] 李延伟, 罗康, 姚金环. Ni(OH)2 负极材料的十二烷基硫酸钠辅助制备及其储锂性能[J]. 材料研究学报, 2023, 37(6): 453-462.
[6] 余谟鑫, 张书海, 朱博文, 张晨, 王晓婷, 鲍佳敏, 邬翔. N掺杂生物炭的制备及其对Co2+ 的吸附性能[J]. 材料研究学报, 2023, 37(4): 291-300.
[7] 朱雪冬, 张爽, 邹存磊, 刘林根, 朱智浩, 万鹏, 董闯. Zr55Cu30Al10Ni5 块体金属玻璃的成分优化设计及其晶化行为[J]. 材料研究学报, 2023, 37(4): 281-290.
[8] 朱明星, 戴中华. SrSc0.5Nb0.5O3 改性BNT基无铅陶瓷的储能特性研究[J]. 材料研究学报, 2023, 37(3): 228-234.
[9] 刘志华, 岳远超, 丘一帆, 卜湘, 阳涛. g-C3N4/Ag/BiOBr复合材料的制备及其光催化还原硝酸盐氮[J]. 材料研究学报, 2023, 37(10): 781-790.
[10] 周毅, 涂强, 米忠华. 制备方法对磷酸盐微晶玻璃结构和性能的影响[J]. 材料研究学报, 2023, 37(10): 739-746.
[11] 谢锋, 郭建峰, 王海涛, 常娜. ZnO/CdS/Ag复合光催化剂的制备及其催化和抗菌性能[J]. 材料研究学报, 2023, 37(1): 10-20.
[12] 余超, 邢广超, 吴郑敏, 董博, 丁军, 邸敬慧, 祝洪喜, 邓承继. 亚微米Al2O3 对重结晶碳化硅的作用机制[J]. 材料研究学报, 2022, 36(9): 679-686.
[13] 方向明, 任帅, 容萍, 刘烁, 高世勇. 自供能Ag/SnSe纳米管红外探测器的制备和性能研究[J]. 材料研究学报, 2022, 36(8): 591-596.
[14] 李福禄, 韩春淼, 高嘉望, 蒋健, 许卉, 李冰. 氧化石墨烯的变温发光[J]. 材料研究学报, 2022, 36(8): 597-601.
[15] 朱晓东, 夏杨雯, 喻强, 杨代雄, 何莉莉, 冯威. Cu掺杂金红石型TiO2 的制备及其光催化性能[J]. 材料研究学报, 2022, 36(8): 635-640.