Zr55Cu30Al10Ni5 块体金属玻璃的成分优化设计及其晶化行为

doi:10.11901/1005.3093.2022.090

材料研究学报

2023, Vol. 37

Issue (4): 281-290 DOI: 10.11901/1005.3093.2022.090

研究论文

本期目录 | 过刊浏览

Zr₅₅Cu₃₀Al₁₀Ni₅ 块体金属玻璃的成分优化设计及其晶化行为

朱雪冬¹, 张爽¹(

), 邹存磊¹, 刘林根², 朱智浩², 万鹏³, 董闯¹^,²

^1.大连交通大学材料科学与工程学院大连 116028
^2.大连理工大学三束材料改性教育部重点实验室大连 116024
^3.佛山市顺德区美的电热电器制造有限公司佛山 528300

Optimization Design of a Bulk Metallic Glass Zr₅₅Cu₃₀Al₁₀Ni₅ and its Crystallization Behavior

ZHU Xuedong¹, ZHANG Shuang¹(

), ZOU Cunlei¹, LIU Lingen², ZHU Zhihao², WAN Peng³, DONG Chuang¹^,²

^1.School of Materials Science and Engineering, Dalian Jiaotong University, Dalian 116028, China
^2.Key Laboratory of Materials Modification by Laser, Ion and Electron Beams of Ministry of Education, Dalian University of Technology, Dalian 116024, China
^3.Foshan Shunde Midea Electric Heating Appliance Manufacturing Co. Ltd., Foshan 528300, China

引用本文:

朱雪冬, 张爽, 邹存磊, 刘林根, 朱智浩, 万鹏, 董闯. Zr₅₅Cu₃₀Al₁₀Ni₅ 块体金属玻璃的成分优化设计及其晶化行为[J]. 材料研究学报, 2023, 37(4): 281-290.
Xuedong ZHU, Shuang ZHANG, Cunlei ZOU, Lingen LIU, Zhihao ZHU, Peng WAN, Chuang DONG. Optimization Design of a Bulk Metallic Glass Zr₅₅Cu₃₀Al₁₀Ni₅ and its Crystallization Behavior[J]. Chinese Journal of Materials Research, 2023, 37(4): 281-290.

全文: PDF(8920 KB) HTML

摘要:

参照Zr₅₅Cu₃₀Al₁₀Ni₅合金的成分并应用团簇加连接原子模型，设计具有高玻璃形成能力的Zr-Cu-Al-Ni体系成分。在Zr-Cu-Al-Ni四元体系中，先定出两个与金属玻璃形成相关的晶化相CuZr₂和CuZr，其中的局域结构可分别用团簇表述为[Cu-Zr₈Cu₄]和[Cu-Zr₈Cu₆]，然后应用双团簇模型将这两个团簇按照1∶1的配比构建双团簇式，连接原子个数为2或4或6，由此确定总原子个数为30或32或34，进而选择双团簇式原子总数为32设计出最接近Zr₅₅Cu₃₀Al₁₀Ni₅合金的四元块体金属玻璃成分Zr₁₇Cu₁₀Al₃Ni₂≈Zr_53.1Cu_31.3Al_9.4Ni_6.3。这种合金玻璃的T_rg值可达0.6，晶化激活能为334.138 kJ/mol，均略高于参照合金Zr₅₅Cu₃₀Al₁₀Ni₅，表明其具有更高的玻璃形成能力。

关键词 ：金属材料, 成分优化, 团簇加连接原子模型, 玻璃形成能力, 块体金属玻璃, 晶化行为

Abstract：

According to the principle of cluster-plus-glue-atom model, the composition of a novel Zr-Cu-Al-Ni alloy with glass formation ability was designed by taking the alloy Zr₅₅Cu₃₀Al₁₀Ni₅ as reference. In the quaternary Zr-Cu-Al-Ni system, two crystallization phases CuZr₂ and CuZr related with amorphous formation were firstly identified, the local structures of these two clusters can be expressed as [Cu-Zr₈Cu₄] and [Cu-Zr₈Cu₆] respectively; then, by combining these two clusters in equal proportion while coupling with the number of glue atoms 2, 4, or 6, the dual-cluster formulas for total atom number of 30, 32, or 34 respectively may be constructed by means of the dual-cluster model. Furthermore, according to dual- cluster formula of the total number of atoms of 32, a quaternary alloy with composition Zr₁₇Cu₁₀Al₃Ni₂≈Zr_53.1Cu_31.3Al_9.4Ni_6.3was tentatively designed, which is closest to the reference Zr₅₅Cu₃₀Al₁₀Ni₅. The glass formation ability of this alloy was tested experimentally. The results show that its T_rg reaches 0.6 and its crystallization activation energy is 334.138 kJ/mol, which are all slightly higher than that of the reference alloy, indicating that the designed alloy has a higher glass formation ability.

Key words： metallic materials composition optimization cluster-plus-glue-atom model glass formation ability bulk metallic glasses crystallization behavior

收稿日期: 2022-02-07

ZTFLH:

TG139.8

基金资助:国家自然科学基金(52101127);国家自然科学基金(51901033);辽宁省自然科学基金(2020-BS-208);辽宁省自然科学基金(2020-BS-207);大连理工大学三束材料改性教育部重点实验室开放课题(KF2006);顺德区科技计划(201911220001)

作者简介: 朱雪冬，女，1997年生，硕士生

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https://www.cjmr.org/CN/10.11901/1005.3093.2022.090 或 https://www.cjmr.org/CN/Y2023/V37/I4/281

表1 CuZr2相的晶体结构信息[22]

图1 CuZr2相中的两种团簇

Phase name CuZr	Structure type ClCs	Pearson symbol cP2	Space group Pm $3 ¯$ m			No.221
a=0.32620(5) nm
Cu	1a	m $3 ¯$ m	x=0	y=0	z=0	Occ.=1
Zr	1b	m $3 ¯$ m	x=1/2	y=1/2	z=1/2	Occ.=1

表2 CuZr相的晶体结构信息[22]

图2 CuZr相中的两种团簇

图3 尺寸为5 mm的Zr17Cu10Al3Ni2块体金属玻璃的X射线衍射谱

图4 Zr17Cu10Al3Ni2 BMG能谱面扫分析

表3 Zr17Cu10Al3Ni2 面扫描能谱成分

图5 Zr17Cu10Al3Ni2 BMG 微观组织

表4 析出晶化相对应的成分表

图6 Zr17Cu10Al3Ni2块体金属玻璃的DSC、DTA曲线(DSC的升温速率为10 K/min，DTA为恒速度升温)

图7 Zr17Cu10Al3Ni2大块金属玻璃在不同升温速率下的DSC曲线

图8 Zr17Cu10Al3Ni2大块金属玻璃在不同升温速率下的DTA曲线

图9 Zr17Cu10Al3Ni2大块金属玻璃试样的Kissinger曲线

表5 不同升温速率下Zr17Cu10Al3Ni2BMG样品的热学参数

图10 在800 K热处理保温1 h后几乎完全晶化的Zr17Cu10Al3Ni2的X射线衍射谱

图11 退火态Zr17Cu10Al3Ni2的能谱面扫分析

图12 退火态Zr17Cu10Al3Ni2 BMG 的微观组织图

表6 试样的定点EDS分析结果

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