在钛基合金表面水热电化学沉积羟基磷灰石涂层*

doi:10.11901/1005.3093.2016.143

材料研究学报

2016, Vol. 30

Issue (10): 787-794 DOI: 10.11901/1005.3093.2016.143

研究论文

本期目录 | 过刊浏览

在钛基合金表面水热电化学沉积羟基磷灰石涂层*

杜晶¹,何代华¹(

),刘平¹,刘新宽¹,马凤仓¹,李伟¹,陈小红¹,张珂¹,赵君²

1. 上海理工大学材料科学与工程学院上海 200093
2. 中国科学院特种无机涂层重点实验室上海 200050

Hydroxyapatite Coatings on Titanium Substrate Prepared by Hydrothermal-Electrochemical Deposition

Jing DU¹,Daihua HE^1,^**(

),Ping LIU¹,Xinkuan LIU¹,Fengcang MA¹,Wei LI¹,Xiaohong CHEN¹,Ke ZHANG¹,Jun ZHAO²

1. School of Materials Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
2. Key Laboratory of Inorganic Coating Materials, Chinese Academy of Sciences, Shanghai 200050, China

引用本文:

杜晶,何代华,刘平,刘新宽,马凤仓,李伟,陈小红,张珂,赵君. 在钛基合金表面水热电化学沉积羟基磷灰石涂层*[J]. 材料研究学报, 2016, 30(10): 787-794.
Jing DU, Daihua HE, Ping LIU, Xinkuan LIU, Fengcang MA, Wei LI, Xiaohong CHEN, Ke ZHANG, Jun ZHAO. Hydroxyapatite Coatings on Titanium Substrate Prepared by Hydrothermal-Electrochemical Deposition[J]. Chinese Journal of Materials Research, 2016, 30(10): 787-794.

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摘要:

在Ca²⁺、H₂PO₄^-和NO₃^-离子浓度分别为0.025 mol/L、0.015 mol/L和0.1 mol/L电解液中加入2.5×10^-4 mol/L的柠檬酸钠, 采用水热电化学方法在Ti6Al4V基体表面沉积羟基磷灰石涂层, 研究了柠檬酸根对羟基磷灰石(HA)涂层的物相组成、形貌及结合强度的影响以及沉积时间对HA涂层物相、形貌、结晶度、涂层厚度及结合强度的影响。结果表明: 在含柠檬酸根电解液中水热电化学沉积的仍为HA涂层, 与不含柠檬酸根的电解液相比, HA晶体的尺寸显著减小, 涂层表面更加均匀致密, 涂层与基体之间的结合强度由15.39 MPa提高到24.31 MPa; HA(002)晶面的衍射峰随着水热电化学沉积时间的增加先增强后减弱, 在沉积2 h时达到最大, HA晶粒尺寸较小, 涂层更为均匀致密。随着沉积时间的增加, HA涂层厚度呈非线性增加, HA涂层的结晶度和结合强度均, 先增大后减小, 沉积时间为2 h时结晶度和结合强度分别达到最大值为75.7%和24.31 MPa。

关键词 ：金属材料, Ti6Al4V, 柠檬酸根, 水热电化学, 羟基磷灰石涂层

Abstract：

Hydroxyapatite coatings were deposited on the Ti6Al4V surface by hydrothermal-electrochemical deposition method in an electrolyte composited of 0.025 mol/L Ca²⁺, 0.015 mol/L H₂PO₄^- and 0.1 mol/L NO₃^- with addition of 2.5×10^-4 mol/L Na-Citrate . The effect of the citrate and deposition time on the composition, microstructure, crystallinity and thickness of coatings as well as the bonding strength between the coating and the substrate were investigated. The results show that: in comparison with the electrolyte without citrate, HA coating formed in the electrolyte with addition of citrate exhibits uniform and compact appearance with smaller gain size, which covers entirely the substrate, correspondingly the bonding strength between the coating and the substrate increases from 15.39 MPa to 24.31 MPa. The thickness of HA coating increases non-linearly with deposition time. With the increase of deposition time, the orientation index of the (002) plane of HA increases first and then decreases, which reaching a maximum for 2 h deposition while the coating has much smaller grain size; the crystallinity and bonding strength of HA coatings all increase first, and then decrease, which come to peak values, ca 75.7% and 24.3 MPa respectively by 2 h deposition.

Key words： metallic materials Ti6Al4V citrate hydrothermal electrochemical hydroxyapatite coating

收稿日期: 2016-03-17

基金资助:* 中国科学院特种无机涂层重点实验室开放课题项目KLICM-2014-11和上海市自然科学基金15ZR1428300资助

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	杜晶
	何代华
	刘平
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	李伟
	陈小红
	张珂
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https://www.cjmr.org/CN/10.11901/1005.3093.2016.143 或 https://www.cjmr.org/CN/Y2016/V30/I10/787

图1 在不同电解液中沉积HA涂层的XRD图谱

图2 在不同电解液中沉积HA涂层的FTIR图谱

图3 在不同电解液中沉积HA涂层的SEM照片

图4 使用不同的电解液试样的断面SEM照片

图5 沉积时间不同的HA涂层的XRD图谱

图6 沉积时间不同的HA涂层结晶度的变化趋势

图7 沉积时间不同的HA涂层的SEM形貌

图8 不同沉积时间HA涂层的厚度

图9 不同沉积时间HA涂层的结合强度

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