聚苯胺-钴铬锌铁氧体复合材料的微波吸收性能和磁性能

doi:10.11901/1005.3093.2014.707

材料研究学报

2015, Vol. 29

Issue (8): 622-626 DOI: 10.11901/1005.3093.2014.707

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聚苯胺-钴铬锌铁氧体复合材料的微波吸收性能和磁性能

马瑞廷(

),蒋丹,王晓,赵海涛

沈阳理工大学材料科学与工程学院沈阳 110159

Microwave Absorbing and Magnetic Properties of the Polyaniline-Co_0.7Cr_0.1Zn_0.2Fe₂O₄ Composites

Ruiting MA^JIANGDan^**(

),Xiao WANG,Haitao ZHAO

School of Materials Science and Engineering, Shenyang Ligong University, Shenyang 110159, China

引用本文:

马瑞廷,蒋丹,王晓,赵海涛. 聚苯胺-钴铬锌铁氧体复合材料的微波吸收性能和磁性能[J]. 材料研究学报, 2015, 29(8): 622-626.
Ruiting MA, Xiao WANG, Haitao ZHAO, . Microwave Absorbing and Magnetic Properties of the Polyaniline-Co_0.7Cr_0.1Zn_0.2Fe₂O₄ Composites[J]. Chinese Journal of Materials Research, 2015, 29(8): 622-626.

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摘要:

用聚丙烯酰胺凝胶法和原位聚合法分别制备了钴铬锌铁氧体(Co_0.7Cr_0.1Zn_0.2Fe₂O₄)和聚苯胺-钴铬锌铁氧体复合材料(PANI-Co_0.7Cr_0.1Zn_0.2Fe₂O₄), 用XRD和FT-IR对材料的结构进行了表征。结果表明, 制备的Co_0.7Cr_0.1Zn_0.2Fe₂O₄铁氧体为尖晶石结构, 少量Cr³⁺离子替代了铁氧体八面体位置上的Co²⁺离子, 导致铁氧体的晶格常数从0.8409 nm减小到0.8377 nm。用振动样品磁强计(VSM)测量了材料的磁性能, 结果表明, PANI-Co_0.7Cr_0.1Zn_0.2Fe₂O₄复合材料的饱和磁化强度(M_s)、剩余磁化强度(M_r)和矫顽力(H_c)分别为8.80 emu/g、14 emu/g和37.22 kA/m, 小于铁氧体的相应数值; 用波导法研究了PANI-Co_0.7Cr_0.1Zn_0.2Fe₂O₄复合材料的微波吸收性能, 在5-20 GHz频率范围内14.1 GHz和17.9 GHz处出现两个极大反射损耗, 分别为-13.17 dB和-15.36 dB, 大于铁氧体的反射损耗。

关键词 ：复合材料, 铁氧体, 聚苯胺, 微波吸收性能, 磁性能

Abstract：

The spinel cobalt chromium zinc ferrites (Co_0.7Cr_0.1Zn_0.2Fe₂O₄) and composites of polyaniline(PANI)-Co_0.7Cr_0.1Zn_0.2Fe₂O₄were prepared by polyacrylamide gel and in situ polymerization method, respectively, and then the synthesized materials were characterized by X-ray diffraction (XRD) and Fourier transform infrared spectrometer (FT-IR), their magnetic properties were measured using vibrating sample magnetometer (VSM) and their microwave absorbing capability was investigated by wave-guide method. The results show that the spinel Co_0.7Cr_0.1Zn_0.2Fe₂O₄ ferrites and the composites PANI-Co_0.7Cr_0.1Zn_0.2Fe₂O₄ are acquired. Because a small amount Co²⁺ ion of the octahedron ferrite is replaced by Cr³⁺ ions, the lattice constant of the Co_0.8Zn_0.2Fe₂O₄ ferrite reduces from 0.8409 nm to 0.8377 nm. The saturation magnetization (M_s), remanent magnetization (M_r) and coercive force (H_c) of the PPy-Co_0.7Cr_0.1Zn_0.2Fe₂O₄ composites are 8.80 emug^-1, 3.14 emug^-1 and 37.22 kAm^-1, respectively, which are smaller than that of the Co_0.7Cr_0.1Zn_0.2Fe₂O₄ ferrite. In a measuring frequency range of 5.0-20.0 GHz, two peak values of reflection loss for the composites PPy-Co_0.7Cr_0.1Zn_0.2Fe₂O₄ appear at 14.1 GHz and 17.9 GHz with -13.17 dB and -15.36 dB, respectively, which is obviously higher than those of the Co_0.7Cr_0.1Zn_0.2Fe₂O₄ ferrite.

Key words： composites ferrite polyaniline microwave absorbing properties magnetic properties

收稿日期: 2014-11-27

基金资助:* 辽宁省自然科学基金2014020094和沈阳市重点实验室建设基金F14-187-1-00资助项目。

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https://www.cjmr.org/CN/10.11901/1005.3093.2014.707 或 https://www.cjmr.org/CN/Y2015/V29/I8/622

图1 PANI-Co0.7Cr0.1Zn0.2Fe2O4, Co0.7Cr0.1Zn0.2Fe2O4和Co0.8Zn0.2Fe2O4的XRD谱

图2 PANI-Co0.7Cr0.1Zn0.2Fe2O4和Co0.7Cr0.1Zn0.2Fe2O4的红外光谱图

图3 PANI-Co0.7Cr0.1Zn0.2Fe2O4和Co0.7Cr0.1Zn0.2Fe2O4的磁滞回线图

表1 各物质的饱和磁化强度Ms、剩余磁化强度Mr和矫顽力Hc

图4 PANI-Co0.7Cr0.1Zn0.2Fe2O4和Co0.7Cr0.1Zn0.2Fe2O4的介电损耗(tanε=ε''/ε')随频率的变化曲线

图5 PANI-Co0.7Cr0.1Zn0.2Fe2O4和Co0.7Cr0.1Zn0.2Fe2O4的反射损耗随频率的变化曲线

1	J. W. Ye, Y. Liu, X. F. Chen, M. Yao,Microwave electromagnetic and absorption properties of Sm N/α-Fe/Sm2Fe17N3 composites in 0.5-18 GHz range, J. Alloys. Compd., 526, 59(2012)
2	S. Ke, W. L. Zhong, Y. Zhong,L Li, X. Jiang, H. Ji, Temperature dependence of core losses at high frequency for MnZn ferrites, Physical B, 405, 1018(2010)
3	WU Yanfei,HUANG Ying, ZHANG Yinling, NIU Lei, Several w-type barium ferrites with different Me2: preparation and the electromagnetic properties, Chinese Journal of Materials Research, 25(6), 607(2011)
3	(吴燕飞, 黄英, 张银铃, 牛磊, Me2-W型钡铁氧体的制备及其电磁性能研究, 材料研究学报, 25(6), 607(2011))
4	K. Gupta, P. C. Jana, A. K. Meikap,Electrical transport and optical properties of the composite of polyaniline with gold, Solid State Sci, 14, 324(2012)
5	Y. Yao, H. Y. Jiang, J. Wu, D. Gu, L. Shen,Synthesis of Fe3O4/polyaniline nanocomposite in reversed micelle systems and its performance characteristics, Proc. Eng., 27, 664(2012)
6	LI Yuanxun,LIU Yingli, ZHANG Huaiwu, LING Weiwei, XIE Yunsong, XIAO Johnqiang, Preparation, Characterization and properities of polyaniline-barium ferrite nanocomposite, Chemical Journal of Chinese Universities, 29(3), 640(2008)
6	(李元勋, 刘颖力, 张怀武, 凌味未, 谢云松, XIAO JohnQiang, 聚苯胺钡铁氧体纳米复合材料的制备、表征及性能, 高等学校化学学报, 29(3), 640(2008).)
7	S. P. Gairola, V. Verma, L. Kumar, M. A. Dar, S. Annapoomi, R. K. Kotnala,Enhanced microwave absorption properties in polyaniline and nano-ferrite composite in X-band, Synth. Met., 160, 2315(2010)
8	C. C. Yang, Y. J. Gung, W. C. Hung, T. H. Ting, K. H. Wu,Infrared and microwave absorbing properties of BaTiO3/polyaniline and BaFe12O19/polyaniline composites, Compos. Sci. Technol., 70, 466(2010)
9	R. T. Ma, Y. W. Tian, H. T. Zhao, G. Zhang, H. Zhao,Synthesis, Characterization and electromagnetic studies on nanocrystalline Co0.5Zn0.5Fe2O4 by polyacrylamide gel, J. Mater. Sci. & Technol., 24(4), 628(2008)
10	C. C. Hwang, J. S. Tasi, T. H. Huang,Combustion synthesis of Ni–Zn ferrite by using glycine and metal nitrates—investigations of precursor homogeneity, product reproducibility, and reaction mechanism, Mater. Chem. Phys., 93, 330(2005)
11	C. J. Leng, J. H. Wei, Z. Y. Liu, J. Shi,Influence of imidazolium-based ionic liquids on the performance of polyaniline-CoFe2O4 nanocomposites, J. Alloys Compd., 509, 3052(2011)
12	C. D. Prasanna, H. S. Jayanna, A. R. Lamani, S. Dash,Polyaniline/CoFe2O4 nanocomposites: A novel synthesis, characterization and magnetic properties, Synth. Met., 161, 2306(2011)
13	D. S. Birajadar, U. N. Debatwal, K. M. Jadhav,X-ray, IR and bulk magnetic properties of Cu1-xMnxFe2-2xO4 ferrite system, J. Mater. Sci., 37, 1443(2002)
14	L. C. Li, J. Jiang, F. Xu,Synthesis and ferromagnetic properities of novel Sm-substituted LiNi ferrite-polyaniline nanocomposite, Mater. Lett., 61, 1091(2007)
15	G. Namita, S. Kuldeep, O. Anil, D. P. Singh, S. K. Dhawan,Thermal, dielectric and microwave absorption properties of polyaniline-CoFe2O4 nanocomposites, Compos. Sci. Technol., 71, 1754(2011)
16	Y. P. Duan, G. L. Wu, X. G. Li,On the correlation between structural characterization and electromagnetic properties of doped polyaniline, Solid State Sci., 12, 1374(2010)
17	S. W. Phang, T. Hino, M. H. Abdullah, N. Kuramoto,Applications of polyaniline doubly doped with p-toluene sulphonic acid and dichloroacetic acid as microwave absorbing and shielding materials, Mater. Chem. Phys., 104, 327(2007)
18	T. H. Ting, R. P. Yu, Y. N. Jau,Synthesis and microwave absorption characteristics of polyaniline/NiZn ferrite composites in 2-40 GHz, Mater. Chem. Phys., 126, 364(2011)

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