材料研究学报  2013, Vol. 27 Issue (1): 85-90

研究论文 本期目录 | 过刊浏览 |

β-环糊精与油酸包合物的制备和摩擦学性能*

关集俱1 许雪峰1 何荣军2 黄亦申1 彭 伟1

1. 特种装备制造与先进加工技术教育部/浙江省重点实验室 (浙江工业大学) 杭州 30014 2. 浙江工业大学生物与环境工程学院 杭州 310014

Preparation and Tribological Performance of Complex of β-Cyclodextrin and Oleic Acid

GUAN Jiju1 XU Xuefeng1** HE Rongjun2 HUANG Yishen1 PENG Wei1

1. Key Laboratory of Special Purpose Equipment and Advanced Processing Technology (Zhejiang University of Technology), Ministry of Education Zhejiang Province, Hangzhou 310014 2. College of Biological and Environmental Engineering, Zhejiang University of Technology, Hangzhou 310014

关集俱 许雪峰 何荣军 黄亦申 彭 伟. β-环糊精与油酸包合物的制备和摩擦学性能*[J]. 材料研究学报, 2013, 27(1): 85-90.
GUAN Jiju XU Xuefeng** HE Rongjun HUANG Yishen PENG Wei. Preparation and Tribological Performance of Complex of β-Cyclodextrin and Oleic Acid[J]. Chinese Journal of Materials Research, 2013, 27(1): 85-90.

摘要 参考文献 相关文章 Metrics 全文: PDF(6544 KB)   摘要: 合成β-环糊精与油酸的包合物, 以包合物作为一种润滑添加剂, 用四球法研究了载荷、摩擦时间及添加量对其摩擦学性能的影响, 并分析了润滑机理。结果表明, 在196、294和392 N载荷下, 添加包合物的润滑液的摩擦系数均随时间的增加逐渐减小。在各种含量下, 包合物的抗磨性能都优于β-CD和油酸的, 含量为0.9%时, 添加包合物的润滑液具有最佳的减摩效果。在摩擦过程中, 包合物主体β-环糊精被分解, 释放客体油酸, 油酸通过化学吸附形成羧酸皂膜起主要润滑作用, β-环糊精的分解片段形成羟基吸附膜和碳沉积膜起辅助促进作用, 二者共同作用形成的复合润滑膜具有良好的摩擦学性能。 关键词 ： 有机高分子材料,  β-环糊精,  油酸,  包合物,  摩擦学性能     Abstract：ABSTRACT The complex of β-cyclodextrin (β-CD) and oleic acid was prepared as a kind of lubricant additive. The effects of testing load, friction time and additive content on tribological performance were investigated using four ball testing methods, and the lubrication mechanism of the complex was analyzed. The results showed that the friction coefficient of lubricant of complex continuously reduced with the increasing of time under the load of 196 N, 294 N and 392 N. The anti-wear property of complex was better than that of β-CD and oleic acid for different additive content. When the content was 0.9%, lubricant of complex had the best friction-reducing ability. The host β-CD molecules of complex were decomposed and guest oleic acid molecules were released during friction process. The carboxylic acid soap film formed by oleic acid played a major role in lubrication, and the alcohol chemisorption film and carbon deposition film formed by the fragments of β-CD played auxiliary and promoting role. They formed a composite lubricating film, which had better tribological performance under certain conditions.      ZTFLH:  TH117   服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 关集俱 许雪峰 何荣军 黄亦申 彭 伟 44.8K 链接本文: https://www.cjmr.org/CN/      或      https://www.cjmr.org/CN/Y2013/V27/I1/85 1 TONG Linhui, Cyclodextrin Chemistry Fundaments and Application (Beijing, Science Press, 2001) p.330 (童林荟, 环糊精化学-基础与应用 (北京, 科学出版社, 2001) p.330) 2 Disco Corporation, Electrodeposited grinding wheel and manufacturing method, CN Patent, 200610004514. X, 2006-8-16 (株式会社迪思科, 电沉积砂轮及其制造方法, 中国专利, 200610004514.X, 2006-8-16) 3 TENG Lin, SHI Xingkuan, REN Jingxin, On improving cooling and lubrication of grinding process, Journal of Northwestern Polytechnical University, 15(1), 7(1997) (滕 霖, 史兴宽, 任敬心, 增效浸渗砂轮的增效机理及其效果, 西北工业大学学报, 15(1), 7(1997)) 4 SONG Lexin, ZHOU Taoyu, GUO Zijian, Progress on supramolecular structure of inclusion compounds of cyclodextrins and their derivatives, Chinese Journal of Inorganic Chemistry, 17(1), 9(2001) (宋乐新, 周桃玉, 郭子建, 环糊精及其衍生物的超分子晶体结构研究进展, 无机化学学报, 17(1), 9(2001)) 5 F. P. Bowden, D. Tabor, The Friction and Lubrication of Solids, 1st, (Oxford, Clarendon Press, 1986) p.202 6 S. Jahanmir, Chain length effects in boundary lubrication, Wear, 102(4), 331(1985) 7 WANG Jiugen, ZHANG Jianzhong, On formation and breakup of boundary lubricating layer, Lubrication Engineering, 172(6), 5(2005) (汪久根, 张建忠, 边界润滑膜的形成与破裂分析, 润滑与密封, 172(6), 5(2005)) 8 G. Heinicke, Tribochemistry, 1st (Berlin, Akademie-Verlag, 1984) p.18 9 C. Kajdas, Importance of the triboemission process for tribochemical reaction, Tribol. Int., 38(3), 337(2005) 10 M. Majzner, C. Kajdas, Reactions of carboxylic acids under boundary friction conditions, Tribologia, 34(1), 63(2003) 11 D. A. Fischer, Z. S. Hu, S. M. Hsu, Tribochemical and thermochemical reactions of stearic acid on copper surfaces in air as measured by ultrasoft X-ray absorption spectroscopy, Tribol. Lett., 3(1), 35(1997) 12 D. Briggs, Surface Analysis of Polymers by XPS and Static SIMS, 1st (London, Cambridge University Press, 1998) p.64 13 C. Kajdas, About an ionic-radical concept of the lubrication mechanism of alcohols, Wear, 116(6), 167(1987) 14 ZHANG Ruijun, LI Shenghua, JIN Yuansheng, FT-IR and Raman spectroscopic evaluation of products derived from pyrolyzed lubricant during friction and wear, J. Tsinghua. Univ. (Sci. & Tech.), 43(5), 648(2003) (张瑞军, 李生华, 金元生, 润滑油摩擦碳化物的FT-IR及Raman评价, 清华大学学报(自然科学版), 43(5), 648(2003)) 15 WANG Rulin, Tribochemistry of Lubricant (Beijing, China Petrochemical Press, 1994) p.16 (王汝霖, 润滑剂摩擦化学 (北京, 中国石化出版社, 1994) p.16) 16 HUANG Ping, MENG Yonggang, XU Hua, Tribology Course (Beijing, Higher Education Press, 2007) p.406 (黄 平, 孟永刚, 徐 华, 摩擦学教程 (北京, 高等教育出版社, 2007) p.406) [1] 叶姣凤, 王飞, 左洋, 张钧翔, 罗晓晓, 冯利邦. 兼具高强度、高韧性和自修复性能的环氧树脂改性热可逆聚氨酯[J]. 材料研究学报, 2023, 37(4): 257-263. [2] 李瀚楼, 焦晓光, 朱欢欢, 赵晓欢, 矫庆泽, 冯彩虹, 赵芸. 支链含氟聚酯的合成和性能[J]. 材料研究学报, 2023, 37(4): 315-320. [3] 马逸舟, 赵秋莹, 杨路, 裘进浩. 热塑型聚酰亚胺/聚偏氟乙烯全有机复合薄膜的制备及其介电储能[J]. 材料研究学报, 2023, 37(2): 89-94. [4] 殷洁, 胡云涛, 刘慧, 杨逸霏, 王艺峰. 基于电沉积技术构建聚苯胺/海藻酸膜及电化学性能研究[J]. 材料研究学报, 2022, 36(4): 314-320. [5] 申延龙, 李北罡. 磁性氨基酸功能化海藻酸铝凝胶聚合物的制备及对偶氮染料的超强吸附[J]. 材料研究学报, 2022, 36(3): 220-230. [6] 龙庆, 王传洋. 不同碳黑含量PMMA的热降解行为和动力学分析[J]. 材料研究学报, 2022, 36(11): 837-844. [7] 蒋平, 吴丽华, 吕太勇, José Pérez-Rigueiro, 王安萍. 蜘蛛大壶状腺丝的反复拉伸力学行为和性能[J]. 材料研究学报, 2022, 36(10): 747-759. 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