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材料研究学报  2013, Vol. 27 Issue (1): 60-64    
  研究论文 本期目录 | 过刊浏览 |
不同媒介金属层的铅/钢层状复合材料的性能*
梁方1 竺培显1 周生刚1 周亚平2 马会宇1
1. 昆明理工大学 材料科学与工程学院 昆明 650093
2. 昆明理工大学 信息工程与自动化学院 昆明 650093
Influence of Medium Layer on Interface and Properties of Lead/Steel Laminated Composites
LIANG Fang1 ZHU Peixian1** ZHOU Shenggang1 ZHOU Yaping2 MA Huiyu1
1. Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming 650093
2. Faculty of Information Engineering and Automation, Kunming University of Science and Technology, Kunming 650093
引用本文:

梁方 竺培显 周生刚 周亚平 马会宇. 不同媒介金属层的铅/钢层状复合材料的性能*[J]. 材料研究学报, 2013, 27(1): 60-64.
LIANG Fang ZHU Peixian** ZHOU Shenggang ZHOU Yaping MA Huiyu. Influence of Medium Layer on Interface and Properties of Lead/Steel Laminated Composites[J]. Chinese Journal of Materials Research, 2013, 27(1): 60-64.

全文: PDF(5575 KB)  
摘要: 选取Ⅰ(50%Pb-50%Sn)、Ⅱ(35%Pb-60%Sn-5%Zn)两种合金焊料, 采用热浸镀的方法在钢表面覆镀媒介金属, 用过渡液相扩散焊接技术将镀膜钢板与铅板进行焊合, 制备铅/钢层状复合材料。借助SEM, XRD等手段对样品的界面形貌及生成相进行了测试, 使用电化学工作站、四探针法等手段分别对试样的物理及化学性能进行了测试。结果表明:铅/钢层状复合材料的界面结合良好。与传统铅阳极样品比较, 优化工艺参数制得的铅/钢层状复合阳极样品的电极电位分别负移120 mV和180 mV, 催化活性明显提高。两种铅/钢层状复合材料电阻率下降了28%—40%。
关键词 复合材料 铅/钢层状复合材料 低熔点合金 界面形貌 阳极材料    
Abstract:ABSTRACT I (50%Pb-50%Sn) and Ⅱ(35%Pb-60%Sn-5%Zn) solder alloys were selected as a medium layer, and the solder alloys were plated by hot dipping. Both hot-dipped steel and lead were welded by transient liquid phase diffusion bonding-TLP, and the lead/steel laminated composites were obtained. The interface morphology and phase of samples were observed by SEM and XRD. Physical and chemical properties were tested by electrochemical workstation and four-probe techniques. The results show that the interface of lead/steel laminated composite is good. Comparing with conventional lead anode, the electrode potential of layered composite anodes which prepared by optimized parameters decreased 120 mV and 180 mV, respectively. The catalytic activity of the samples was significantly improved; The resistivity of composites decreased 28%—40%.
    
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