Please wait a minute...
材料研究学报  2012, Vol. 26 Issue (6): 610-614    
  研究论文 本期目录 | 过刊浏览 |
聚丙烯接枝苯乙烯磺酸--聚苯胺抗静电剂的制备和性能
祖立武, 张晓宇, 王雅珍,  薛守成, 徐岽双, 张小舟
齐齐哈尔大学材料科学与工程学院 齐齐哈尔 161006
Preparation and Properties of Polypropylene Grafted Styrene Sulfonic Acid–polyaniline Antistatic Agents
ZU Liwu, ZHANG Xiaoyu, WANG Yazhen, XUE Shoucheng, XU Dongshuang, ZHANG Xiaozhou
College of Materials Science and Engineering, Qiqihar University, Qiqihar 161006
引用本文:

祖立武 张晓宇 王雅珍 薛守成 徐岽双 张小舟. 聚丙烯接枝苯乙烯磺酸--聚苯胺抗静电剂的制备和性能[J]. 材料研究学报, 2012, 26(6): 610-614.
ZU Liwu ZHANG Xiaoyu WANG Yazhen XUE Shoucheng XU Dongshuang ZHANG Xiaozhou. Preparation and Properties of Polypropylene Grafted Styrene Sulfonic Acid–polyaniline Antistatic Agents[J]. Chinese Journal of Materials Research, 2012, 26(6): 610-614.

全文: PDF(979 KB)  
摘要: 

以聚丙烯(PP)为基体, 以丙烯酸为掺杂剂, 采用溶液接枝法制备了聚丙烯接枝苯乙烯磺酸--聚苯胺(PP--g--SPS--PANI)高分子复合物, 用红外光谱仪、ZC--90数字高阻计和扫描电子显微镜等手段对高分子抗静电剂进行了表征。研究了引发剂用量、丙烯酸用量等因素对其抗静电性能的影响, 结果表明: 抗静电剂性能随着丙烯酸、引发剂用量增加先升高后降低, 丙烯酸掺杂使复合到PP分子链上聚苯胺分子链上的电荷离域形成共轭结构而具有导电性能, 当丙烯酸用量与聚丙烯接枝苯乙烯磺酸质量比m丙烯酸/
mPP-g-SPS=7:1, 引发剂与苯胺摩尔比nAPS/nANI=2:1时复合效率最高, 抗静电效果最好, 抗静电剂与PP共混物的电阻率下降到9.5×1012Ω·cm。对PP共混物界面的SEM测试结果表明, 共混物具有良好的相容性。

关键词 有机高分子材料聚丙烯抗静电剂溶液接枝聚苯胺    
Abstract

Polymer complex of polypropylene grafted styrene sulfonic acid–polyaniline(PP–g–SPS–PANI) was prepared by solution grafting to acrylic acid as a dopant and polypropylene (PP) as the matrix. PP–g–SPS–PANI were characterized by fourier transfer infrared spectrometry(FTIR), ZC–90 digital impedance meter and scanning electron microscopy(SEM). The amount of acrylic and initiator to influence on antistatic properties were studied. The results showed that the antistatic properties of PP–g–SPS–PANI increased with the amount of the acrylic and initiator, and then decreased. Acrylic doped so that PANI molecular chain formed charge delocalized conjugated structure and having conductive properties. The complex efficient and antistatic properties of antistatic agents are best when the mass ratio of acrylic with
polypropylene graft styrene sulfonamide acid(PP–g–SPS) macrylic/mPP−g−SPS=7:1, the molar ratio of initiator with aniline nAPS/nANI=2:1. The volume resistivity of PP–g–SPS–PANI/PP blends decreased to 9.5×1012Ω·cm. SEM results show that the interface of PP blends has a good compatibility.

Key wordsorganic polymer materials    polypropylene antistatic agent    solution grafting    polyaniline
收稿日期: 2012-05-29     
ZTFLH:  TB324  
基金资助:

黑龙江省教育厅12521613和黑龙江省科学自然基金重点ZD201101资助项目。

1 K.B.Cheng, K.C.Leeb, T.H.Uengc, Electrical and impact properties of the hybrid knitted inlaid fabric reinforced  polypropylene composites, Composites Part A, 1216, 1219(2002)

2 Guoliang Tao, Aijun Gong, Jianjun Lu, Hung–Jue Sue, David E. Bergbreiter, Surface functionalized polypropylene: synthesis, characterization, and adhesion properties, Macromolecules, 34(22), 7672(2001)

3 Wentian Lin, Zhen Shao, Jinyong Dong, T.C.Mike Chung, Cross–linked polypropylene prepared by PP copolymers containing flexible styrene groups, Macromolecules, 42(11), 3750(2009)

4 Kazimiera A. Wilk, Ryszard Po zniak, Adam Sokolowski, Antistatic and wetting properties of chemodegradable cationic surfactants containing 1,3–dioxolane moiety, Journal of Surfactants and Detergents, 3(2), 207(2000)

5 Bohwon Kim, Vladan Koncar, Eric Devaux, Electrical and morphological properties of PP and PET conductive polymer fibers, Synthetic Metals, 167, 174(2004)

6 Jiku Wang, Xuyan Liu, Ho–Suk Choi, Jong–Hoon Kim,Conducting polymer films fabricated by oxidative graft copolymerization of aniline on poly(acrylic acid) grafted poly(ethylene terephthalate) surfaces, Phys. Chem. B, 112(47), 14829(2008)

7 Suzuki, Masahiro, Antistatic agent for synthetic polymer materials and method of application thereof, US, 6225386,2001

(铃  木, 正  宏, 高分子材料抗静电剂的合成方法及其应用, 美国, 6225386, 2001)

8 Yamasaki S, Koga T, Ohura H, Electrical conductivity effect of polyanili ne addition to poly(ethylene oxide) electrolyte film containing lithium Perchlor ate, J Mater Sci Lett, 15, 225(1996)

9 Z.M.Wang, H.Hong, T.C.Chung, Synthesis of maleic anhydride grafted polypropylene with high molecular weight using borane/O2 radical initiator and commercial PP polymers, Macromolecules, 38(22), 8966(2005)

10 Gangopadhyay R, De A, Ghosh G, Polyaniline–poly (vinylalcohol) conducting composite: material with easy process ability and novel application potential, Synthetic Metals, 123(1), 21(2001)

11 ZHANG Hongbo, SU Chunhui, LI Lin, Study of synthesis and property of the new antistatic agent, Journal of Materials Science and Engineering, 22(1), 121(2004)

(张洪波, 苏春辉, 李 林, 新型抗静电剂的合成及性能研究, 材料科学与工程学报,  22(1), 121(2004))

12 LIN Lin, WANG Cunguo, ZHANG Ping, YANG Lei, XIAO Hongjie, LI Binghai, LI Dapeng, ZHAO Qiang, Preparation of antistatic and flame retarding material by polypropylene composites filled with conductive polyacenic semiconductor material, Chemical Journal of Chinese Universities, 29(6), 1276(2008)

(林  琳, 王存国, 张  萍, 杨  蕾, 肖红杰, 李炳海, 李大鹏, 赵  强, 聚并苯纳米颗粒与聚丙烯复合制备新型抗静电阻燃材料, 高等学校化学学报,  29(6), 1276(2008))

13 GUO Jing, SHEN Xinyuan, LI Fuqing, BAI Lan, PEG–ZnO–PP composite antistatic agent and its modification for polypropylene fiber, China Synthetic Fiber Industry, 30(1), 31(2007)

(郭 静, 沈新元, 李福清, 白 兰, PEG--ZnO--PP复合抗静电剂及其对聚丙烯纤维的改性, 合成纤维工业,  30(1), 31(2007))

[1] 叶姣凤, 王飞, 左洋, 张钧翔, 罗晓晓, 冯利邦. 兼具高强度、高韧性和自修复性能的环氧树脂改性热可逆聚氨酯[J]. 材料研究学报, 2023, 37(4): 257-263.
[2] 李瀚楼, 焦晓光, 朱欢欢, 赵晓欢, 矫庆泽, 冯彩虹, 赵芸. 支链含氟聚酯的合成和性能[J]. 材料研究学报, 2023, 37(4): 315-320.
[3] 马逸舟, 赵秋莹, 杨路, 裘进浩. 热塑型聚酰亚胺/聚偏氟乙烯全有机复合薄膜的制备及其介电储能[J]. 材料研究学报, 2023, 37(2): 89-94.
[4] 殷洁, 胡云涛, 刘慧, 杨逸霏, 王艺峰. 基于电沉积技术构建聚苯胺/海藻酸膜及电化学性能研究[J]. 材料研究学报, 2022, 36(4): 314-320.
[5] 申延龙, 李北罡. 磁性氨基酸功能化海藻酸铝凝胶聚合物的制备及对偶氮染料的超强吸附[J]. 材料研究学报, 2022, 36(3): 220-230.
[6] 龙庆, 王传洋. 不同碳黑含量PMMA的热降解行为和动力学分析[J]. 材料研究学报, 2022, 36(11): 837-844.
[7] 蒋平, 吴丽华, 吕太勇, José Pérez-Rigueiro, 王安萍. 蜘蛛大壶状腺丝的反复拉伸力学行为和性能[J]. 材料研究学报, 2022, 36(10): 747-759.
[8] 鄢俊, 杨进, 王涛, 徐桂龙, 李朝晖. 有机硅油改性水性酚醛的制备及其性能[J]. 材料研究学报, 2021, 35(9): 651-656.
[9] 张昊, 李帆, 常娜, 王海涛, 程博闻, 王攀磊. 羧酸型接枝淀粉吸附树脂的制备和对染料的去除性能[J]. 材料研究学报, 2021, 35(6): 419-432.
[10] 孙丽颖, 钱建华, 赵永芳. AgNWs-TPU/PVDF柔性薄膜电容传感器的制备和性能[J]. 材料研究学报, 2021, 35(6): 441-448.
[11] 杨小刚, 崔世宏, 李斌, 王传洁, 韩捷佳. 石墨烯/醋酸掺杂态聚苯胺的制备及其防腐性能[J]. 材料研究学报, 2021, 35(5): 357-363.
[12] 唐开元, 黄洋, 黄湘舟, 葛颖, 李娉婷, 袁凡舒, 张威威, 孙东平. 碳化细菌纤维素的理化性质及其在甲醇电催化中的应用[J]. 材料研究学报, 2021, 35(4): 259-270.
[13] 苏晨文, 张婷玥, 郭丽伟, 李乐, 杨苹, 刘艳秋. 用于模拟细胞外基质的硫醇-烯水凝胶的制备[J]. 材料研究学报, 2021, 35(12): 903-910.
[14] 张向阳, 章奇羊, 汤涛, 郑涛, 柳浩, 刘国金, 朱海霖, 朱海峰. 基于MOFs的复合材料制备及其对亚甲基蓝染料的吸附性能[J]. 材料研究学报, 2021, 35(11): 866-872.
[15] 万里鹰, 肖洋, 张伦亮. 基于热可逆Diels-Alder动态共价键PU-DA体系的制备和性能[J]. 材料研究学报, 2021, 35(10): 752-760.