材料研究学报  2010, Vol. 24 Issue (5): 478-482

研究论文 本期目录 | 过刊浏览 |

溶胶粒径对氧化硅减反射膜结构和光学性能的影响

倪志龙1, 王彪1,2,  杨晔1, 宋伟杰1

1.中国科学院宁波材料技术与工程研究所 宁波 315201 2.中国科学院上海硅酸盐研究所 上海 200050

Effect of Colloid Particle Sizes on Microstructure and Optical Properties of the Silica Antireflective Coatings

NI Zhilong1,  WANG Biao1,2,  YANG Ye1,  SONG Weijie1

1.Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201 2.Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050

倪志龙 王彪 杨晔 宋伟杰. 溶胶粒径对氧化硅减反射膜结构和光学性能的影响[J]. 材料研究学报, 2010, 24(5): 478-482.
, , , . Effect of Colloid Particle Sizes on Microstructure and Optical Properties of the Silica Antireflective Coatings[J]. Chin J Mater Res, 2010, 24(5): 478-482.

摘要 参考文献 相关文章 Metrics 全文: PDF(825 KB)   摘要: 以正硅酸四乙酯为前驱体, 制备出粒径20--100 nm的二氧化硅溶胶。用提拉法在玻璃基片上制备出氧化硅基多孔减反射膜, 并研究了不同粒径的二氧化硅溶胶老化后溶胶胶粒的微观结构与相应的多孔氧化硅减反射膜微观孔结构的差异。 结果表明, 颗粒粒径约20 nm的硅溶胶在老化过程中易团聚成较大的二次颗粒, 形成结构疏松的氧化硅多孔减反射薄膜。镀有这种减反射膜的玻璃, 其峰值透过率在波长510 nm处达到99.2%。 关键词 ： 无机非金属材料 ,   ,  减反射膜 ,   溶胶凝胶法 ,   氧化硅 ,   粒径     Abstract：The silica sols of particle size 20--100 nm were prepared using tetraethyl silicate as precursor. The porous silica antireflective coatings were prepared on the glass by the dip-coating method. The microstructure of sol particles with different particle size after aging and their influence on porous silica antireflective coating were investigated. Results show that the small silica colloid particles with size -20 nm reunit into large secondary particles during the aging process. The antireflective coating prepared of secondary particles has the desired loose structure and the peak transmittance of glass with the antireflective coating reaches 99.2% at 510 nm. Key words： inorganic non-metallic materials     antireflective coating     sol-gel     silica     particle size 收稿日期: 2010-01-24      ZTFLH:  O484   基金资助: 国家自然科学基金20975107、中国博士后基金和中科院百人计划资助项目。 服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 倪志龙 宋伟杰 王彪 杨晔 44.8K 链接本文: https://www.cjmr.org/CN/      或      https://www.cjmr.org/CN/Y2010/V24/I5/478 1 I.M. Thomas, High laser damage threshold porous silica antireflective coating, Applied Optics，25 (9), 1481-1483 (1986) 2 C. Ballif, J. Dicker, D. Borchert, T. Hofmann, Solar glass with industrial porous SiO2 antireflection coating: measurements of photovoltaic module properties improvement and modelling of yearly energy yield gain, Solar Energy Materials & Solar Cells, 82, 331-334 (2004) 3 T.H. Elmer, H. Walters, Method for providing porous broad-band antireflective surface layers on chemically-durable borosilicate glasses, 美国, US 4019884 (1977) 4 J.Q. XI, M.F. Schubert, J.K. Kim, E.F. Schubert, M. Chen, S.Y. Lin, W. Liu, J.A. 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Born, Controlled growth of monodisperse silica spheres in the micron size range, Journal of Colloid and Interface Science, 26 (1), 62-69 (1968) 10 R. Takahashi, K. Nakanishi, N. Soga, Effects of aging and solvent exchange on pore structure of silica gels with interconnected macropores, Journal of Non-Crystalline Solids, 189 (2), 66-76 (1995) 11 FU Yuanxiang, SUN Yanhui, GE Xingxin, Synthesis and characterization of monodisperse SiO2 Nanoparticles, Bulletin of the Chinese Ceramic Society, 27 (1), 154-159 (2008) (符远翔，孙艳辉，葛杏心，单分散纳米二氧化硅的制备与表征，硅酸盐通报，27 (1)， 154-159 (2008)) 12 G.H. Bogush, M.A. Tracy, C.F. Zukoski IV, Preparation of monodisperse silica particles: Control of size and mass fraction, Journal of Non-Crystalline Solids, 104 (1), 95-106 (1988) 13 XIONG Huashan, CHEN Ning, ZHANG Qinghua, WANG Ke, YIN Qinjian, JIANG Bo, Study on the SiO2 antireflective coatings prepared from sol-gel process, Journal of Functional Materials, 35 (4), 485-486 (2004) （熊华山，陈宁，张清华，王克，殷勤俭，江波，Sol-gel制备SiO2增透膜的研究，功能材料，35 (4)，485-486 (2004)) 14 TANG Jiamiao, ZHU Congshan, Effect of Particles Distribution on Antireflectivity of the Coatings, Acta Optica Sinica, 17 (3), 338-341 (1997) (汤加苗，朱从善，溶胶颗粒度分布对溶胶-凝胶光学增透膜性能的影响，光学学报，17 (3)，338-341 (1997) [1] 宋莉芳, 闫佳豪, 张佃康, 薛程, 夏慧芸, 牛艳辉. 碱金属掺杂MIL125的CO2 吸附性能[J]. 材料研究学报, 2023, 37(9): 649-654. [2] 邵鸿媚, 崔勇, 徐文迪, 张伟, 申晓毅, 翟玉春. 空心球形AlOOH的无模板水热制备和吸附性能[J]. 材料研究学报, 2023, 37(9): 675-684. [3] 任富彦, 欧阳二明. g-C3N4 改性Bi2O3 对盐酸四环素的光催化降解[J]. 材料研究学报, 2023, 37(8): 633-640. [4] 刘明珠, 樊娆, 张萧宇, 马泽元, 梁城洋, 曹颖, 耿仕通, 李玲. SnO2 作散射层的光阳极膜厚对量子点染料敏化太阳能电池光电性能的影响[J]. 材料研究学报, 2023, 37(7): 554-560. 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