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材料研究学报  2010, Vol. 24 Issue (2): 213-216    
  研究论文 本期目录 | 过刊浏览 |
YAl3(BO3)4:Eu 3+荧光粉的高温球磨制备和发光性能
贾林艳1;2; 邵忠宝2
1.牡丹江师范学院 牡丹江 157012
2.东北大学理学院 沈阳 110004
Preparation and Luminescence of Yttrium Aluminoborate Doped with Eu 3+ Ions
JIA Linyan1;2; SHAO Zhongbao2
1.Mudanjiang Normal University; Mudangjiang 157012
2.College of science; Northeastern University; Shenyang 110004
引用本文:

贾林艳 邵忠宝. YAl3(BO3)4:Eu 3+荧光粉的高温球磨制备和发光性能[J]. 材料研究学报, 2010, 24(2): 213-216.
, . Preparation and Luminescence of Yttrium Aluminoborate Doped with Eu 3+ Ions[J]. Chin J Mater Res, 2010, 24(2): 213-216.

全文: PDF(638 KB)  
摘要: 

以稀土氧化物、硝酸铝和硼酸为原料, 用高温球磨法制备红色荧光粉YAl3(BO3)4:Eu3+, 研究其结构、形貌和发光性能。结果表明, 在700℃高温球磨制备YAl3(BO3)4:Eu3+荧光粉, 煅烧温度比硝酸盐分解法降低200℃, 比高温固相法降低500℃; 制备出的荧光粉粒度分布均匀, 晶粒近似呈球状, 尺寸为纳米级; 在394 nm的紫外光激发下YAl3(BO3)4:Eu3+荧光粉具有较好的发光性能, 发射光以波长为618 nm的红光(Eu 3+离子5D0→ 7F2 跃迁)为主; Eu 3+的最佳掺杂量为15%。

关键词 无机非金属材料 发光性 高温球磨 YAl3(BO3)4 Eu3+    
Abstract

The red phosphor yttrium aluminoborate doped with Eu 3+ was prepared by high temperature ball milling method. The phosphor was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and luminescence spectroscopy. The results show that Y 3+ ions are replaced by Eu 3+ ions in view of their similar sizes and valence state, the Eu 3+ ions are non-centrosymmetric sites in YAl3(BO3)4:Eu3+. The synthesis temperature of high temperature ball milling method is 700oC  , which is obviously decreased in contrast to that of nitrate salts decomposition method (900oC ) and conventional solid state reaction method (1200oC ). The particles are approximately nanometer-sized with narrow distribution range and spherical morphology. In the emission spectra under 394 nm excitation, the strongest peak at 618 nm is due to the forced electric dipole transition 5D0→ 7F2 of Eu 3+ ions.

Key wordsinorganic non-metallic materials     luminescence    high temperature ball milling    YAl3(BO3)4 Eu3+
收稿日期: 2009-12-10     

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