Please wait a minute...
材料研究学报  2009, Vol. 23 Issue (4): 399-404    
  研究论文 本期目录 | 过刊浏览 |
甲基丙烯酸丁酯/苯乙烯共聚物纤维的制备和性能
张玉婷;  肖长发
天津工业大学改性与功能纤维天津市重点实验室 天津 300160
Preparation and properties of butyl methacrylate/styrene copolymer fiber
ZHANG Yuting; XIAO Changfa
Tianjin Municipal Key Label of Fiber Modification and Functional Fiber; Tianjin Polytechnic University; Tianjin 300160
引用本文:

张玉婷 肖长发. 甲基丙烯酸丁酯/苯乙烯共聚物纤维的制备和性能[J]. 材料研究学报, 2009, 23(4): 399-404.
. Preparation and properties of butyl methacrylate/styrene copolymer fiber[J]. Chin J Mater Res, 2009, 23(4): 399-404.

全文: PDF(977 KB)  
摘要: 

以过氧化苯甲酰(BPO)为引发剂, 采用水相悬浮聚合法合成了甲基丙烯酸丁酯(BMA)/苯乙烯(St)共聚物, 将共聚物溶于N, N--二甲基乙酰胺(DMAc) 中配制成纺丝溶液, 将其用湿法纺丝成形后制备出具有吸附弱极性液态有机物(油品)功能的甲基丙烯酸丁酯/苯乙烯共聚物纤维. 用傅里叶红外光谱仪(FTIR)和1H核磁共振波谱仪(NMR)研究了共聚物的化学结构, 用热重分析仪(TG)、动态热机械分析仪(DMA)、单丝强力仪等对纤维的相关性能进行了分析. 结果表明, BMA/St70/30共聚物纤维的性能良好, 对煤油、石油醚和庚烷等油品的饱和吸附率分别达到3.7 g/g纤维、5.3 g/g纤维和4.1 g/g纤维.

关键词 有机高分子材料甲基丙烯酸丁酯苯乙烯共聚物纤维吸附特性    
Abstract

Butyl methacrylate/styrene copolymer was synthesized with butyl methacrylate and styrene monomer by suspension polymerization, with BPO as initiator. The spinning liquid was prepared by dissolving synthetic copolymer into dimethyl acetylamide (DMAc) and then spun into fibers. The fiber with absorption function was obtained. The methacrylate/styrene copolymer were characterized by FTIR and 1H nuclear magnetic resonance (NMR) spectrometer. The related performance of copolymer fiber were analysized by thermogravimetric analysis (TG), dynamic mechanical analysis (DMA) and single–wire power equipment. It showed that BMA/St70/30 copolymer fiber which had better absorptive ability for specific kinds of oil was prepared had good performance. Its per gram methacrylate/styrene copolymer fiber saturated absorbency of kerosene, petroleumether, gasoline was 3.7 g kerosene/g copolymer fiber, 5.3 g petroleum/g copolymer fiber, 4.1 g heptane/g copolymer fiber respectively.

Key wordsorganic polymer materials    butyl methacrylate    styrene    copolymer fiber    absorptive performance
收稿日期: 2009-02-27     
ZTFLH: 

TB324

 
基金资助:

国家自然科学基金50673077项目资助.

1 Blaney, Carol Ann, Oil–sorbing article and methods for making and using same, United States Patent, 5, 834, 385. 1998 – 11 – 10 2 WANG Kexin, CHEN Jiangping, Study on molecular weight of butyl methacrylate–styrene copolymer–viscosity. Guangxi Chemical Industry and Technology, 3, 35(1989) (王克信, 陈江平, 甲基丙烯酸丁酯--苯乙烯共聚物分子量的测定--粘度法, 广西化工,  3, 35(1989)) 3 ZOU Yousi, QIU Zhiping, ZHUANG Rongchuan, LIN Donghai, DAI Lizong, Atom transfer radical copolymerization of styrene and butyl methacrylate, Acta Polymerica Sinica, 2, 146(1999) (邹友思, 邱志平, 庄荣传, 林东海, 戴李综, 甲基丙烯酸丁酯和苯乙烯的原子转移自由基共聚, 高分子学报,  2, 146(1999)) 4 JANG Jyongsik, KIM Beom–seok, Studies of crosslinked styrene-alkyl acrylate copolymers for oil absorbency application (I) Synthesis and characterization, J. Appl. Polym. Sci., 77, 903(2000) 5 JANG Jyongsik, KIM Beom–seok, Studies of crosslinked styrene-alkyl acrylate copolymers for oil absorbency application (II) Effects of polymerization conditions on oil absorbency, J. Appl. Polym. Sci., 77, 914(2000) 6 LI Yunyun, SHU Wubing, ZAN Lina, Studies on the synthesis of high oil–absorbing resin by copolymerization, Chemical Industry and Engineering Progress, 26(6), 842(2007) (李芸芸, 舒武炳, 昝丽娜, 二元共聚高吸油树脂的合成工艺, 化工进展,  26(6), 842(2007)) 7 Gordon S. Bond, Southlake, Tex, Process for deabsorbing oil from oil absorbent.US, 5244566(1993) 8 Richard Middleton, Mehtod and system for removing oil from oil absorbent material, US, 5538646(1996) 9 HAN Zhewen, Polymer Science Experiment, (Shanghai, East China university of science technology press, 2004) p.56 (韩哲文, 高分子科学实验  (上海, 华东理工大学出版社, 2004) p.56) 10 WANG Yifeng, FENG Yan, GE Zhaogang, XIAO Changfa, Preparation and oil absorptivity of  polystearylmethacrylate, China Plastics Industry, 34(10), 7(2006) (王仪凤, 封 严, 葛兆刚, 肖长发, 聚甲基丙烯酸十八酯的制备及吸油性能, 塑料工业, 34(10), 7(2006)) 11 Mei Hua Zhou, Won–Jei Cho, Synthesis and properties of high oil–absorbent4–tert–butylstyrene–EPDM– divinylbenzene graft terpolymer, Appl. Poly. Sci., 85(10), 2119(2002) 12 LU Jiang, LIANG Hui, Polymer chemistry, (Beijing, Chemical industry press, 2006) p.98 (卢江, 梁 晖, 高分子化学, (北京, 化学工业出版社, 2006) p.98) 13 YU Dequan, YANG Junshan, Nuclear Magnetic Resonance spectra, (Beijing, Chemical industry press, 2000)p.59 (于德泉, 杨俊山,  分析化学手册(第七分册)--核磁共振波谱分析(北京, 化学工业出版社, 2000) p.59) 14 LU Zhibao, WU Pingping, HAN Zhewen, Study on measurement of relative reactivity ratios of styrene and butyl methacrylate by nuclear magnetic resonance spectrometry, Acta Polymerica Sinica, 1, 47(1996) (陆志豹, 吴平平, 韩哲文, 核磁共振法测定苯乙烯--甲基丙烯酸丁酯竞聚率的研究, 高分子学报,  1, 47(1996)) 15 GUO Junmin, YAN Guoliang, WANG Shuangyan, Analysis of the structure of amorphous area in polyester fibers with DMA method, Petrochemical Technology in Jinshan, 23(2), 6(2004) (郭俊敏, 严国良, 王双燕, DMA法分析聚酯纤维无定形区结构, 金山油化纤, 23(2), 6(2004) 16 GU Junwei, ZHANG Guangcheng, DONG Shanlai, Study on thermal analysis of polyester resin, China Paint, 20(9), 26(2005) (顾军渭, 张广成, 董善来等. 聚酯树膳防火涂料阻燃体系的热分析研究, 中国涂料,  20(9), 26(2005)) 17 D.Kilburn, G.Dlubek, Free volume in poly(n-alkyl methacrylate)s from positron lifetime and PVT experiments and its relation to the structural relaxation, Polymer, (47), 7774(2006)
[1] 叶姣凤, 王飞, 左洋, 张钧翔, 罗晓晓, 冯利邦. 兼具高强度、高韧性和自修复性能的环氧树脂改性热可逆聚氨酯[J]. 材料研究学报, 2023, 37(4): 257-263.
[2] 李瀚楼, 焦晓光, 朱欢欢, 赵晓欢, 矫庆泽, 冯彩虹, 赵芸. 支链含氟聚酯的合成和性能[J]. 材料研究学报, 2023, 37(4): 315-320.
[3] 马逸舟, 赵秋莹, 杨路, 裘进浩. 热塑型聚酰亚胺/聚偏氟乙烯全有机复合薄膜的制备及其介电储能[J]. 材料研究学报, 2023, 37(2): 89-94.
[4] 殷洁, 胡云涛, 刘慧, 杨逸霏, 王艺峰. 基于电沉积技术构建聚苯胺/海藻酸膜及电化学性能研究[J]. 材料研究学报, 2022, 36(4): 314-320.
[5] 申延龙, 李北罡. 磁性氨基酸功能化海藻酸铝凝胶聚合物的制备及对偶氮染料的超强吸附[J]. 材料研究学报, 2022, 36(3): 220-230.
[6] 龙庆, 王传洋. 不同碳黑含量PMMA的热降解行为和动力学分析[J]. 材料研究学报, 2022, 36(11): 837-844.
[7] 蒋平, 吴丽华, 吕太勇, José Pérez-Rigueiro, 王安萍. 蜘蛛大壶状腺丝的反复拉伸力学行为和性能[J]. 材料研究学报, 2022, 36(10): 747-759.
[8] 鄢俊, 杨进, 王涛, 徐桂龙, 李朝晖. 有机硅油改性水性酚醛的制备及其性能[J]. 材料研究学报, 2021, 35(9): 651-656.
[9] 张昊, 李帆, 常娜, 王海涛, 程博闻, 王攀磊. 羧酸型接枝淀粉吸附树脂的制备和对染料的去除性能[J]. 材料研究学报, 2021, 35(6): 419-432.
[10] 孙丽颖, 钱建华, 赵永芳. AgNWs-TPU/PVDF柔性薄膜电容传感器的制备和性能[J]. 材料研究学报, 2021, 35(6): 441-448.
[11] 唐开元, 黄洋, 黄湘舟, 葛颖, 李娉婷, 袁凡舒, 张威威, 孙东平. 碳化细菌纤维素的理化性质及其在甲醇电催化中的应用[J]. 材料研究学报, 2021, 35(4): 259-270.
[12] 苏晨文, 张婷玥, 郭丽伟, 李乐, 杨苹, 刘艳秋. 用于模拟细胞外基质的硫醇-烯水凝胶的制备[J]. 材料研究学报, 2021, 35(12): 903-910.
[13] 张向阳, 章奇羊, 汤涛, 郑涛, 柳浩, 刘国金, 朱海霖, 朱海峰. 基于MOFs的复合材料制备及其对亚甲基蓝染料的吸附性能[J]. 材料研究学报, 2021, 35(11): 866-872.
[14] 万里鹰, 肖洋, 张伦亮. 基于热可逆Diels-Alder动态共价键PU-DA体系的制备和性能[J]. 材料研究学报, 2021, 35(10): 752-760.
[15] 张翠歌, 胡良, 卢祖新, 周佳慧. 基于海藻酸自组装胶体粒子的制备及其乳化性能[J]. 材料研究学报, 2021, 35(10): 761-768.