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材料研究学报  2009, Vol. 23 Issue (2): 123-126    
  研究论文 本期目录 | 过刊浏览 |
溶剂热法制备太阳电池用NaYF4:Yb3+,  Er3+纳米上转换材料
刘永娟1;2;   张晓丹1;  王东丰1;  张存善2;  赵颖1
1.南开大学光电子薄膜器件与技术研究所; 南开大学光电子薄膜器件与技术天津市重点实验室;光电信息技术科学教育部重点实验室(南开大学; 天津大学); 天津 300071
2.河北工业大学信息工程学院; 天津 300130
Optimized solvent-thermal preparation of NaYF4 :Yb3+,  Er3+  up-conversion nanoparticles for application in solar cells
LIU Yongjuan1;2;  ZHANG Xiaodan1;  WANG Dongfeng1;  ZHANG Cunshan2;  ZHAO Ying1
1.Institute of Photo-electronics Thin Film Devices and Technique of Nankai University; Key Laboratory of Photo-electronics Thin Film Devices and Technique of Tianjin; Key Laboratory of Photo-electronic Information Science and Technology (Nankai University; Tianjin University); Ministry of Education; Tianjin 300071
2.College of Information Engineering; Hebei University of Technology; Tianjin 300130
引用本文:

刘永娟 张晓丹 王东丰 张存善 赵颖. 溶剂热法制备太阳电池用NaYF4:Yb3+,  Er3+纳米上转换材料[J]. 材料研究学报, 2009, 23(2): 123-126.
, . Optimized solvent-thermal preparation of NaYF4 :Yb3+,  Er3+  up-conversion nanoparticles for application in solar cells[J]. Chin J Mater Res, 2009, 23(2): 123-126.

全文: PDF(789 KB)  
摘要: 

用溶剂热法合成Yb3+、Er3+共掺的NaYF4 纳米上转换材料, 研究了去离子水、乙醇两种反应溶剂对材料性能的影响. 用X射线衍射光谱、扫描电镜和荧光光谱等测试手段对材料性能进行了对比分析. 结果表明: 以乙醇为溶剂并加入一定比例的EDTA, 所制备的上转换材料能发射较强的、可被太阳电池吸收的可见光.

关键词 无机非金属材料溶剂去离子水乙醇乙二胺四乙酸二钠(EDTA)上转换    
Abstract

Nanoparticles of Yb3+,  Er3+-codoped sodium yttrium fluoride were prepared by solventthermal method. The properties of the prepared materials were characterized. The up-conversion luminescent properties of the NaYF4 : Yb3+, Er3+ nanoparticles were investigated. The effect of deionized water and ethanol as reaction medium on the performance of the up-conversion materials was studied. The results showed that the up-conversion nanoparticles had relatively high up-conversion effect when ethanol was used as reaction medium and simultaneously ethylenediaminetetraacetic acid (EDTA) was also added. The up-conversion phosphors emit visible light which could be well utilized by solar cells.

Key wordsinorganic non-metallic materials    solvent    deionized water    ethanol    ethylenediaminetetraacetic acid (EDTA)    up-conversion
收稿日期: 2008-06-25     
ZTFLH: 

TB321

 
基金资助:

国家高技术研究发展计划2007AA05Z436、国家重点基础研究发展计划2006CB202602和2006CB202603、国家自然科学基金60506003、南开大学博士启动基金J02031、科技部国际合作重点2006DFA62390和教育部新世纪人才计划NCET--05--0227资助项目.

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