Please wait a minute...
材料研究学报  2008, Vol. 22 Issue (5): 539-544    
  论文 本期目录 | 过刊浏览 |
微波合成固体氧化物燃料电池阴极材料La1-xSrxMnO3
翟秀静;符岩;韩庆;储刚
东北大学材料冶金学院
Microwave technology synthesized the cathode materials of solid oxide fuel cell La1-xSrxMnO3
东北大学
引用本文:

翟秀静; 符岩; 韩庆; 储刚 . 微波合成固体氧化物燃料电池阴极材料La1-xSrxMnO3[J]. 材料研究学报, 2008, 22(5): 539-544.

全文: PDF(737 KB)  
摘要: 采用微波无机合成技术制备固体氧化物燃料电池(SOFC)阴极材料La1-xSrxMnO3,表征了结构和性能, 研究了微波功率、反应时间和原料粒度等微波合成条件对其性能的影响,以及合成La1-xSrxMnO3的反应机理.
关键词 无机非金属材料微波合成    
Abstract:The cathode materials of solid oxide fuel cell (SOFC) La1-xSrxMnO3 powder have been synthesized by microwave method using inorganic precursors. The mechanism and conditions of reaction for the formation of La1-xSrxMnO3 have been studied. The influences of microwave synthesis conditions, such as, microwave power, reaction time and reactant size are examined. And the structure of the sample is determined by XRD, SEM and TGA-DTA. Furthermore, the conductivity of sample is investigated by four probe method.
Key words
收稿日期: 2007-10-15     
ZTFLH:  TB321  
1 QIN Bo,MA Wenhui,YANG Bin,LIU Dachun, DAI Yongnian,Synthesis and characterization of La_(1-x)Sr_xFe_(1-y)MnyO_(3-δ) for SOFC cathode materials, Acta Scientiarum Naturalium Universitatis Sunyatseni, 46(S1),141(2007)
2 LI Zhaohui,LI Guangyuo,GAO Dongmei,LIAN Jianshe, Synthesis of La_(0.6)Sr_(0.4)Fe_(0.8)Co_(0.2)O_3 and its performance as ITSOFC cathodes,Chinese Journal of Applied Chem- istry,24(1),25(2007)(in Chinese)
3 SUN Liping,HUO Lihua,ZHAO Hui,Christophe Pijo- lat,Synthesis and performance of Sm_(2-x)Ce_xCuO_4 cath- ode materials for IT-SOFC,Chinese Journal of Inorganic Chemistry,23(9),1545(2007)(in Chinese)
4 BAO Xia,CHEN Yonghong,LU Xiaoyong,LIU Xingqin, MENG Guangyao,Preparation and characterization of Ba_(0.4)Sr_(0.6)Co_(1-x)Fe_xO_(3-δ) cathode materials,Chinese Journal of Inorganic Chemistry,24(3),363(2008) (in Chi- nese)
5 D.Waldbillig,A.Wood,D.G.IVEY,Electrochemical and microstructural characterization of the redox tolerance of solid oxide fuel cell anodes,Journal of Power Sources,145, 206(2005)
6 LU Yixin,SCHAEFER Laura,LI Peiwen,Numerical study of a fiat-tube high power density solid oxide fuel ceil-heat/mass transfer and fluid flow,Journal of Power Sources,140,331(2005)
7 D.Stver,H.P.Buchkremer,S.Uhlenbruck,Processing and properties of the ceramic conductive multilayer device solid oxide fuel cell (SOFC),Ceramics International,30, 1107(2004)
8 A Mai,V.A.C.Haanappel,S.Uhlenbruck,Ferrite-based perovskites as cathode materials for anode supported solid oxide fuel cells-I.Variation of composition,Solid State Ionics,176,1341(2005)
9 L.W.Tai,M.M.Nasrallah,H.U.Anderson,Structure and electrical properties of La_(1-x)Sr_xCo_(1-y)Fe_yO_3,Solid State Ionics,76,259(1995)
10 JIANG Jinguo,CUI Chong,Research in the electrical conduction mechanism of La_(1-x)Sr_xCo_(0.2)Fe_(0.8)O_3 cath- ode materials,Materials Science & Technology,15(4), 575(2007)
11 YAN Hongwei,HUANG Xuejie,CHEN Liquan,Mi- crowave synthesis of LiMn204 cathode material,Journal of Power Source,81,647(1999)
12 YANG Shuting,ZHANG Yanfeng,LI Qingzhang, LiM_xMn_2O_4(M=La,Nd,Y) prepared by microwave- polymer network process for rechargeable lithium batter- ies,Journal of Functional Material,32(4),399(2001)(in Chinese)
13 Aobert Armstrong,Alastair D.Robertson,Robert Gitzen- danner,Peter G.Bruce,The layered intercalation com- pounds Li(Mn_(1-y)Co_y)O_2:Positive electrode materials for lithium-ion batteries,Journal of Solid Static Chemistry, 145,549(1999)
14 LIU Hanxing,LIU Zhijian,Ouyang Shiweng,Study on the microstructure and properties of SrTiO_3 synthesized by microwave heating,Acta Physico-Chimica Sinica,14(7), 624(1998)(in Chinese)
15 J.H.KUO,H.Uanderson,Oxidation-reduction behavior of undoped and Sr-doped LaMnO_3:defect structure,Solid State Chemistry,(87),55(1990)
16 Shoji Otoshi,Hirokazu Sasaki,Hisao Ohnishi,Minoru Hase,Kimio Ishimaru,Masamichi Ippommatsu,Changes in the Phases and electrical conduction properties of (La_(1-x)Sr_x)_(1-y)MnO_3,J.Electrochem.Soc.,138(5), 1519(1991)
17 J A.M Van Roosmalen,J P Huijsma,E H P Cord- funke,Sinter behavior and electrical conductivity of (La, Sr)MnO_3 as a function of Sr-content,Proc.of the 2nd Symp.on SOFC,507(1997)
18 M.Kertesz,I.Riess,D.Tannhauser,R.Longpqpe, F.J.Rohr,Structure and electrical conductivity of La0.84Sr0.16MnO3,Solid State Chemistry,42,125(1982)
19 A.Hammouche,E.Siebert,A.Hammou,M.Kleitz,Electro- catalytic properties and nonstoichiometry of the high tem- perature air electrode La_(1-x)Sr_xMnO_3,J.Electrochem. Soc.,138(5),1212(1991)
20 LIU Xiaomei,LI Kun,LIU Jiang,Production and proper- ties of cathode materials La_(1-x)Sr_xMnO_3,Journal of Jilin University (Natural Science),4,44(1999)(in Chinese)
[1] 宋莉芳, 闫佳豪, 张佃康, 薛程, 夏慧芸, 牛艳辉. 碱金属掺杂MIL125CO2 吸附性能[J]. 材料研究学报, 2023, 37(9): 649-654.
[2] 邵鸿媚, 崔勇, 徐文迪, 张伟, 申晓毅, 翟玉春. 空心球形AlOOH的无模板水热制备和吸附性能[J]. 材料研究学报, 2023, 37(9): 675-684.
[3] 任富彦, 欧阳二明. g-C3N4 改性Bi2O3 对盐酸四环素的光催化降解[J]. 材料研究学报, 2023, 37(8): 633-640.
[4] 刘明珠, 樊娆, 张萧宇, 马泽元, 梁城洋, 曹颖, 耿仕通, 李玲. SnO2 作散射层的光阳极膜厚对量子点染料敏化太阳能电池光电性能的影响[J]. 材料研究学报, 2023, 37(7): 554-560.
[5] 李延伟, 罗康, 姚金环. Ni(OH)2 负极材料的十二烷基硫酸钠辅助制备及其储锂性能[J]. 材料研究学报, 2023, 37(6): 453-462.
[6] 余谟鑫, 张书海, 朱博文, 张晨, 王晓婷, 鲍佳敏, 邬翔. N掺杂生物炭的制备及其对Co2+ 的吸附性能[J]. 材料研究学报, 2023, 37(4): 291-300.
[7] 朱明星, 戴中华. SrSc0.5Nb0.5O3 改性BNT基无铅陶瓷的储能特性研究[J]. 材料研究学报, 2023, 37(3): 228-234.
[8] 刘志华, 岳远超, 丘一帆, 卜湘, 阳涛. g-C3N4/Ag/BiOBr复合材料的制备及其光催化还原硝酸盐氮[J]. 材料研究学报, 2023, 37(10): 781-790.
[9] 周毅, 涂强, 米忠华. 制备方法对磷酸盐微晶玻璃结构和性能的影响[J]. 材料研究学报, 2023, 37(10): 739-746.
[10] 谢锋, 郭建峰, 王海涛, 常娜. ZnO/CdS/Ag复合光催化剂的制备及其催化和抗菌性能[J]. 材料研究学报, 2023, 37(1): 10-20.
[11] 余超, 邢广超, 吴郑敏, 董博, 丁军, 邸敬慧, 祝洪喜, 邓承继. 亚微米Al2O3 对重结晶碳化硅的作用机制[J]. 材料研究学报, 2022, 36(9): 679-686.
[12] 方向明, 任帅, 容萍, 刘烁, 高世勇. 自供能Ag/SnSe纳米管红外探测器的制备和性能研究[J]. 材料研究学报, 2022, 36(8): 591-596.
[13] 李福禄, 韩春淼, 高嘉望, 蒋健, 许卉, 李冰. 氧化石墨烯的变温发光[J]. 材料研究学报, 2022, 36(8): 597-601.
[14] 朱晓东, 夏杨雯, 喻强, 杨代雄, 何莉莉, 冯威. Cu掺杂金红石型TiO2 的制备及其光催化性能[J]. 材料研究学报, 2022, 36(8): 635-640.
[15] 熊庭辉, 蔡文汉, 苗雨, 陈晨龙. ZnO纳米棒阵列和薄膜的同步外延生长及其光电化学性能[J]. 材料研究学报, 2022, 36(7): 481-488.