Please wait a minute...
材料研究学报  2008, Vol. 22 Issue (2): 175-181    
  论文 本期目录 | 过刊浏览 |
晶种对低温烧结BaO--Al2O3-SiO2系微晶玻璃析晶的影响
芦玉峰; 堵永国; 肖加余; 张为军; 郑晓慧; 郭良
国防科技大学航天与材料工程学院
引用本文:

芦玉峰; 堵永国; 肖加余; 张为军; 郑晓慧; 郭良 . 晶种对低温烧结BaO--Al2O3-SiO2系微晶玻璃析晶的影响[J]. 材料研究学报, 2008, 22(2): 175-181.

全文: PDF(1089 KB)  
摘要: 用烧结法制备了化学计量比和高Ba含量的两组BaO--Al2O3-SiO2BAS系微晶玻璃, 研究了晶种对低温烧结BaO--Al2O3-SiO2系微晶玻璃析晶的影响. 结果表明, 玻璃的软化温度随着晶种含量的增加而提高. 在两组玻璃粉中添加晶种有助于降低析晶活化能, 促进六方钡长石和单斜钡长石的析出; 晶种含量为1%时活化能最小, 成分为化学计量比的玻璃析晶峰值温度也最低. 在850℃保温时间2 h, 添加1%晶种的BAS系微晶玻璃全部转变为单斜钡长石. 在两组成分的BAS系微晶玻璃中, 六方钡长石的析出表现为整体析晶. 不加晶种时, 单斜钡长石通过六方钡长石单斜钡长石的晶型转变析出, 表现为整体析晶;
关键词 无机非金属材料微晶玻璃钡长石    
Key words
收稿日期: 2007-09-10     
1 N.J.Clayden,S.Esposito,C.Ferone,M.Pansini,Substitu- tion clustering in a non-stoichiometric celsian synthesized by the thermal transformation of barium exchanged zeo- lite X,J.Solid State Chem.,179(7),1957(2006)
2 N.P.Bansal,E.A.Gamble,Crystallization kinetics of a solid oxide fuel cell seal glass by differential thermal analy- sis,J.Power Sources,147(1-2),107(2005)
3 K.N.Lee,D.S.Fox,N.P.Bansal,Rare earth silicate environ- mental barrier coatings for SiC/SiC composites and SiaN4 ceramics,J.Eur.Ceram.Soc.,25(10),1705(2005)
4 F.Ye,L.M.Liu,J.X.Zhang,M.Iwasa,C.L.Su,Synthesis of silicon nitride-barium aluminosilicate self-reinforced ceramic composite by a two-step pressureless sintering, Compos.Sci.Technol.,65(14),2233(2005)
5 S.B.Sohn,S.Y.Choi,G.H.Kim,H.S.Song,G.D.Kim,Suit- able glass-ceramic sealant for planar solid-oxide fuel cells, J.Am.Ceram.Soc.,87(2),254(2004)
6 L.Yoshihiko,Multilayered Low Temperature Cofired Ce- ramics(LTCC) Technology,Boston,Springer,2005,p.13
7 H.L.Lin,R.K.Chiang,W.T.Li,Low-temperature synthe- sis of pure BaAl_2Si_2O_8 glass-ceramic powder by citrate process,J.Non-Cryst.Solids,351(37-39),3044(2005)
8 LU Yufeng,DU Yongguo,XIAO Jiayu,ZHNAG Wei- jun,HU Junsui,TANG Zhenlan,WU Jianfeng,WANG Yueran,Research progress and applications of BaO- A1203-SIO2 glass-ceramics,J.Mat.Sci.Eng.(in Chi- nese),25(4),634(2007) (芦玉峰,堵永国,肖加余,张为军,胡君遂,唐珍兰,吴剑锋,王跃然,BaO-Al_2O_3-SiO_2系微晶玻璃的研究进展和应用,材料科学与工程学报,25(4),634(2007)
9 N.P.Bansal,Ceisian formation in fiber-reinforced barium aluminosilicate glass-ceramic matrix composites,Mater. Sci.Eng.,A,342(1-2),23(2003)
10 F.Ye,Y.Zhou,T.C.Lei,J.M.Yang,L.T.Zhang,Mi- crostructure and mechanical properties of barium alumi- nosilicate glass-ceramic matrix composites reinforced with SiC whiskers,J.Mater.Sci.,36(10),2575(2001)
11 YANG Jueming,ZHOU Wancheng,ZHANG Litong,Ef- fect of ceisian seeds on the phase transformation of BAS glass-ceramic,J.Xi' an Inst.Techno.(in Chinese),18(1), 40(1998) (杨觉明,周万城,张立同,单斜钡长石作为晶种对BAS玻璃陶瓷的影响,西安工业学院学报,18(1),40(1998))
12 YANG Jueming,ZHANG Litong,ZHOU Wancheng,Crys- tallization and properties of BAS glass-ceramics,Chin.J. Mater.Research (in Chinese),12(6) ,580(1998) (杨觉明,张立同,周万城,BAS玻璃陶瓷的晶化行为与性能,材料研究学报,12(6),580(1998))
13 S.Chen,F.Ye,Y.Zhou,Low temperature hot-pressed BAS matrix composites reinforced with in situ grown Si3N4 whiskers,Ceram.Int.,28(1),51(2002)
14 F.Ye,J.C.Gu,Y.Zhou,M.Iwasa,Synthesis of BaAl_2Si_2O_8 glaes-ceramic by a sol-gel method and the fabrication of SiC_(p1)/BaAl_2Si_2O_8 composites,J.Eur.Ceram.Soc., 23(13),2203(2003)
15 C.Liu,S.Komarneni,R.Roy,Crystallization and seeding effect in BaAl_2Si_2O_8 gels,J.Am.Ceram.Soc.,78(9), 2521(1995)
16 W.E.Lee,M.Chen,P.F.James,Crystallization of ceisian (BaAl_2Si_2O_8)glad,J.Am.Ceram.Soc.,78(8), 2180(1995)
17 J.C.Debsikdar,O.S.Sowemimo,Effect of zirconia addi- tion on crystallinity,hardness,and microstructure of gel- derived barium aluminosilicate,BaAl_2Si_2O_8,J.Mater. Sci.,27(19),5320(1992)
18 K.T.Lee,P.B.Aswath,Role of mineralizers on the hexac- elsian to celsian transformation in the barium aluminosil- icate (BAS) system,Mater. Sci. Eng.,A,352(1-2), 1(2003)
19 YANG Jueming,ZHANG Litong,ZHOU Wancheng,Ef- fect of Li20 on phase transition and properties of BAS (BaO-Al_2O_3-SiO_2 system) glass-ceramics,J.Northwest- ern Polytech.Univ.,14(2),194(1996) (杨觉明,张立同,周万城,添加LiO_2对BAS玻璃陶瓷相变和性能的影响,西北工业大学学报,14(2),194(1996))
20 C.Ferone,S.Esposito,G.Dell'agli,M.Pansini,Role of Li in the low temperature synthesis of monoclinic celsian from (Ba,Li)-exchanged zeolite-A precursor,Solid State Sci., 7(11),1406(2005)
21 J.A.Griggs,K.J.Anusavice,J.J.Mecholsky,Jr.,Devitri- fication and microstructural coarsening of a fluoride- containing barium aluminosilicate glass,J.Mater.Sci., 37(10),2017(2002)
22 K.T.Lee,Studies of Hexacelsian and Celsian Barium Alu- minosilicates,Arlington,The University of Taxas(1998)
23 J.C.Gu,F.Ye,Y.Zhou,T.C.Lei,Microstructure and me- chanical properties of SiC platelet reinforced BaO-Al_2O_3- 2SiO_2(BAS) composites,Ceram.Int.,26(8),855(2000)
24 WANG Chengyu,TAO Ying,Design and Adjustment for Glass Composition,(Beijing,Chemical Industry Press, 2006) (in Chinese) p.127-136 (王承遇,陶瑛,玻璃成分设计与调整,(北京,化学工业出版社,2006)p,127-136)
25 ZHAO Yanzhao,YIN Hairong,Glass Technology,(Beijing, Chemical Industry Press,2006) (in Chinese) p.24 (赵彦钊,殷海荣,玻璃工艺学,(北京,化学工业出版社,2006) p.24)
26 LU Yufeng,DU Yongguo,XIAO Jiayu,ZHANG Chuanyu, ZHNAG Weijun,YIN Ruiming,Quantitative analysis of crystal-phases in glass-ceramics by X-ray diffraction,J. Chin.Ceram.Soc.(in Chinese),33(12),1488(2005) (芦玉峰,堵永国,肖加余,张传禹,张为军,银锐明,XRD法测定微晶玻璃晶相含量,硅酸盐学报,33(12),1488(2005))
27 HU Rongzu,SHI Qizhen,Thermal Analysis Kinetics, (Beijing,Science Press,2001) (in Chinese) p.65 (胡荣祖,史启祯,热分析动力学,(北京,科学出版社,2001) p.65)
28 J.S.M.Corral,A.G.Verduch,The solid solution of silica in celsian and its polymorphic transition kinetics,Trans.J. Br.Ceram.Soc.,77(2),40(1978)A
[1] 宋莉芳, 闫佳豪, 张佃康, 薛程, 夏慧芸, 牛艳辉. 碱金属掺杂MIL125CO2 吸附性能[J]. 材料研究学报, 2023, 37(9): 649-654.
[2] 邵鸿媚, 崔勇, 徐文迪, 张伟, 申晓毅, 翟玉春. 空心球形AlOOH的无模板水热制备和吸附性能[J]. 材料研究学报, 2023, 37(9): 675-684.
[3] 任富彦, 欧阳二明. g-C3N4 改性Bi2O3 对盐酸四环素的光催化降解[J]. 材料研究学报, 2023, 37(8): 633-640.
[4] 刘明珠, 樊娆, 张萧宇, 马泽元, 梁城洋, 曹颖, 耿仕通, 李玲. SnO2 作散射层的光阳极膜厚对量子点染料敏化太阳能电池光电性能的影响[J]. 材料研究学报, 2023, 37(7): 554-560.
[5] 李延伟, 罗康, 姚金环. Ni(OH)2 负极材料的十二烷基硫酸钠辅助制备及其储锂性能[J]. 材料研究学报, 2023, 37(6): 453-462.
[6] 余谟鑫, 张书海, 朱博文, 张晨, 王晓婷, 鲍佳敏, 邬翔. N掺杂生物炭的制备及其对Co2+ 的吸附性能[J]. 材料研究学报, 2023, 37(4): 291-300.
[7] 朱明星, 戴中华. SrSc0.5Nb0.5O3 改性BNT基无铅陶瓷的储能特性研究[J]. 材料研究学报, 2023, 37(3): 228-234.
[8] 刘志华, 岳远超, 丘一帆, 卜湘, 阳涛. g-C3N4/Ag/BiOBr复合材料的制备及其光催化还原硝酸盐氮[J]. 材料研究学报, 2023, 37(10): 781-790.
[9] 周毅, 涂强, 米忠华. 制备方法对磷酸盐微晶玻璃结构和性能的影响[J]. 材料研究学报, 2023, 37(10): 739-746.
[10] 谢锋, 郭建峰, 王海涛, 常娜. ZnO/CdS/Ag复合光催化剂的制备及其催化和抗菌性能[J]. 材料研究学报, 2023, 37(1): 10-20.
[11] 余超, 邢广超, 吴郑敏, 董博, 丁军, 邸敬慧, 祝洪喜, 邓承继. 亚微米Al2O3 对重结晶碳化硅的作用机制[J]. 材料研究学报, 2022, 36(9): 679-686.
[12] 方向明, 任帅, 容萍, 刘烁, 高世勇. 自供能Ag/SnSe纳米管红外探测器的制备和性能研究[J]. 材料研究学报, 2022, 36(8): 591-596.
[13] 李福禄, 韩春淼, 高嘉望, 蒋健, 许卉, 李冰. 氧化石墨烯的变温发光[J]. 材料研究学报, 2022, 36(8): 597-601.
[14] 朱晓东, 夏杨雯, 喻强, 杨代雄, 何莉莉, 冯威. Cu掺杂金红石型TiO2 的制备及其光催化性能[J]. 材料研究学报, 2022, 36(8): 635-640.
[15] 熊庭辉, 蔡文汉, 苗雨, 陈晨龙. ZnO纳米棒阵列和薄膜的同步外延生长及其光电化学性能[J]. 材料研究学报, 2022, 36(7): 481-488.