<strong>CsPbI<sub>2</sub>Br</strong>无机钙钛矿太阳能电池稳定性的研究进展

doi:10.11901/1005.3093.2020.158

材料研究学报

2020, Vol. 34

Issue (11): 811-821 DOI: 10.11901/1005.3093.2020.158

研究论文

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CsPbI₂Br无机钙钛矿太阳能电池稳定性的研究进展

吴巧凤¹, 张富¹, 于月¹, 张萌¹, 于华¹(

), 樊栓狮²(

)

^1.西南石油大学光伏产业技术研究院成都 610500
^2.华南理工大学传热强化与过程节能教育部重点实验室广州 510640

Research Progress on Stability of CsPbI₂Br Inorganic Perovskite Solar Cells

WU Qiaofeng¹, ZHANG Fu¹, YU Yue¹, ZHANG Meng¹, YU Hua¹(

), FAN Shuanshi²(

)

^1.Institute of Photovoltaics, Southwest Petroleum University, Chengdu 610500, China
^2.Key Laboratory of Heat Transfer Enhancement and Energy Conservation of Education Ministry, South China University of Technology, Guangzhou 510640, China

引用本文:

吴巧凤, 张富, 于月, 张萌, 于华, 樊栓狮. CsPbI₂Br无机钙钛矿太阳能电池稳定性的研究进展[J]. 材料研究学报, 2020, 34(11): 811-821.
Qiaofeng WU, Fu ZHANG, Yue YU, Meng ZHANG, Hua YU, Shuanshi FAN. Research Progress on Stability of CsPbI₂Br Inorganic Perovskite Solar Cells[J]. Chinese Journal of Materials Research, 2020, 34(11): 811-821.

全文: PDF(8877 KB) HTML

摘要:

有机-无机杂化钙钛矿材料中易挥发的有机成分(MA⁺，FA⁺)用高耐热性无机金属铯离子(Cs⁺)取代，用其制备的太阳能电池具有优异的热稳定性。自2016年以来，以CsPbI₂Br材料作为光活性层的无机钙钛矿太阳能电池(IPSCs)的光电转换效率(PCE)从9.84%提高到18.06%，但是IPSCs的稳定性问题仍然制约其商业化。本文总结和分析了影响CsPbI₂Br IPSCs稳定性的因素，从制备工艺、离子掺杂、界面优化等方面评述了近年来IPSCs稳定性的研究进展，并展望了CsPbI₂Br IPSCs的研究趋势和发展方向。

关键词 ：评述, 无机非金属材料, 无机钙钛矿太阳能电池, 稳定性, CsPbI₂Br

Abstract：

Inorganic perovskite materials have excellent thermal stability due to that the volatile organic components (MA⁺, FA⁺) in organic-inorganic hybrid perovskite materials are completely replaced by cesium ions (Cs⁺). Inorganic perovskite solar cells (IPSCs) are favored by researchers internationally due to their excellent thermal stability. Since the CsPbI₂Br was used as the photoactive layer for the first time in 2016, its photoelectric conversion efficiency (PCE) increased from 9.84% to 18.06%, but the device stability of IPSCs still restricts its commercial application progress. This paper reviews the unstable factors of CsPbI₂Br IPSCs and summarizes the recent research progress on the stability of CsPbI₂Br IPSCs from three aspects: preparation methods, ion doping, and interface optimization. Finally, an outlook on the research challenges and prospects of CsPbI₂Br based IPSCs was proposed and discussed.

Key words： review inorganic nonmetallic materials inorganic perovskite solar cells stability CsPbI₂Br

收稿日期: 2020-05-11

ZTFLH:

TM 914.4

基金资助:西南石油大学“双一流”建设专项基金(X151528)

作者简介: 吴巧凤，女，1997年生，硕士生

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图1 CsPbI2Br钙钛矿太阳能电池能量转换效率的进展

图2 水诱导无机钙钛矿相变的机理

图3 钙钛矿前驱体常用溶剂的分子结构及性质[47]、DMSO引入钙钛矿薄膜的演变示意图[48]、100~350℃温度范围内退火2 min后的CsPbI2Br薄膜的SEM图像[57]以及CsPbI2Br钙钛矿通过GTA或GTA-ATS工艺结晶的示意图[58]

图4 典型三维钙钛矿晶体结构示意图[65]、无掺杂CsPbI2Br(A)与CsPb0.95Eu0.05I2Br钙钛矿薄膜(B)的SEM图[78]以及器件的结构和Mn2+掺杂于间隙和取代Pb2+的两种模式示意图[80]

图5 插入MoO3界面层的平面型CsPbI2Br无机钙钛矿太阳能电池的结构原理图[89]、沉积不同厚度碲化铋纳米片的钙钛矿薄膜SEM图像以及SIM法合成2D/3D钙钛矿的工艺流程[26]

1	Chen Z, Dong Q, Liu Y, et al. Thin single crystal perovskite solar cells to harvest below-bandgap light absorption [J]. Nat. Commun., 2017, 8(1): 1890
2	Wei H, Fang Y, Mulligan P, et al. Sensitive X-ray detectors made of methylammonium lead tribromide perovskite single crystals [J]. Nat. Photonics, 2016, 10(5): 333
3	Stranks S D, Eperon G E, Grancini G, et al. Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber [J]. Science, 2013, 342(6156): 341
4	Wang Z K, Li M, Yang Y G, et al. High efficiency Pb-In binary metal perovskite solar cells [J]. Adv. Mater., 2016, 28(31): 6695
5	Kojima A, Teshima K, Shirai Y, et al. Organometal halide perovs-kites as visible-light sensitizers for photovoltaic cells [J]. J. Am. Chem. Soc., 2009, 131(17): 6050
6	Chen Y, Tan S, Li N, et al. Self-elimination of intrinsic defects improves the low-temperature performance of perovskite photovoltaics [J]. Joule, 2020. DOI:10.1016/j.joule.2020.07.006
7	Tai Q, Tang K C, Yan F. Recent progress of inorganic perovskite solar cells [J]. Energy Environ. Sci., 2019, 12(8): 2375
8	Liang J, Wang C, Wang Y, et al. All-inorganic perovskite solar cells [J]. J. Am. Chem. Soc., 2016, 138(49): 15829
9	Yang Z, Babu B H, Wu S, et al. Review on practical interface engineering of perovskite solar cells: From efficiency to stability [J]. Solar Rrl, DOI:10.1002/solr.201900257
10	Yang J, Siempelkamp B D, Liu D, et al. Investigation of CH₃NH₃-PbI₃ degradation rates and mechanisms in controlled humidity environments using in situ techniques [J]. ACS Nano, 2015, 9(2): 1955
11	Hoffman J B, Schleper A L, Kamat P V. Transformation of sintered CsPbBr₃ nanocrystals to cubic CsPbI₃ and gradient CsPbBr_xI_3-_xthrough halide exchange [J]. J. Am. Chem. Soc., 2016, 138(27): 8603
12	Sun J K, Huang S, Liu X Z, et al. Polar solvent induced lattice distortion of cubic CsPbI₃ nanocubes and hierarchical self-assembly into orthorhombic single-crystalline nanowires [J]. J. Am. Chem. Soc., 2018, 140(37): 11705
13	Li B, Zhang Y, Fu L, et al. Surface passivation engineering strategy to fully-inorganic cubic CsPbI₃ perovskites for high-performance solar cells [J]. Nat. Commun., 2018, 9: 1
14	Yuan H, Zhao Y, Duan J, et al. All-inorganic CsPbBr₃ perovskite solar cell with 10.26% efficiency by spectra engineering [J]. J. Mater. Chem. A, 2018, 6(47): 24324
15	Kang J, Wang L W. High defect tolerance in lead halide perovskite CsPbBr₃ [J]. J. Phys. Chem. Lett., 2017, 8(2): 489
16	Stoumpos C C, Malliakas C D, Peters J A, et al. Crystal growth of the perovskite semiconductor CsPbBr₃: A new material for high-energy radiation detection [J]. Cryst. Growth Des., 2013, 13(7): 2722
17	Chang S, Bai Z, Zhong H. In situ fabricated perovskite nanocrystals: A revolution in optical materials [J]. Adv. Opt. Mater., 2018, 6(18): 1800380
18	Kulbak M, Cahen D, Hodes G. How important is the organic part of lead halide perovskite photovoltaic cells? Efficient CsPbBr₃ cells [J]. J. Phys. Chem. Lett., 2015, 6(13): 2452
19	Sutton R J, Eperon G E, Miranda L, et al. Bandgap-tunable cesium lead halide perovskites with high thermal stability for efficient solar cells [J]. Adv. Energy Mater., 2016, 6(8): 1502458
20	Bai D, Bian H, Jin Z, et al. Temperature-assisted crystallization for inorganic CsPbI₂Br perovskite solar cells to attain high stabilized efficiency 14.81% [J]. Nano Energy, 2018, 52:408
21	Beal R E, Slotcavage D J, Leijtens T, et al. Cesium lead halide perovskites with improved stability for tandem solar cells [J]. J. Phys. Chem. Lett., 2016, 7(5): 746
22	Lin J, Lai M, Dou L, et al. Thermochromic halide perovskite solar cells [J]. Nat. Mater., 2018, 17(3): 261
23	Chen C Y, Lin H Y, Chiang K M, et al. All-vacuum-deposited stoichiometrically balanced inorganic cesium lead halide perovskite solar cells with stabilized efficiency exceeding 11% [J]. Adv. Mater., 2017, 29(12): 201605290
24	Yin G, Zhao H, Jiang H, et al. Precursor engineering for all-inorganic CsPbI₂Br perovskite solar cells with 14.78% efficiency [J]. Adv. Funct. Mater., 2018, 28(39): 1803269
25	Han Y, Zhao H, Duan C, et al. Controlled n-doping in air-stable CsPbI₂Br perovskite solar cells with a record efficiency of 16.79% [J]. Adv. Funct. Mater., 2020, 30(12): 1909972
26	Zheng Y, Yang X, Su R, et al. High-performance CsPbI_xBr_3-x all-inorganic perovskite solar cells with efficiency over 18% via spontaneous interfacial manipulation [J]. Adv. Funct. Mater., 2020, 2000457. DOI: 10.1002/adfm.202000457
27	Prakash J, Singh A, Sathiyan G, et al. Progress in tailoring perovs-kite based solar cells through compositional engineering: Materials properties, photovoltaic performance and critical issues [J]. Mater. Today Energy, 2018, 9:440
28	Ouedraogo N A, Chen Y, Xiao Y Y, et al. Stability of all-inorganic perovskite solar cells [J]. Nano Energy, 2020, 67:104249
29	Mariotti S, Hutter O S, Phillips L J, et al. Stability and performance of CsPbI₂Br thin films and solar cell devices [J]. ACS Appl. Mater. Interfaces, 2018, 10(4): 3750
30	Edoardo M, Jon M A, Filippo D A. Ab initio molecular dynamics simulations of methylammonium lead iodide perovskite degradation by water [J]. Chem. Mater., 2015, 27(13): 4885
31	Yang J, Siempelkamp B D, Liu D, et al. Investigation of CH₃NH₃PbI₃ degradation rates and mechanisms in controlled humidity environments using in situ techniques [J]. ACS Nano, 2015, 9(2): 1955
32	Imler G H, Li X, Xu B, et al. Solid state transformation of the crystalline monohydrate (CH₃NH₃)PbI₃(H₂O) to the (CH₃NH₃)PbI₃ per-ovskite [J]. Chem. Commun. (Camb), 2015, 51(56): 11290
33	Vincent B R, Robertson K N, Cameron T S, et al. Alkylammonium lead halides. Part 1. Isolated PbI₆^4- ions in (CH₃NH₃)₄PbI₆·2H₂O [J]. Canadian Journal of Chemistry, 1987, 65(5): 1042
34	Halder A, Choudhury D, Ghosh S, et al. Exploring thermochromic behavior of hydrated hybrid perovskites in solar cells [J]. J. Phys. Chem. Lett., 2015, 6(16): 3180
35	Eperon G E, Paterno G M, Sutton R J, et al. Inorganic caesium lead iodide perovskite solar cells [J]. J. Mater. Chem. A, 2015, 3(39): 19688
36	Xu L, Yuan S, Zeng H, et al. A comprehensive review of doping in perovskite nanocrystals/quantum dots: Evolution of structure, electronics, optics, and light-emitting diodes [J]. Mater. Today Nano, 2019, 6: 100036
37	Zhou Y, Zhao Y. Chemical stability and instability of inorganic halide perovskites [J]. Energy Environ. Sci., 2019, 12(5): 1495
38	Ju M G, Chen M, Zhou Y, et al. Toward eco-friendly and stable perovskite materials for photovoltaics [J]. Joule, 2018, 2(7): 1231
39	Berhe T A, Su W N, Chen C H, et al. Organometal halide perovs-kite solar cells: Degradation and stability [J]. Energy Environ. Sci., 2016, 9(2): 323
40	Zeng Q, Zhang X, Liu C, et al. Inorganic CsPbI₂Br perovskite solar cells: The progress and perspective [J]. Solar Rrl, 2019, 3(1): 201800239
41	Wang R, Mujahid M, Duan Y, et al. A review of perovskites solar cell stability [J]. Adv. Funct. Mater., 2019, 29(47): 1808843
42	Xue J, Gu Y, Shan Q, et al. Constructing mie-scattering porous interface-fused perovskite films to synergistically boost light harvesting and carrier transport [J]. Angew. Chem., Int. Ed., 2017, 56(19): 5232
43	Roose B, Wang Q, Abate A. The role of charge selective contacts in perovskite solar cell stability [J]. Adv. Energy Mater., 2019, 9(5): 1803140
44	Chang C Y, Chu C Y, Huang Y C, et al. Tuning perovskite morphology by polymer additive for high efficiency solar cell [J]. ACS Appl. Mater. Interfaces, 2015, 7(8): 4955
45	Wakamiya A, Endo M, Sasamori T, et al. Reproducible fabrication of efficient perovskite-based solar cells: X-ray crystallographic studies on the formation of CH₃NH₃PbI₃ layers [J]. Chem. Lett., 2014, 43(5): 711
46	Rong Y, Tang Z, Zhao Y, et al. Solvent engineering towards controlled grain growth in perovskite planar heterojunction solar cells [J]. Nanoscale, 2015, 7(24): 10595
47	Chen J, Xiong Y, Rong Y, et al. Solvent effect on the hole-conductor-free fully printable perovskite solar cells [J]. Nano Energy, 2016, 27:130
48	Zai H, Zhang D, Li L, et al. Low-temperature-processed inorganic perovskite solar cells via solvent engineering with enhanced mass transport [J]. J. Mater. Chem. A, 2018, 6(46): 23602
49	Rong Y, Venkatesan S, Guo R, et al. Critical kinetic control of non-stoichiometric intermediate phase transformation for efficient pero-vskite solar cells [J]. Nanoscale, 2016, 8(26): 12892
50	Shi L, Hao H, Dong J, et al. Solvent engineering for intermediates phase, all-ambient-air-processed in organic-inorganic hybrid pero-vskite solar cells [J]. Nanomaterials, 2019, 9(7): 915
51	Jeon N J, Noh J H, Kim Y C, et al. Solvent engineering for high-performance inorganic-organic hybrid perovskite solar cells [J]. Nat. Mater., 2014, 13(9): 897
52	Yin M, Xie F, Chen H, et al. Annealing-free perovskite films by instant crystallization for efficient solar cells [J]. J. Mater. Chem. A, 2016, 4(22): 8548
53	Yu Y, Yang S, Lei L, et al. Ultrasmooth perovskite film via mixed anti-solvent strategy with improved efficiency [J]. ACS Appl. Mater. Interfaces, 2017, 9(4): 3667
54	Rao H, Ye S, Gu F, et al. Morphology controlling of all-inorganic perovskite at low temperature for efficient rigid and flexible solar cells [J]. Adv. Energy Mater., 2018, 8(23): 1800758
55	Kim M, Kim G H, Oh K S, et al. High-temperature-short-time annealing process for high-performance large-area perovskite solar cells [J]. ACS Nano, 2017, 11(6): 6057
56	Huang L, Hu Z, Xu J, et al. Multi-step slow annealing perovskite films for high performance planar perovskite solar cells [J]. Sol. Energy Mater. Sol. Cells, 2015, 141:377
57	Nam J K, Jung M S, Chai S U, et al. Unveiling the crystal formation of cesium lead mixed-halide perovskites for efficient and stable solar cells [J]. J. Phys. Chem. Lett., 2017, 8(13): 2936
58	Chen W, Chen H, Xu G, et al. Precise control of crystal growth for highly efficient CsPbI₂Br perovskite solar cells [J]. Joule, 2019, 3(1): 191
59	Chen C Y, Lin H Y, Chiang K M, et al. All-vacuum-deposited stoichiometrically balanced inorganic cesium lead halide perovskite solar cells with stabilized efficiency exceeding 11% [J]. Adv. Mater., 2017, 29(12): 2936
60	Kong R, Kim J E, Yeo J S, et al. Optimized organometal halide perovskite planar hybrid solar cells via control of solvent evaporation rate [J]. J. Phys. Chem. C, 2014, 118(46): 26513
61	Hsu H L, Chen C P, Chang J Y, et al. Two-step thermal annealing improves the morphology of spin-coated films for highly efficient perovskite hybrid photovoltaics [J]. Nanoscale, 2014, 6(17): 10281
62	Li M H, Liu S C, Qiu F Z, et al. High-efficiency CsPbI₂Br perovs-kite solar cells with dopant-free poly(3-hexylthiophene) hole transporting layers [J]. Adv. Energy Mater., 2020, 10(21): 2000501
63	Sanchez S, Hua X, Phung N, et al. Flash infrared annealing for antisolvent-free highly efficient perovskite solar cells [J]. Adv. Energy Mater., 2018, 8(12): 1702915
64	Chen Q, Ma T, Wang F, et al. Rapid microwave-annealing process of hybrid perovskites to eliminate miscellaneous phase for high performance photovoltaics [J]. Adv. Sci., DOI:10.1002/advs.202000480
65	Wang P, Wu Y, Cai B, et al. Solution-processable perovskite solar cells toward commercialization: Progress and challenges [J]. Adv. Funct. Mater., 2019, 29(47): 1807661
66	Cheng Z, Lin J. Layered organic-inorganic hybrid perovskites: Structure, optical properties, film preparation, patterning and templating engineering [J]. Crystengcomm, 2010, 12(10): 2646
67	Li C, Soh K C K, Wu P. Formability of ABO₃ perovskites [J]. Journal of Alloys and Compounds, 2004, 372(1): 40
68	Li C, Lu X, Ding W, et al. Formability of ABX₃ (X=F, Cl, Br, I) halide perovskites [J]. Acta Crystallogr. B, 2008, 64(Pt6): 702
69	Green M A, Ho Baillie A, Snaith H J. The emergence of perovskite solar cells [J]. Nat. Photonics, 2014, 8(7): 506
70	Zhang W, Eperon G E, Snaith H J. Metal halide perovskites for energy applications [J]. Nature Energy, 2016, 1(6): 16048
71	Zhou Y, Chen J, Bakr O M, et al. Metal-doped lead halide per-ovskites: Synthesis, properties, and optoelectronic applications [J]. Chem. Mater., 2018, 30(19): 6589
72	Nam J K, Chai S U, Cha W, et al. Potassium incorporation for enhanced performance and stability of fully inorganic cesium lead halide perovskite solar cells [J]. Nano Letters, 2017, 17(3): 2028
73	Kang D H, Park N G. On the current-voltage hysteresis in per-ovskite solar cells: Dependence on perovskite composition and methods to remove hysteresis [J]. Adv. Mater., 2019, 31(34): 1805214
74	Song D H, Jang M H, Lee M H, et al. A discussion on the origin and solutions of hysteresis in perovskite hybrid solar cells [J]. J. Phys. D: Appl. Phys., 2016, 49(47): 473001
75	Patil J V, Mali S S, Hong C K. A-site rubidium cation-incorporated CsPbI₂Br all-inorganic perovskite solar cells exceeding 17% efficiency [J]. Solar RRL, 2020, DOI:10.1002/solr.202000164
76	Yang F, Hirotani D, Kapil G, et al. All-inorganic CsPb_1-xGe_xI₂Br perovskite with enhanced phase stability and photovoltaic performance [J]. Angew. Chem., Int. Ed., 2018, 57(39): 12745
77	Guo Z, Zhao S, Liu A, et al. Niobium incorporation into CsPbI₂Br for stable and efficient all-inorganic perovskite solar cells [J]. ACS Appl. Mater. Interfaces, 2019, 11(22): 19994
78	Xiang W, Wang Z, Kubicki D J, et al. Europium-doped CsPbI₂Br for stable and highly efficient inorganic perovskite solar cells [J]. Joule, 2019, 3(1): 205
79	Liu C, Li W, Li H, et al. Structurally reconstructed CsPbI₂Br perovskite for highly stable and square-centimeter all-inorganic perovskite solar cells [J]. Adv. Energy Mater., 2019, 9(7): 205
80	Bai D, Zhang J, Jin Z, et al. Interstitial Mn²⁺-driven high-aspect-ratio grain growth for low-trap-density microcrystalline films for record efficiency CsPbI₂Br solar cells [J]. ACS Energy Lett., 2018, 3(4): 970
81	Wang K L, Wang R, Wang Z K, et al. Tailored phase transformation of CsPbI₂Br films by copper(II) bromide for high-performance all-inorganic perovskite solar cells [J]. Nano Lett., 2019, 19(8): 5176
82	Sun H, Zhang J, Gan X, et al. Pb-reduced CsPb_0.9Zn_0.1I₂Br thin films for efficient perovskite solar cells [J]. Adv. Energy Mater., 2019, 9(25): 1900896
83	Wang T, Abbasi S, Wang X, et al. Hierarchy of interfacial passivation in inverted perovskite solar cells [J]. Chem. Commun., 2019, 55(99): 14996
84	Yang S, Chen S, Mosconi E, et al. Stabilizing halide perovskite surfaces for solar cell operation with wide-bandgap lead oxysalts [J]. Science, 2019, 365(6452): 473
85	Liu R, Zheng Z, Spurgeon J, et al. Enhanced photoelectrochemical water-splitting performance of semiconductors by surface passivation layers [J]. Energy Environ. Sci., 2014, 7(8): 2504
86	Mahmud M A, The D, Yin Y, et al. Double-sided surface passivation of 3D perovskite film for high-efficiency mixed-dimensional perovskite solar cells [J]. Adv. Funct. Mater., 2019, 30(7): 1907962
87	Wang T, Cheng Z, Zhou Y, et al. Highly efficient and stable perovskite solar cells via bilateral passivation layers [J]. J.Mater. Chem. A, 2019, 7(38): 21730
88	Jiang Q, Zhao Y, Zhang X, et al. Surface passivation of perovskite film for efficient solar cells [J]. Nat. Photonics, 2019, 13(7): 460
89	Zhou L, Guo X, Lin Z, et al. Interface engineering of low temperature processed all-inorganic CsPbI₂Br perovskite solar cells toward pce exceeding 14% [J]. Nano Energy, 2019, 60: 583
90	Fu L, Nie Y, Li B, et al. Bismuth telluride interlayer for all-inorganic perovskite solar cells with enhanced efficiency and stability [J]. Solar Rrl, 2019, 3(12): 1900233
91	Zhao H, Yang S, Han Y, et al. A high mobility conjugated polymer enables air and thermally stable CsPbI₂Br perovskite solar cells with an efficiency exceeding 15% [J]. Adv. Mater. Technol., 2019, 4(9): 1900311
92	Chen S, Zhang S, Zheng Q. A facile surface passivation method for efficient inorganic CsPbI₂Br perovskite solar cells with efficiencies over 15% [J]. Sci. China Mater., 2020, 63(5): 719
93	Liu X M, Li Y H, Wang X T, et al. Organic ammonium salt surface treatment stabilizing all-inorganic CsPbI₂Br perovskite [J]. Acta Physica Sinica, 2019, 68(15): 158805
93	刘晓敏, 李亦回, 王兴涛等. 有机铵盐表面稳定化CsPbI₂Br全无机钙钛矿 [J]. 物理学报, 2019, 68(15): 158805
94	Liu Y H, Akin S, Pan L F, et al. Ultrahydrophobic 3D/2D fluoroarene bilayer-based water-resistant perovskite solar cells with efficiencies exceeding 22% [J]. Sci. Adv., 2019, 5(6): eaaw2543
95	Li J, Yu Q, He Y, et al. Cs₂PbI₂Cl₂, All-inorganic two-dimensional ruddlesden-popper mixed halide perovskite with optoelectronic response [J]. J. Am. Chem. Soc., 2018, 140(35): 11085

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