双连续Si<sub>3</sub>N<sub>4</sub>/1Cr18Ni9Ti复合材料的制备和冲蚀性能

doi:10.11901/1005.3093.2018.296

材料研究学报

2019, Vol. 33

Issue (1): 34-42 DOI: 10.11901/1005.3093.2018.296

研究论文

本期目录 | 过刊浏览

双连续Si₃N₄/1Cr18Ni9Ti复合材料的制备和冲蚀性能

杜奇^1,²,高勇¹,任志恒^1,³,曹小明¹,王超¹,张劲松¹(

)

1. 中国科学院金属研究所沈阳 110016
2. 中国科学技术大学材料科学与工程学院沈阳 110016
3. 辽宁卓异新材料有限公司营口 115004

Preparation and Erosion Performance for Co-continuous Phase Composites of Si₃N₄/1Cr18Ni9Ti

Qi DU^1,²,Yong GAO¹,Zhiheng REN^1,³,Xiaoming CAO¹,Chao WANG¹,Jinsong ZHANG¹(

)

1. Institute of Metal Research, Chinese Academy of Science, Shenyang 110016, China
2. School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China
3. Liaoning ZhuoYi New Materials Corporation, Yingkou 115004, China

引用本文:

杜奇,高勇,任志恒,曹小明,王超,张劲松. 双连续Si₃N₄/1Cr18Ni9Ti复合材料的制备和冲蚀性能[J]. 材料研究学报, 2019, 33(1): 34-42.
Qi DU, Yong GAO, Zhiheng REN, Xiaoming CAO, Chao WANG, Jinsong ZHANG. Preparation and Erosion Performance for Co-continuous Phase Composites of Si₃N₄/1Cr18Ni9Ti[J]. Chinese Journal of Materials Research, 2019, 33(1): 34-42.

全文: PDF(15459 KB) HTML

摘要:

用凝胶注模和压力铸造两步法制备具有双连续结构的Si₃N₄/1Cr18Ni9Ti复合材料并分析其物相组成、宏观和微观结构，研究了材料的冲蚀率与攻角、流速、含沙量以及时间的关系。结果表明，与1Cr18Ni9Ti材料相比，Si₃N₄/1Cr18Ni9Ti复合材料具有双连续结构，界面结合良好；其冲蚀率随着攻角变化的幅度小，冲蚀率与流速之间的关系由1Cr18Ni9Ti材料的线性关系转变为指数关系(E∝V^0.67)，且随着时间的延长冲蚀率降低；冲蚀率与含沙量之间的关系仍呈线性。具有双连续结构的Si₃N₄/1Cr18Ni9Ti复合材料，具有更加优异的耐冲蚀性能。

关键词 ：复合材料, 双连续相, 泥浆冲蚀, 1Cr18Ni9Ti, 泡沫陶瓷

Abstract：

Composites with co-continuous structure of Si₃N₄/1Cr18Ni9Ti were prepared via a two-step process, namely gel casting and pressure casting. The phase composition, macro- and micro-structure of the composites were characterized. The erosion rate in flow slurry composed of water and quartz sand, as a function of impingement angle, flow velocity, sand content and erosion time was assessed in comparison with the plain 1Cr18Ni9Ti. Results show that Si₃N₄/1Cr18Ni9Ti composites exhibited a perfect co-continuous phase structure with a good combination between Si₃N₄ and 1Cr18Ni9Ti; the fluctuation of erosion rate as a function of impingement angle of this composites is smaller than that of 1Cr18Ni9Ti; the erosion rate of composites has an exponent relationship with flow velocity (E∝V ^0.67), while there is a linear relationship between the erosion rate and flow velocity for 1Cr18Ni9Ti; the erosion rate of this composites decreases gradually with the increasing erosion time and then stabilizes, while that of 1Cr18Ni9Ti is hardly changed; There is a linear relationship between the erosion rate and sand content in the slurry for the two materials. The composite with co-continuous structure of Si3N4/1Cr18Ni9Ti exhibits superior erosion resistance, in contrast with the plain 1Cr18Ni9Ti steel.

Key words： composite co-continuous phase slurry erosion 1Cr18Ni9Ti foam ceramic

收稿日期: 2018-04-26

ZTFLH:

TB333

基金资助:国家重点研发计划重点专项(2017YFB0310405)

作者简介: 杜奇，男，1991年生，硕士生

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https://www.cjmr.org/CN/10.11901/1005.3093.2018.296 或 https://www.cjmr.org/CN/Y2019/V33/I1/34

图1 冲蚀磨损试验装置的示意图

图2 Si3N4泡沫陶瓷的XRD谱

图3 Si3N4泡沫陶瓷的形貌

图4 双连续Si3N4/1Cr18Ni9Ti复合材料的形貌

表1 不同微区EDS元素分析

图5 冲蚀率与攻角的关系

图6 冲蚀率与流速的关系

图7 1Cr18Ni9Ti和复合材料磨损后的SEM和三维表面轮廓图

图8 冲蚀率与含沙量的关系

图9 1Cr18Ni9Ti、双连续Si3N4/1Cr18Ni9Ti复合材料和Si3N4陶瓷3种材料耐冲蚀性的比较

图10 复合材料冲蚀前后高度差

图11 双连续Si3N4/1Cr18Ni9Ti复合材料的冲蚀机理示意图

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