莫来石填充的聚四氟乙烯复合材料及其摩擦学性能*

doi:10.11901/1005.3093.2015.691

材料研究学报

2016, Vol. 30

Issue (6): 427-437 DOI: 10.11901/1005.3093.2015.691

研究论文

本期目录 | 过刊浏览

莫来石填充的聚四氟乙烯复合材料及其摩擦学性能*

李翠, 孙桃, 石国军(

), 袁月, 张辰恺

扬州大学化学化工学院扬州 225002

Polytetrafluoroethylene Composites Filled with Mullite and their Tribological Performance

LI Cui, SUN Tao, SHI Guojun^**(

), YUAN Yue, ZHANG Chenkai

School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China

引用本文:

李翠, 孙桃, 石国军, 袁月, 张辰恺. 莫来石填充的聚四氟乙烯复合材料及其摩擦学性能*[J]. 材料研究学报, 2016, 30(6): 427-437.
Cui LI, Tao SUN, Guojun SHI, Yue YUAN, Chenkai ZHANG. Polytetrafluoroethylene Composites Filled with Mullite and their Tribological Performance[J]. Chinese Journal of Materials Research, 2016, 30(6): 427-437.

全文: PDF(1194 KB) HTML

摘要:

采用机械混匀、带温预压、烧结等工艺制备了莫来石填充的聚四氟乙烯(PTFE)复合材料, 通过万能材料试验机、X射线衍射仪(XRD)、静态热机械分析仪(TMA)分别表征了复合材料的力学性能、物相和热学性质; 研究使用MRH-3型高速环块磨损试验机来测试复合材料的耐摩擦磨损性能, 借助场发射扫描电子显微镜研究了复合材料摩擦面形貌并分析摩擦磨损机理。结果表明: 莫来石在PTFE体系中起填充增强作用, 改性聚四氟乙烯复合材料的弹性模量显著增加; 莫来石的填充提高了聚四氟乙烯的玻璃化转变温度, 其平均线膨胀系数也呈下降趋势; 当莫来石的质量分数由0增加至50%时, 复合材料的摩擦系数呈先降低、后升高的趋势, 复合材料的耐磨损性能显著改善; 当莫来石的质量分数为40%时, 其磨损率降低至纯聚四氟乙烯的1/530。

关键词 ：复合材料, 聚四氟乙烯, 莫来石, 摩擦系数, 磨损率

Abstract：

Polytetrafluoroethylene (PTFE) composites filled with mullite were prepared by mechanical blending, heat compression and then sintering at elevated temperature. The mechanical properties, crystal structure and thermal properties were characterized by universal material testing machine, X-ray diffraction (XRD) and thermal mechanical analysis (TMA), respectively. The friction coefficient and wear rate of the prepared PTFE composites were tested by an MRH-3 high speed friction and wear tester, and the surface morphologies of the composites after friction test were analyzed by a field-emitting scanning electron microscope. It was found that mullite fillings were well dispersed in PTFE, and the thermal and mechanical properties of the composites were enhanced, such as modulus of elasticity, glass transition temperature and average linear expansion coefficient. The friction coefficients of the prepared composites with mullite fillings less than 10% (mass fraction) were smaller than that of pure PTFE, and the larger friction coefficient was found for those with higher among of mullite fillings. It was more important to find that the wear rate of the composites filled with 40% (mass fraction) of mullite fillings decreased to 1/530 of that for the pure PTFE.

Key words： composite PTFE mullite friction coefficient wear rate

收稿日期: 2015-12-03

ZTFLH:

TH117TQ325

基金资助:* 江苏省自然科学基金BK2012681, 教育部博士点基金20123250120008和江苏省优势学科资助项目

作者简介: 本文联系人: 石国军

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	李翠
	孙桃
	石国军
	袁月
	张辰恺
44.8K

链接本文:

https://www.cjmr.org/CN/10.11901/1005.3093.2015.691 或 https://www.cjmr.org/CN/Y2016/V30/I6/427

图1 PTFE、莫来石及PTFE-莫来石复合材料的红外光谱

图2 PTFE、莫来石及PTFE-莫来石复合材料XRD谱

图3 PTFE-莫来石复合材料拉伸性能随莫来石质量分数的变化曲线

图4 PTFE-莫来石复合材料弹性模量随莫来石质量分数的变化图

图5 PTFE及PTFE-莫来石复合材料的拉伸断口形貌

图6 PTFE及PTFE-莫来石复合材料洛氏硬度随莫来石质量分数的变化曲线

图7 PTFE及PTFE-莫来石复合材料的DSC图

表1 PTFE及其复合材料的量热性质

图8 PTFE及PTFE-莫来石复合材料的TMA图

表2 PTFE及其复合材料的平均线膨胀系数及玻璃化温度

图9 PTFE及PTFE-莫来石复合材料摩擦系数随滑动距离变化曲线

图10 PTFE及PTFE-莫来石复合材料体积磨损率和平均摩擦系数变化的关系曲线

图11 PTFE及PTFE-莫来石复合材料在干摩擦条件下的摩擦面的SEM图和3D激光显微镜图

1	K. P. Murali, S. Rajesh, O. Prakash, A. R. Kulkarni, R. Ratheesh, Preparation and properties of silica filled PTFE flexible laminates for microwave circuit applications, Composites Part A Applied Science & Manufacturing, 40(8), 1179(2009) doi: 10.1016/j.compositesa.2009.05.007
2	P. R. Barry, P. Y. Chiu, S. S. Perry, W. G. Sawyer, S. B. Sinnott, S. R. Phillpot, Effect of temperature on the friction and wear of PTFE by atomic-level simulation, Tribology Letters, 58(3), 1(2015) doi: 10.1007/s11249-015-0529-y
3	T. Wang, J. Wang, P. Yan, J. Ran, Influence of temperature on electrical aging characteristics of polyterafluoroethylene under nanosecong pulses, IEEE Transactions on Dielectrics and Electrical Insulation, 22(2), 1171(2015)
4	Z. Zuo, Y. l. Yang, L. z. Song, Miscibility analysis of polyethersulfone and polytetrafluoroethylene using the molecular dynamics method, Fibers and Polymers, 16(3), 510(2015) doi: 10.1007/s12221-015-0510-2
5	H. Kurz, E. Roos, Design of floating type bolted flange connections with grp flanges, International Journal of Pressure Vessels and Piping, 89, 1(2012) doi: 10.1016/j.ijpvp.2011.08.004
6	L. Mazza, A. Trivella, R. Grassi, G. Malucelli, A comparison of the relative friction and wear responses of PTFE and PTFE-based composite when tested using three different types of sliding wear machines, Tribology International, 90, 15(2015)
7	M. M. Yang, X. T. Zhu, G. N. Ren, X. H. Men, F. Guo, P. L. Li, Z. Z. Zhang, Influence of air-plasma treatment and hexagonal boron nitride as filler on the high temperature tribological behaviors of hybrid PTFE/Nomex fabric/phenolic composite, European Polymer Journal, 67, 143(2015)
8	M. Palabiyik, S. Bahadur, Tribological studies of polyamide 6 and high-density polyethylene blends filled with PTFE and copper oxide and reinforced with short glass fibers, Wear, 253(3-4), 369(2002) doi: 10.1016/S0043-1648(02)00144-8
9	J. Ye, H. S. Khare, D. L. Burris, Transfer film evolution and its role in promoting ultra-low of a PTFE nanocomposite, Wear, 297(1-2), 1095(2013)
10	A. A. Pitenis, K. L. Harris, C. P. Junk, G. S. Blackman, W. G. Sawyer, B. A. Krick, Ultralow wear PTFE and alumina composites: It is all about tribochemistry, Tribology Letters, 57(1), 1(2015) doi: 10.1007/s11249-014-0445-6
11	XIANG Dinghan, PAN Qinglin, YAO Zhengjun, Design theory and friction experiment for brass-plastic self-lubricating composite, Chinese Journal of Materials Research, 17(5), 549(2003)
11	(向定汉, 潘青林, 姚正军, 铜-塑自润滑复合材料的设计和性能, 材料研究学报, 17(5), 549(2003))
12	Y. X. Wang, F. Y. Yan, Tribological properties of transfer films of PTFE-based composites, Wear, 261(11-12), 1359(2006) doi: 10.1016/j.wear.2006.03.050
13	YAN Luke, LI Weiguang, SUN Zengzhi, Preparation of GF/PTFE composites and its properties, Insulating Materials, 43(4), 3(2010)
13	(颜录科, 李伟光, 孙增智, 玻璃纤维/聚四氟乙烯复合材料的制备与性能研究, 绝缘材料, 43(4), 3(2010)) doi: 10.3969/j.issn.1009-9239.2010.04.002
14	YAN Luke, LI Weiguang, KOU Kaixhang, SUN Zengzhi, XU Ouming, Frication and wear mechanism of BaSO4/PTFE composites under dry conditions, Journal of Aeronautical Materials, 30(5), 78(2010)
14	(颜录科, 李伟光, 窦开昌, 孙增智, 徐鸥明, BaSO4/PTFE复合材料在干摩擦条件下的摩擦磨损机理的研究, 航空材料学报, 30(5), 78(2010))
15	JIAN Xuzhen, LI Hua, FANG Guangqiang, ZENG Qingping, YANG Lei, KANG Hongmei, LIU Hezhou, Friction and wear properties of PTFE composites containing CNT and grapheme, Functional Materials, 45(3), 03011(2014)
15	(见雪珍, 李华, 房光强, 曾庆平, 杨磊, 康红梅, 刘河洲, 含碳纳米管、石墨烯的PTFE基复合材料摩擦磨损性能, 功能材料, 45(3), 03011(2014)) doi: 10.3969/j.issn.1001-9731.2014.03.003
16	YANG Dongya, WANG Yue, DONG Yue, GONG Jun, GAO Gui, WANG Honggan, Tribological performance of different nanoparticles reinforced PPS-PTFE blends, Functional Materials, 45(6), 06011(2014)
16	(杨东亚, 王月, 董悦, 龚俊, 高贵, 王宏刚, 不同纳米填料增强PPS-PTFE共混物的摩擦磨损性能分析, 功能材料, 45(6), 06011(2014)) doi: 10.3969/j.issn.1001-9731.2014.06.003
17	P. Liu, T. Huang, R. Lu, T. Li, Tribological properties of modified carbon fabric/polytetrafluoroethylene composites, Wear, 289(25), 17(2012) doi: 10.1016/j.wear.2012.04.021
18	H. Schneider, J. Schreuer, B. Hildmann, Structure and properties of mullite-A review, Journal of European Ceramic Society, 28(2), 329(2008)
19	J. Wang, H. M. Kou, X. J. Liu, Y. Pan, J. Guo, Reinforcement of mullite matrix with multi-walled carbon nanotubes, Ceramics Internationl, 33(5), 719(2007) doi: 10.1016/j.ceramint.2005.12.009
20	LIU Qiongqiong, XU Dongmei, LIU Feng, CONG Houluo, Mechanical properties of PP filled with nanomullite at low content, Plastic, 38(3), 21(2009)
20	(刘琼琼, 徐冬梅, 柳峰, 从后罗, 低纳米莫来石填充聚丙烯的力学性能, 塑料, 38(3), 21(2009))
21	LIU Qiongqiong, XU Dongmei, CONG Houluo, LIU Feng, Crystallization behavior of PP filled with nanomullite at low content, Plastic, 38(2), 98(2009)
21	(刘琼琼, 徐冬梅, 从后罗, 柳峰, 低纳米莫来石填充聚丙烯的结晶性能研究, 塑料, 38(2), 98(2009))
22	Q. Q. Liu, J. Gao, R. N. Du, Properties comparison of mullite and precipitated silica-filled styrene-butadiene rubber composites, China Synthetic Rubber Industry, 34(2), 133(2011) doi: 10.3724/SP.J.1077.2010.10636
23	HUANG Haigang, WANG Caiyun, SHI Dianwang, Study on the Qualitative Identification for PTFE Fiber, Chinese Fiber Inspection, 17(17), 78(2014)
23	(黄海刚, 王彩云, 施点望, 聚四氟乙烯纤维的定性鉴别研究, 中国纤检, 17(17), 78(2014)) doi: 10.3969/j.issn.1671-4466.2014.17.028
24	FU Pingqiu, LIU Gaokui, GUO Jiugao, WANG Guanxin, Some structurally mineralogical characteristics of fused mullite, Acta Mineralogica Sinica, (3), 235(1992)
24	(傅平秋, 刘高魁, 郭九皋, 王冠鑫, 烧结莫来石的某些结构矿物学特征, 矿物学报, (3), 235(1992))
25	ZHANG Yanhong, Study on Preparation Methods and Performance of Nano-reinforced PTFE Materials, Master thesis, Huazhong University of Science and Technology(2006)
25	(张雁鸿, 纳米颗粒增强PTFE材料的制备方法及其性能研究, 硕士学位论文, 华中科技大学(2006)) doi: 10.7666/d.d044514
26	JIAN Xuezhen, The study on mechanical properties and friction and wear properties of filler PTFE composities, Master degree thesis, School of Material Science and Engineering Shanghai Jiao Tong University, 40(2013)
26	(见雪珍, 填充聚四氟乙烯复合材料的力学性能和摩擦磨损性能研究, 硕士学位论文, 上海交通大学材料科学与工程学院, 40(2013))
27	TIAN Hua, XIE Xudong, SONG Xiwen, The research on mechanical and tribological properties of TiO2 modified PTFE composites, Journal of Inner Mongolia University of Science and Technology, 29(4), 334(2010)
27	(田华, 解旭东, 宋希文, TiO2改性PTFE复合材料力学与摩擦性能的研究, 内蒙古科技大学学报, 29(4), 334(2010)) doi: 10.3969/j.issn.2095-2295.2010.04.010
28	GU Chunyan, HE Chunxia, Frictional and Mechanical properties of PTFE composites filled with powered fiber. Engineering Plastics Applications, 37(6), 15(2009)
28	(顾春艳, 何春霞, 粉状纤维增强PTFE复合材料的力学与摩擦磨损性能, 工程塑料应用, 37(6), 15(2009)) doi: 10.3969/j.issn.1001-3539.2009.06.004
29	ZHENG Jing, HUANG Yi, ZHOU Zhongrong, Research of relationship between microstructure and tribological properties of ename, 2008 National Youth Conference on Tribology and Surface Protection(2008)
29	(郑靖, 黄毅, 周仲荣, 人牙釉质微结构与其宏观摩擦学特性的关系研究, 2008全国青年摩擦学与表面保护学术会议(2008))
30	LUO Hua, Relationship between the wear resistance of hard rock and basic mechanical parameters of rock, West-China Exploration Engineering, 21(7), 166(2009)
30	(罗华, 某隧道硬岩岩石耐磨性与岩石基本力学指标的关系, 西部探矿工程, 21(7), 166(2009)) doi: 10.3969/j.issn.1004-5716.2009.07.060
31	GAO Pan, KOU Kaichang, ZHANG Dongna, SHI Hailin, ZHUO Longhai, Effect of oriented drawing on properties and structure of BaSO4 filled PTFE composites, China Plastics, (12), 76(2012)
31	(高攀, 寇开昌, 张冬娜, 史海林, 卓龙海, 定向拉伸对PTFE/BaSO4复合材料性能和结构的影响, 中国塑料, (12), 76(2012))
32	ZHENG Zhenchao, KOU Kaichang, ZHANG Dongna, HOU Mei, Study on creep behavior nd crystallization of POB filled PTFE blends, China Plastics, (7), 52(2013)
32	(郑振超, 寇开昌, 张冬娜, 侯梅, 聚四氟乙烯/聚苯酯共混物的蠕变及结晶性能研究, 中国塑料, (7), 52(2013))
33	S. Ye, X. Zeng, F. Tan, Q. Fan, Research on the tribological performance of Cr2O3 filled with bronze‐based PTFE composites, Journal of Applied Polymer Science, 131(22), 547(2014)
34	XIANG Donghu, XI Bo, ZHU Yabo, A study on the friction and wear properties of PTFE composites filled with carbon fiber and carbon micro-coils, Journal of Huaiyin Institute of Technology, 19(5), 4(2010)
34	(项东虎, 席博, 朱亚波, 碳纤维增强PTFE复合材料的摩擦磨损性能研究, 淮阴工学院学报, 19(5), 4(2010)) doi: 10.3969/j.issn.1009-7961.2010.05.002
35	H. Unal, A. Mimaroglu, U. Kadıoglu, H. Ekiz, Sliding friction and wear behaviour of polytetrafluoroethylene and its composites under dry conditions, Materials and Design, 25(3), 239(2004) doi: 10.1016/j.matdes.2003.10.009
36	J. G. Xu, H. B. Yan, D. G. Gu, Friction and wear behavior of polytetrafluoroethene composites filled with Ti3SiC2 , Materials and Design, 61(9), 270(2014)
37	YU Xiaolin, Research on precision grinding mechanism and surface evalution of SiCp/Al composities with high volume fraction, Doctor’s dissertation, School of Mechanical Engineering Shenyang University of Technology, 32(2012)
37	(于晓琳, 高体积分数SiCp/Al复合材料精密磨削机理及表面评价, 博士学位论文, 沈阳工业大学机械制造及其自动化, 32(2012))
38	KANG Kejia, DU Sanming, ZHANG Yongzhen, ZHANG Zhiyuan, A summary of study on friction and modification of PTFE composites, Lubrication Engineering, 37(6), 99(2012)
38	(康克家, 杜三明, 张永振, 张智源. PTFE复合材料摩擦及改性研究综述, 润滑与密封, 37(6), 99(2012)) doi: 10.3969/j.issn.0254-0150.2012.06.023
39	ZHU Changlin, CHEN Yue, DU Sanming, FENG Xianjuan, ZHANG Yongzhen, Tribological research process of modified PTFE, Engineering Plastics Applications, 39(6), 92(2011)
39	(朱长岭, 陈跃, 杜三明, 逢显娟, 张永振. 改性聚四氟乙烯摩擦学研究进展, 工程塑料应用, 39(6), 92(2011)) doi: 10.3969/j.issn.1001-3539.2011.06.023

[1]	潘新元, 蒋津, 任云飞, 刘莉, 李景辉, 张明亚. 热挤压钛/钢复合管的微观组织和性能[J]. 材料研究学报, 2023, 37(9): 713-720.
[2]	刘瑞峰, 仙运昌, 赵瑞, 周印梅, 王文先. 钛合金/不锈钢复合板的放电等离子烧结技术制备及其性能[J]. 材料研究学报, 2023, 37(8): 581-589.
[3]	季雨辰, 刘树和, 张天宇, 查成. MXene在锂硫电池中应用的研究进展[J]. 材料研究学报, 2023, 37(7): 481-494.
[4]	王伟, 解泽磊, 屈怡珅, 常文娟, 彭怡晴, 金杰, 王快社. Graphene/SiO₂ 纳米复合材料作为水基润滑添加剂的摩擦学性能[J]. 材料研究学报, 2023, 37(7): 543-553.
[5]	张藤心, 王函, 郝亚斌, 张建岗, 孙新阳, 曾尤. 基于界面氢键结构的石墨烯/聚合物复合材料的阻尼性能[J]. 材料研究学报, 2023, 37(6): 401-407.
[6]	邵萌萌, 陈招科, 熊翔, 曾毅, 王铎, 王徐辉. C/C-ZrC-SiC复合材料的Si²⁺ 离子辐照行为[J]. 材料研究学报, 2023, 37(6): 472-480.
[7]	张锦中, 刘晓云, 杨健茂, 周剑锋, 查刘生. 温度响应性双面纳米纤维的制备和性能[J]. 材料研究学报, 2023, 37(4): 248-256.
[8]	王刚, 杜雷雷, 缪自强, 钱凯成, 杜向博文, 邓泽婷, 李仁宏. 聚多巴胺改性碳纤维增强尼龙6复合材料的界面性能[J]. 材料研究学报, 2023, 37(3): 203-210.
[9]	林师峰, 徐东安, 庄艳歆, 张海峰, 朱正旺. TiZr基非晶/TC21双层复合材料的制备和力学性能[J]. 材料研究学报, 2023, 37(3): 193-202.
[10]	苗琪, 左孝青, 周芸, 王应武, 郭路, 王坦, 黄蓓. 304不锈钢纤维/ZL104铝合金复合泡沫的孔结构、力学、吸声性能及其机理[J]. 材料研究学报, 2023, 37(3): 175-183.
[11]	张开银, 王秋玲, 向军. FeCo/SnO₂ 复合纳米纤维的制备及其吸波性能[J]. 材料研究学报, 2023, 37(2): 102-110.
[12]	周聪, 昝宇宁, 王东, 王全兆, 肖伯律, 马宗义. (Al₁₁La₃+Al₂O₃)/Al复合材料的高温性能及其强化机制[J]. 材料研究学报, 2023, 37(2): 81-88.
[13]	罗昱, 陈秋云, 薛丽红, 张五星, 严有为. 钠离子电池双层碳包覆Na₃V₂(PO₄)₃ 正极材料的超声辅助溶液燃烧合成及其电化学性能[J]. 材料研究学报, 2023, 37(2): 129-135.
[14]	刘志华, 岳远超, 丘一帆, 卜湘, 阳涛. g-C₃N₄/Ag/BiOBr复合材料的制备及其光催化还原硝酸盐氮[J]. 材料研究学报, 2023, 37(10): 781-790.
[15]	谢东航, 潘冉, 朱士泽, 王东, 刘振宇, 昝宇宁, 肖伯律, 马宗义. 增强颗粒尺寸对B₄C/Al-Zn-Mg-Cu复合材料微观组织及力学性能的影响[J]. 材料研究学报, 2023, 37(10): 731-738.

Viewed

Full text

Abstract

Cited

Shared

Discussed