SIMP钢和T91钢在800℃的高温氧化行为*

doi:10.11901/1005.3093.2015.230

材料研究学报

2016, Vol. 30

Issue (2): 81-86 DOI: 10.11901/1005.3093.2015.230

本期目录 | 过刊浏览

SIMP钢和T91钢在800℃的高温氧化行为*

石全强^1,², 刘坚^1,², 严伟^2,³, 王威^2,³, 单以银^2,³, 杨柯²(

)

1. 中国科学院大学北京 100049
2. 中国科学院金属研究所沈阳 110016
3. 中国科学院核用材料与安全评价重点实验室中国科学院金属研究所沈阳 110016

High Temperature Oxidation Behavior of SIMP Steel and T91 Steel at 800℃

SHI Quanqiang^1,², LIU Jian^1,², YAN Wei^2,³, WANG Wei^2,³, SHAN Yiyin^2,³, YANG Ke^2,^**(

)

1. University of Chinese Academy of Sciences, Beijing 100049, China
2. Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
3. Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China;

引用本文:

石全强, 刘坚, 严伟, 王威, 单以银, 杨柯. SIMP钢和T91钢在800℃的高温氧化行为*[J]. 材料研究学报, 2016, 30(2): 81-86.
Quanqiang SHI, Jian LIU, Wei YAN, Wei WANG, Yiyin SHAN, Ke YANG. High Temperature Oxidation Behavior of SIMP Steel and T91 Steel at 800℃[J]. Chinese Journal of Materials Research, 2016, 30(2): 81-86.

全文: PDF(4373 KB) HTML

摘要:

研究了ADS嬗变系统候选结构材料新型低活化马氏体耐热钢SIMP钢和T91钢在800℃空气中的高温氧化行为.结果表明, SIMP钢和T91钢在空气中氧化500 h后在表面形成了不同结构的氧化膜: 在SIMP钢表面形成了连续致密的Cr₂O₃层, 在Cr₂O₃层分布一层颗粒状的铬锰尖晶石, 在基体和氧化膜之间出现硅的富集; 而在T91钢表面形成了外层为Fe₂O₃和内层为铁铬尖晶石的双层结构氧化膜.新型SIMP钢的高温氧化速率远比T91钢的低, 表现出优异的抗高温氧化性能.SIMP钢中较高的铬和硅元素含量, 是其抗高温氧化性能优于T91钢的主要原因.

关键词 ：金属材料, ADS, 高温氧化, SIMP钢, T91钢, 氧化膜

Abstract：

Oxidation behavior of two ferrite/martensite(F/M) steels, namely a novel 9%-12% Cr modified F/M steel (SIMP steel) and a commercial T91 steel were comparatively studied in air at 800^oC. The oxide scales formed on the two steels were characterized by XRD, SEM and EPMA. The results show that the oxide scale formed on SIMP steel is single-layer composed of Cr₂O₃and Mn_1.5Cr_1.5O₄ spinel particles, and Si was enriched at the interface between the chromia scale and matrix; while the oxide scale formed on T91 steel has a double layered structure with an outer hematite Fe₂O₃ layer and an inner Fe-Cr spinel layer. The SIMP steel has better high temperature oxidation resistance than T91 steel, which may be due to the higher content of Cr and Si beneficial to the formation of the compact oxide scale on the SIMP steel.

Key words： metallic materials ADS high temperature oxidation SIMP steel T91 steel oxide scale

收稿日期: 2015-04-20

ZTFLH:

TG172

基金资助:* 中国科学院战略性先导科技专项子课题XDA03010301,XDA03010302资助项目

作者简介: 通讯作者：杨柯, 研究员

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https://www.cjmr.org/CN/10.11901/1005.3093.2015.230 或 https://www.cjmr.org/CN/Y2016/V30/I2/81

表1 实验用钢的化学成分

图1 T91钢和SIMP钢热处理后的组织

图2 SIMP钢和T91钢在800℃空气中氧化500 h的氧化增重曲线

图3 SIMP钢和T91钢800℃空气中氧化500 h的XRD谱

图4 T91钢和SIMP钢在800℃空气中氧化500 h后表面氧化物的形貌和EDS分析

图5 T91钢和SIMP钢在800℃空气中氧化500 h后氧化膜的截面形貌和EPMA元素分析

图6 T91钢和SIMP钢在800℃空气中氧化500 h后的氧化膜截面形貌

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