石墨烯作为润滑油添加剂在青铜织构表面的摩擦磨损行为*

doi:10.11901/1005.3093.2015.082

材料研究学报

2016, Vol. 30

Issue (1): 57-62 DOI: 10.11901/1005.3093.2015.082

研究论文

本期目录 | 过刊浏览

石墨烯作为润滑油添加剂在青铜织构表面的摩擦磨损行为*

赵磊, 蔡振兵(

), 张祖川, 张旭, 林映武, 彭金方, 朱旻昊

西南交通大学摩擦学研究所成都 610031

Tribological Properties of Graphene as Effective Lubricant Additive in Oil on Textured Bronze Surface

ZHAO Lei, CAI Zhenbing^**(

), ZHANG Zuchuan, ZHANG Xu, LIN Yingwu, PENG Jinfang, ZHU Minhao

Tribology Research Institute, Southwest Jiaotong University, Chengdu 610031, China

引用本文:

赵磊, 蔡振兵, 张祖川, 张旭, 林映武, 彭金方, 朱旻昊. 石墨烯作为润滑油添加剂在青铜织构表面的摩擦磨损行为*[J]. 材料研究学报, 2016, 30(1): 57-62.
Lei ZHAO, Zhenbing CAI, Zuchuan ZHANG, Xu ZHANG, Yingwu LIN, Jinfang PENG, Minhao ZHU. Tribological Properties of Graphene as Effective Lubricant Additive in Oil on Textured Bronze Surface[J]. Chinese Journal of Materials Research, 2016, 30(1): 57-62.

全文: PDF(3390 KB) HTML

摘要:

采用球面接触往复移动方式, 使用UTM-2摩擦磨损试验机考察了石墨烯作为润滑油添加剂的摩擦磨损性能。用TEM、SEM、XRD、红外光谱、拉曼光谱等手段对石墨烯的形貌和结构进行表征, 用PAO4作为基础油和添加质量分数为0.01%石墨烯(GP)的润滑油进行对比, 研究了在不同温度和不同织构面积率下的摩擦学性能。结果表明: 在润滑油中添加石墨烯能显著改善摩擦磨损性能, 温度为60℃和100℃时的效果最明显。在60℃和100℃工况下, 在PAO4基础油中相对于原始表面各种织构都增大了摩擦系数和磨损率, 在25℃和150℃工况下表面织构对摩擦磨损的影响不大; 使用含有石墨烯的润滑油在不同温度下织构面积率为5%时摩擦系数较低, 织构面积率为20%时摩擦系数较高, 织构面积率为10%时磨损率较低。

关键词 ：无机非金属材料, 石墨烯, 添加剂, 织构, 摩擦磨损

Abstract：

The friction and wear properties of graphene (GP) as a lubricant additives were investigated by means of a UTM-2 tribometer via a ball on plate contact reciprocating sliding. The molecular structure and morphology of graphene nano sheets were characterized by TEM, SEM, XRD, IR and Raman spectroscopy. The friction and wear test was performed with lubricant of PAO4 oil without and with addition of 0.01% graphene (GP) respectively at different temperatures for the textured bronze with different ratio of textured area. The results show that GP can effectively reduce the friction and wear, especially at 60℃ and 100℃. For the simple PAO4 oil, the bronze with untextured surface exhibits the lowest friction coefficient and wear rate at 60℃ and 100℃; whilst, with the increasing ratio of the textured area, the friction coefficient and wear rate increase. For graphene-containing PAO4 lubricating oil, the friction coefficient is lower for the bronze with 5% textured area, while higher for those with 20%; the wear rate is lower for the bronze with 10% textured area.

Key words： inorganic non-metallic materials graphene additive texture friction and wear

收稿日期: 2015-02-10

基金资助:* 国家自然科学基金51375407, U1530136资助项目

作者简介: 蔡振兵

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https://www.cjmr.org/CN/10.11901/1005.3093.2015.082 或 https://www.cjmr.org/CN/Y2016/V30/I1/57

表1 表面织构参数

图1 石墨烯的分散性试验

图2 2#试样在不同温度下的摩擦系数

图3 2#试样不同温度条件下的平面试样磨痕轮廓

图4 2#试样在60℃磨损后的球和平面试样光镜形貌(?表示滑动方向)

图5 2#试样在60℃的磨痕SEM像和EDS能谱

图6 不同表面织构平均摩擦系数对比

表2 平面试样磨损率

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